Fabrication of nitride nanoparticles
AssigneeSharp Kabushiki Kaisha
InventorsPeter Neil Taylor, Jonathan Heffernan
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Abstract
A method of manufacturing a nitride nanoparticle comprises manufacturing the nitride nanostructure from constituents including: a material containing metal, silicon or boron, a material containing nitrogen, and a capping agent having an electron-accepting group for increasing the quantum yield of the nitride nanostructure. Nitride nanoparticles, for example nitride nanocrystals, having a photoluminescence quantum yield of at least 1%, and up to 20% or greater, may be obtained.
Claims22
A method of manufacturing a light-emissive nitride nanoparticle, the method comprising:
- reacting in a first solvent (i) at least one Group III metal iodide with (ii) at least one Group I metal amide in the presence of (iii) at least one capping agent having an electron-accepting group to produce a nitride crystal, at least two dimensions of the nitride crystal being of a nanoscale dimension, the nitride crystal having the general formula:
- M1x1M2x2M3 x3. . .Mn xnNy
- wherein M1, M2, M3. . .Mn are different Group III metals, the numbers x1, x2, x3. . . xn are the relative quantities of the Group III metals in the nitride crystal and range from 0 to 1, where x1+x2+x3+. . .xn =1, and y is the quantity of nitrogen and y =1;
- wherein the Group I metal of the metal amide is selected from among Li, Na and K;
- and
- wherein the capping agent comprises a zinc carboxylate, the zinc passivating nitrogen atoms of the nitride crystal at the surface of the nitride crystal, thereby increasing the photoluminescent quantum yield of the light-emissive nitride nanoparticle.
A method as claimed in 6 wherein the group for promoting solubility of the nitride nanoparticle is an alkyl chain.
Dependencies are inferred from the claim text.