Back to results
US 8,945,776 B2Granted
Electrolyte for rechargeable lithium battery and rechargeable lithium battery including the same
AssigneeSamsung SDI Co., Ltd.
InventorsTae-Ahn Kim, Mi-Hyeun Oh, Na-Rae Won, Sung-Hoon Kim
Life of this patent
Estimating the term…
Abstract
An electrolyte for a rechargeable lithium battery and a rechargeable lithium battery including the same, the electrolyte including a lithium salt, a silylborate-based compound, an anhydride component, and a non-aqueous organic solvent.
Claims17
An electrolyte for a rechargeable lithium battery, comprising:
- a lithium salt;
- a silylborate-based compound (A) represented by Formula 1:
- wherein, in Formula 1, R1 to R9 are each independently hydrogen, a halogen-substituted C1 to C10 alkyl, or an unsubstituted C1 to C10 alkyl;
- an anhydride component (B) consisting of one or more compounds represented by Formulae 2 to 5:
- wherein, in Formulae 2 to 5, R10 to R25 are each independently hydrogen or a C1 to C10 alkyl;
- and
- a non-aqueous organic solvent, wherein:
- the silylborate-based compound (A) and the anhydride component (B) are included at a weight ratio (A/B) of about 0.1 to 0.5 or 2 to about 15,
- the silylborate-based compound (A) is included in an amount of about 0.05 to about 3 wt % based on the combined weight of the non-aqueous organic solvent and the lithium salt, and
- the anhydride component (B) is included in an amount of about 0.3 to about 3 wt % based on the combined weight of the non-aqueous organic solvent and the lithium salt,
- wherein:
- the organic solvent includes about 15 to about 25 volume % of a cyclic carbonate and the electrolyte has a viscosity of about 3.0 to about 3.7 cP at 0° C., or
- the organic solvent includes about 26 to about 35 volume % of a cyclic carbonate and the electrolyte has a viscosity of about 4.0 to about 4.7 cP at 0° C.
10 more elements
A rechargeable lithium battery, comprising:
- a positive electrode;
- a negative electrode;
- and
- an electrolyte including:
- a lithium salt,
- a silylborate-based compound (A) represented by Formula 1:
- wherein, in Formula 1, R1 to R9 are each independently hydrogen, a halogen-substituted C1 to C10 alkyl, or an unsubstituted C1 to C10 alkyl,
- an anhydride component (B) consisting of one or more compounds represented by Formulae 2 to 5:
- wherein, in Formulae 2 to 5, R10 to R25 are each independently hydrogen or a C1 to C10 alkyl, and
- a non-aqueous organic solvent, wherein:
- the silylborate-based compound (A) and the anhydride component (B) are included at a weight ratio (A/B) of about 0.1 to 0.5 or 2 to about 15,
- the silylborate-based compound (A) is included in an amount of about 0.05 to about 3 wt % based on the combined weight of the non-aqueous organic solvent and the lithium salt, and
- the anhydride component (B) is included in an amount of about 0.3 to about 3 wt % based on the combined weight of the non-aqueous organic solvent and the lithium salt,
- wherein:
- the organic solvent includes about 15 to about 25 volume % of a cyclic carbonate and the electrolyte has a viscosity of about 3.0 to about 3.7 cP at 0° C., or
- the organic solvent includes about 26 to about 35 volume % of a cyclic carbonate and the electrolyte has a viscosity of about 4.0 to about 4.7 cP at 0° C.
13 more elements
Dependencies are inferred from the claim text.