Poly aryl ether ketone polymer blends
AssigneeSabic Global Technologies B.V.
InventorsAshish Aneja, Robert Russell Gallucci, Roy Ray Odle, Kapil Chandrakant Sheth
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Abstract
Filled phase-separated blends of polyaryl ether ketones, polyaryl ketones, polyether ketones, polyether ether ketones and mixtures thereof with at least one polysulfone etherimide, wherein the polysulfone etherimide has greater than or equal to 50 mole % of the polymer linkages contain at least one aryl sulfone group are described. Such filled blends have improved load-bearing capability at high temperature. In another aspect the filled blends have a higher crystallization temperature, especially at fast cooling rates.
Claims17
A filled polymer blend comprising a mixture of:
- from 2 to 99 wt. % of a resin blend comprising:
- a first resin component comprising one or more polyaryl ether ketones;
- and
- a second resin component comprising one or more polysulfone etherimides having greater than or equal to 50 mole % of the polymer linkages containing at least one aryl sulfone group and comprising the reaction product of a dianhydride monomer and a diamine monomer,
- wherein the ratio of the first component to the second component, in parts by weight is from 99:1 to 60:40;
- wherein:
- 1) the dianhydride monomer is selected from the group consisting of oxydiphthalic anhydrides, bisphenol A dianhydride (BPADA), disulfone dianhydride, bis(carbophenoxy phenyl)hexafluoro propane dianhydride, pyromellitic dianhydride (PMDA), biphenyl dianhydride, and mixtures thereof;
- and,
- 2) the diamine monomer is selected from the group consisting of diamino diphenyl sulfone (DDS), m-phenylene diamine (mPD), p-phenylene diamine (pPD), 4,4′-oxydianiline (ODA), 1,3-bis(4-aminophenoxy benzene) and bis(aminophenoxy phenyl)sulfones (BAPS);
- and
- from 1 to 98 wt. % of at least one filler;
- wherein the at least one filler has a weight loss (under nitrogen) of 10% or less at 300° C., as determined by thermal gravimetric analyses ASTM method E1868,
- wherein the polymer blend has a melt viscosity of 200 to 1000 Pa-s at 380° C., and less than a 50% change in initial melt viscosity after 10 minutes at 380° C., and
- wherein the wt. % of resin blend and filler are based upon the combined weight of resin blend and filler.
Dependencies are inferred from the claim text.