Nanostructured metal oxides comprising internal voids and methods of use thereof
AssigneeCornell Research Foundation, Inc.
InventorsLynden A. Archer, Xiong Wen Lou
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AssigneeCornell Research Foundation, Inc.
InventorsLynden A. Archer, Xiong Wen Lou
Estimating the term…
The present invention relates to nano structures of metal oxides having a nanostructured shell (or wall), and an internal space or void. Nanostructures may be nanoparticles, nanorod/belts/arrays, nanotubes, nanodisks, nanoboxes, hollow nanospheres, and mesoporous structures, among other nanostructures. The nanostructures are composed of polycrystalline metal, oxides such as SnO2. The nanostructures may have concentric walls which surround the internal space of cavity. There may be two or more concentric shells or walls. The internal space may contain a core such ferric oxides or other materials which have functional properties. The invention also provides for a novel, inexpensive, high-yield method for mass production of hollow metal oxide nanostructures. The method may be template free or contain a template such as silica. The nanostructures prepared by the methods of the invention provide for improved cycling performance when tested using rechargeable lithium-ion batteries.
An electrode for use in a battery comprising at least one polycrystalline nanostructure, wherein the nanostructure comprises at least two metal oxide concentric shells defining an inner void, wherein the nanostructure further comprises a core within the inner void, and wherein the nanostructure has a discharge capacity of at least about 300 mAh/g after about 25 cycles.
Dependencies are inferred from the claim text.