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US 8,941,007 B2Granted
Electron donating polymer and organic solar cell including the same
AssigneeSamsung Electronics Co., Ltd.
InventorsSoo-Ghang Ihn, Yeong-Suk Choi, Youn-Hee Lim, Bulliard Xavier, Sung-Young Yun, In-Sun Park, Yeon-Ji Chung
Life of this patent
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Abstract
A polymer, and an organic solar cell including the polymer, include a repeating unit A represented by Chemical Formula 1, and a repeating unit B represented by Chemical Formula 2.
Claims14
A polymer, comprising:
- a repeating unit A represented by the following Chemical Formula 1;
- and
- a repeating unit B represented by the following Chemical Formula 2:
- wherein, in Chemical Formula 1,
- X1 is the same or different in each repeating unit, and is independently a group including at least two ester residual groups and a substituted or unsubstituted divalent aliphatic organic group linking the at least two ester residual groups, and
- X2 is the same or different in each repeating unit, and is independently one selected from hydrogen, a halogen, a substituted or unsubstituted C1 to C20 aliphatic organic group, a hydroxyl group, a substituted or unsubstituted C1 to C20 alkoxy group, a substituted or unsubstituted C1 to C20 ester group, a thiol group, and —SR100, wherein R100 is one selected from a substituted or unsubstituted C1 to C20 aliphatic organic group, a substituted or unsubstituted C2 to C30 aromatic organic group, and a substituted or unsubstituted C2 to C30 heterocycloalkyl group,
- wherein, in Chemical Formula 2,
- X3 and X4 are the same or different, and are each independently one selected from hydrogen, a halogen, a substituted or unsubstituted C1 to C20 aliphatic organic group, a hydroxyl group, a substituted or unsubstituted C1 to C20 alkoxy group, a substituted or unsubstituted C1 to C20 ester group, a thiol group, and —SR101, wherein R101 is a substituted or unsubstituted C1 to C20 aliphatic organic group, a substituted or unsubstituted C2 to C30 aromatic organic group, and a substituted or unsubstituted C2 to C30 heterocycloalkyl group
- wherein the group including the at least two ester residual groups and the substituted or unsubstituted divalent aliphatic organic group linking the at least two ester residual groups is a functional group represented by the following Chemical Formula 3 or 4:
- wherein, in Chemical Formulas 3 and 4,
- X5 to X7 are the same or different, and are each independently a substituted or unsubstituted divalent C1 to C20 aliphatic organic group, and
- R1 and R2 are the same or different, and are each independently one selected from hydrogen, and a substituted or unsubstituted C1 to C20 aliphatic organic group.
9 more elements
A polymer, comprising:
- a repeating unit A represented by the following Chemical Formula 1;
- and
- a repeating unit B represented by the following Chemical Formula 2:
- wherein, in Chemical Formula 1,
- X1 is the same or different in each repeating unit, and is independently a group including at least two ester residual groups and a substituted or unsubstituted divalent aliphatic organic group linking the at least two ester residual groups, and
- X2 is the same or different in each repeating unit, and is independently one selected from hydrogen, a halogen, a substituted or unsubstituted C1 to C20 aliphatic organic group, a hydroxyl group, a substituted or unsubstituted C1 to C20 alkoxy group, a substituted or unsubstituted C1 to C20 ester group, a thiol group, and —SR100, wherein R100 is one selected from a substituted or unsubstituted C1 to C20 aliphatic organic group, a substituted or unsubstituted C2 to C30 aromatic organic group, and a substituted or unsubstituted C2 to C30 heterocycloalkyl group,
- wherein, in Chemical Formula 2,
- X3 and X4 are the same or different, and are each independently one selected from hydrogen, a halogen, a substituted or unsubstituted C1 to C20 aliphatic organic group, a hydroxyl group, a substituted or unsubstituted C1 to C20 alkoxy group, a substituted or unsubstituted C1 to C20 ester group, a thiol group, and —SR101, wherein R101 is a substituted or unsubstituted C1 to C20 aliphatic organic group, a substituted or unsubstituted C2 to C30 aromatic organic group, and a substituted or unsubstituted C2 to C30 heterocycloalkyl group,
- wherein the repeating unit A includes one selected from a repeating unit represented by the following Chemical Formula 5-1, a repeating unit represented by the following Chemical Formula 5-2, and a combination thereof:
- wherein, in Chemical Formulas 5-1 and 5-2,
- X2 is the same or different in each repeating unit, and is independently one selected from hydrogen, a halogen, and a substituted or unsubstituted C1 to C20 alkyl group,
- X5 to X7 are the same or different, and are each independently a substituted or unsubstituted divalent C1 to C10 aliphatic organic group, and
- R1 and R2 are the same or different, and are each independently one selected from hydrogen, and a substituted or unsubstituted C1 to C10 aliphatic organic group, and
- wherein, in Chemical Formula 2,
- X3 and X4 are the same or different, and are each independently one selected from hydrogen, a halogen, a substituted or unsubstituted C1 to C15 alkyl group, a substituted or unsubstituted C1 to C15 alkoxy group, and —SR102, wherein R102 is a substituted or unsubstituted C1 to C15 alkyl group.
12 more elements
Dependencies are inferred from the claim text.