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US 8,940,895 B2Granted
Heterocyclic fluorescent dyes and method of production thereof
AssigneeBASF SE
InventorsMarek Grzybowski, Daniel T. Gryko
Life of this patent
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Abstract
The invention relates to novel compounds of formula (III) that can be used as heterocyclic dyes of unique structure and properties. These dyes can be obtained in a three-step synthesis from simple substrates.
Claims18
A compound of formula (III):
- wherein Ar is a homo- or heteroaromatic system.
A compound of formula
- wherein Ar′ is a homo- or heteroaromatic system, which is selected from
- wherein the dotted lines are bonds to the 6-membered ring, the dotted line is a bond to a carbon atom in para-position to the nitrogen atom, the dotted line is a bond to a carbon atom in meta-position to the nitrogen atom, wherein R1, R1′ and R1″ are each independently H, halogen, cyano, C1-C25alkoxy, C1-C25alkyl substituted with a halogen atom, or C1-C25alkyl,
- R2 is H, halogen, cyano, C1-C25alkoxy, or C1-C25alkyl, R3′ is Cl, Br, or I,
- wherein R22 to R25 are each independently H, halogen, cyano, C1-C25alkoxy, C1-C25allyl substituted with a halogen atom, or C1-C25alkyl, and
- R26′ is Cl, Br, or I;
- X is O, S, Se, or NR4,
- R4 is hydrogen, C6-C18aryl;
- C6-C18aryl which is substituted by C1-C18alkyl, or C1-C18alkoxy;
- C1-C25alkyl, which may optionally be interrupted by an oxygen or sulphur atom and/or is optionally substituted by a halogen atom;
- or C7-C25arylalkyl.
7 more elements
Dependencies are inferred from the claim text.