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US 8,933,166 B2Granted
Poly(ureaurethane)s, articles and coatings prepared therefrom and methods of making the same
AssigneePPG Industries Ohio, Inc.
InventorsThomas G. Rukavina, Robert Hunia
Life of this patent
Estimating the term…
Abstract
The present invention provides poly(ureaurethane)s including a reaction product of components comprising: (a) at least one isocyanate functional ureaurethane prepolymer comprising the reaction product of: (1) at least one isocyanate functional urethane prepolymer comprising the reaction product of: (i) a first amount of at least one polyisocyanate; and (ii) a first amount of at least one branched polyol; and (2) water, to form an isocyanate functional ureaurethane prepolymer; and (b) a second amount of at least one polyisocyanate and a second amount of at least one branched polyol; compositions, coatings and articles made therefrom and methods of making the same.
Claims35
A poly(ureaurethane) consisting of a reaction product of components, wherein the components used to prepare the reaction product consist of:
- (a) at least one isocyanate functional ureaurethane prepolymer consisting of the reaction product of:
- (1) at least one isocyanate functional urethane prepolymer consisting of the reaction product of:
- (i) a first amount of at least one polyisocyanate;
- and
- (ii) a first amount of at least one branched polyol selected from the group consisting of glycerol, glycerin, tetramethylolmethane, trimethylolethane, trimethylolpropane, erythritol, pentaerythritol, dipentaerythritol, tripentaerythritol, sorbitan, and mixtures thereof;
- (2) water, wherein the equivalent ratio of isocyanate functional groups of the isocyanate functional urethane prepolymer to water ranges from 1:0.05 to 1:0.5, wherein urea linkages or units are formed by reacting the isocyanate functional groups of the isocyanate functional urethane prepolymer with water to form an isocyanate functional ureaurethane prepolymer;
- and
- (b) a second amount of at least one polyisocyanate and a second amount of at least one branched polyol, and
- (c) at least one aliphatic diol having 2 to 18 carbon atoms,
- wherein the components comprise less than about 5 weight percent of polyester polyol and less than about 5 weight percent of polyether polyol
- wherein urea linkages or units are formed by reacting the isocyanate functional groups of the isocyanate functional urethane prepolymer with water.
8 more elements
A poly(ureaurethane) consisting of a reaction product of components, wherein the components used to prepare the reaction product consist of:
- (a) at least one isocyanate functional ureaurethane prepolymer consisting of the reaction product of:
- (1) at least one isocyanate functional urethane prepolymer consisting of the reaction product of:
- (i) a first amount of at least one polyisocyanate;
- and
- (ii) a first amount of at least one branched polyol selected from the group consisting of glycerol, glycerin, tetramethylolmethane, trimethylolethane, trimethylolpropane, erythritol, pentaerythritol, dipentaerythritol, tripentaerythritol, sorbitan, and mixtures thereof;
- (2) water, wherein the equivalent ratio of isocyanate functional groups of the isocyanate functional urethane prepolymer to water ranges from 1:0.05 to 1:0.5, wherein urea linkages or units are formed by reacting the isocyanate functional groups of the isocyanate functional urethane prepolymer with water to form an isocyanate functional ureaurethane prepolymer;
- and
- (b) a second amount of at least one polyisocyanate and a second amount of at least one branched polyol, and
- (c) at least one of ethylene glycol, diethylene glycol, 1,2-ethanediol, propanediol, butanediol, pentanediol, hexanediol, heptanediol, octanediol, nonanediol, decanediol, dodecane diol, sorbitol, mannitol, cyclopentanediol, 1,4-cyclohexanediol, cyclohexanedimethanol, 1,4-benzenedimethanol, xylene glycol, hydroxybenzyl alcohol, dihydroxytoluene, 1,4-bis(hydroxyethyl)piperazine, N,N′,bis(2-hydroxyethyl)oxamide and mixtures thereof,
- wherein the components comprise less than about 5 weight percent of polyester polyol and less than about 5 weight percent of polyether polyol.
7 more elements
A poly(ureaurethane) consisting of a reaction product of components, wherein the components used to prepare the reaction product consist of:
- (a) at least one isocyanate functional ureaurethane prepolymer consisting of the reaction product of:
- (1) at least one isocyanate functional urethane prepolymer consisting of the reaction product of:
- (i) a first amount of at least one polyisocyanate;
- and
- (ii) a first amount of at least one branched polyol selected from the group consisting of glycerol, glycerin, tetramethylolmethane, trimethylolethane, trimethylolpropane, erythritol, pentaerythritol, dipentaerythritol, tripentaerythritol, sorbitan, and mixtures thereof;
- (2) water, wherein the equivalent ratio of isocyanate functional groups of the isocyanate functional urethane prepolymer to water ranges from 1:0.05 to 1:0.5, wherein urea linkages or units are formed by reacting the isocyanate functional groups of the isocyanate functional urethane prepolymer with water to form an isocyanate functional ureaurethane prepolymer;
- and
- (b) a second amount of at least one polyisocyanate and a second amount of at least one branched polyol, and
- (c) one or more polyurethane polyols, acrylamides, polyvinyl alcohols, hydroxy functional acrylates, hydroxy functional methacrylates, allyl alcohols, dihydroxy oxamides, dihydroxyamides, dihydroxy piperidines, dihydroxyethyl hydroquinones and mixtures thereof,
- wherein the components comprise less than about 5 weight percent of polyester polyol and less than about 5 weight percent of polyether polyol.
7 more elements
A poly(ureaurethane) consisting of a reaction product of components, wherein the components used to prepare the reaction product consist of:
- (a) at least one isocyanate functional ureaurethane prepolymer consisting of the reaction product of:
- (1) at least one isocyanate functional urethane prepolymer consisting of the reaction product of:
- (i) a first amount of at least one polyisocyanate;
- and
- (ii) a first amount of at least one branched polyol selected from the group consisting of glycerol, glycerin, tetramethylolmethane, trimethylolethane, trimethylolpropane, erythritol, pentaerythritol, dipentaerythritol, tripentaerythritol, sorbitan, and mixtures thereof;
- and
- (2) water, wherein the equivalent ratio of isocyanate functional groups of the isocyanate functional urethane prepolymer to water ranges from 1:0.05 to 1:0.5, wherein urea linkages or units are formed by reacting the isocyanate functional groups of the isocyanate functional urethane prepolymer with water to form an isocyanate functional ureaurethane prepolymer;
- and
- (b) a second amount of at least one polyisocyanate and a second amount of at least one branched polyol,
- wherein the components comprise less than about 5 weight percent of polyester polyol and less than about 5 weight percent of polyether polyol.
7 more elements
Dependencies are inferred from the claim text.