Pesticide thiazolyloxy substituted phenylamidine derivatives

A phenyl-amidine derivative of formula (I)

• wherein
• R1 represents H, a substituted or non substituted C1-C12-alkyl, a substituted or non substituted C2-C12-alkenyl, a substituted or non substituted C2-C12-alkynyl, SH, or a substituted or non substituted S—C1-C12-alkyl;
• R2 and R3 form together a 2-alkylated-pyrolidinyl;
• R4 represents a substituted or non substituted C1-C12-alkyl, a halogen atom, halogeno-C1-C12-alkyl, substituted or non substituted O—C1-C12-alkyl, or cyano;
• R5 represents H, a substituted or non substituted C1-C12-alkyl, a halogen atom, halogeno-C1-C12-alkyl, substituted or non substituted O—C1-C12-alkyl, or cyano;
• R6 represents a heterocycle selected from the group consisting of
• R7 represents H, halogen, nitro, cyano, substituted or non substituted phenyl, substituted or non substituted benzyl, C1-C8-alkyl, C1-C8-alkoxy, C1-C8-alkylthio, C1-C6-halo-genalkyl, C1-C6-halogen-alkoxy, C1-C6-halogenalkylthio, C1-C8-alkyl-S(O)mR11, C1-C8-alkyl-SO2NR12R13, C1-C8-alkyl-COR14, —CR15═N—O—R16, S(O)mR11, SO2NR12R13, or COR14;
• R8 represents H, halogen, cyano, substituted or non substituted phenyl, substituted or non substituted benzyl, C1-C8-alkyl, C1-C8-alkoxy, C1-C8-alkylthio, C1-C6-halo-genalkyl, C1-C6-halogenalkoxy, C1-C6-halogenalkylthio, C1-C8-alkyl-COR14, —CR15═N—O—R16, or COR14;
• R7 and R8 can form a carbocycle, which can be saturated, unsaturated or aromatic and substituted or non substituted by halogen, C1-C4-alkyl, C1-C4-halogenalkyl, or C1-C4-alkoxyalkyl;
• R9 represents H, halogen, cyano, substituted phenyl, substituted or non substituted benzyl, C1-C8-alkyl, C1-C8-alkoxy, C1-C8-alkylthio, C1-C6-halogenalkyl, C1-C6-halogenalkoxy, C1-C6-halogenalkylthio, C1-C8-alkyl-COR14, —CR15═N—O—R16, or COR14;
• R10 represents H, halogen, cyano, substituted or non substituted phenyl, substituted or non substituted benzyl, substituted or non substituted pyridyl, C1-C8-alkyl, C1-C8-alkoxy, C1-C8-alkylthio, C1-C6-halogenalkyl, C1-C6-halogenalkoxy, C1-C6-halogenalkylthio, C1-C8-alkyl-S(O)mR11, C1-C8-alkyl-SO2NR12R13, C1-C8-alkyl-COR14, —CR15═N—O—R16, S(O)mR11, SO2NR12R13, or COR14;
• m represents 0, 1, or 2;
• R11 represents C1-C8-alkyl or C3-C6-cycloalkyl;
• R12 represents H, C1-C8-alkyl or C3-C6-cycloalkyl;
• R13 represents H, C1-C8-alkyl or C3-C6-cycloalkyl;
• R14 represents H, substituted or non substituted, branched or linear C1-C8-alkyl, or C1-C8-alkoxy;
• R15 represents H, C1-C8-alkyl or C3-C6-cycloalkyl;
• R16 represents H, C1-C8-alkyl, C3-C6-cycloalkyl, C1-C8-alkoxy, or substituted or non substituted benzyl;
• R12 and R13 can form a 5- or 6-membered heterocycle, which can further comprise one or more heteroatoms selected in the group consisting of O, N, and S;
• R15 and R16 can form a heterocyclic 5- or 6-membered ring, optionally including at least one further heteroatom;
• or a salt, an N-oxyde, a metallic complex, a metalloidic complex and/or an optically active or geometric isomer thereof.

A phenyl-amidine derivative of formula (I):

• wherein
• R1 represents H, a substituted or non substituted C1-C12-alkyl, a substituted or non substituted C2-C12-alkenyl, a substituted or non substituted C2-C12-alkynyl, SH, or a substituted or non substituted S—C1-C12-alkyl;
• R2 represents methyl;
• R3 represents a substituted or non substituted C2-C12-alkyl, substituted or non substituted C3-C6-cycloalkyl, substituted or non substituted C2-C12-alkenyl, substituted or non substituted C2-C12-alkynyl, halogeno-C1-C12-alkyl;
• or
• R1 and R2, R1 and R3, or R2 and R3 can form together a substituted or non substituted 5- to 7-membered heterocycle;
• R4 represents a substituted or non substituted C1-C12-alkyl, a halogen atom, halogeno-C1-C12-alkyl, substituted or non substituted 0-C1-C12-alkyl, or cyano;
• R5 represents H, a substituted or non substituted C1-C12-alkyl, a halogen atom, halogeno-C1-C12-alkyl, substituted or non substituted O—C1-C12-alkyl, or cyano;
• R6 represents the following:
• wherein
• R9 represents H, halogen, cyano, phenyl substituted by F, Cl, Br, I, C1-C4-halogenoalkyl, C1-C4-alkoxy or C1-C4-halogenoalkoxy;
• substituted or non substituted benzyl, C1-C8-alkyl, C1-C8-alkoxy, C1-C8-alkylthio, C1-C6-halo-genalkyl, C1-C6-halogenalkoxy, C1-C6-halogenalkylthio, C1-C8-alkyl-COR14, —CR15═N—O—R16, or COR14;
• R14 represents H, substituted or non substituted, branched or linear C1-C8-alkyl, C1-C8-alkoxy;
• R15 represents H, C1-C8-alkyl or C3-C6-cycloalkyl;
• R16 represents H, C1-C8-alkyl, C3-C6-cycloalkyl, C1-C8-alkoxy, or substituted or non substituted benzyl;
• and
• R15 and R16 can form a heterocyclic 5- or 6-membered ring, optionally including at least one further heteroatom;
• or a salt, an N-oxyde, a metallic complex, a metalloidic complex and/or an optically active or geometric isomer thereof.