Non-caking salt composition, preparation process and use thereof
AssigneeAkzo Nobel Chemicals International B.V.
InventorsHendrikus Wilhelmus Bakkenes, Roberto Aloysius Gerardus Maria Bergevoet, Johannes Albertus Maria Meijer, Maria Steensma
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Abstract
The present invention relates to a sodium chloride composition comprising an iron complex of tartaric acid wherein between 55 and 90% by weight of the tartaric acid is meso-tartaric acid. The present invention furthermore relates to a process to prepare such a sodium chloride composition and to the use of such a sodium chloride composition.
Claims8
A process for the preparation of a sodium chloride composition comprising an iron complex of tartaric acid wherein between 55 and 90% by weight of the tartaric acid is meso-tartaric acid, the process comprising the steps of spraying an aqueous treatment solution comprising an iron complex of tartaric acid, with between 55 and 90% by weight of said tartaric acid being meso-tartaric acid, and having a pH of between 3 and 5 onto the sodium chloride composition;
- wherein the aqueous treatment solution comprising the iron complex of tartaric acid, with between 55 and 90% by weight of said tartaric acid being meso-tartaric acid, is obtained by a process comprising:
- (i) preparing an aqueous mixture comprising between 35 and 65% by weight of a di-alkali metal salt of L-tartaric acid, a di-alkali metal salt of D-tartaric acid, or a mixture of di-alkali metal salts of L-tartaric acid, D-tartaric acid, and optionally meso-tartaric acid, and between 2 and 15% by weight of an alkali metal or alkaline metal hydroxide,
- (ii) stirring and heating the aqueous mixture for between 3 and 200 hours to a temperature of between 100° C. and its boiling point until between 55 and 90% by weight of tartaric acid has been converted to meso-tartaric acid,
- (iii) cooling and optionally adding water,
- (iv) optionally adjusting the pH to a pH of between 5 and 9,
- (v) stirring and admixing the obtained mixture with an iron(II) salt, an iron(III) salt or a mixture thereof,
- (vi) and if the pH is outside the range of between 3 and 5, adjusting the pH of the mixture from step (v) to a pH of between 3 and 5.
Dependencies are inferred from the claim text.