Cyclopara (hetero) arylene compound and method for producing same
AssigneeKyoto University
InventorShigeru Yamago
Life of this patent
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Abstract
Provided are a cyclopara(hetero)arylene compound and a method for producing the same. More specifically, provided is a cycloparaphenylene compound represented by Formula (I): wherein Ar1, Ar2, Ar3, and Ar4 are the same or different, and represent an optionally substituted divalent aromatic group or an optionally substituted divalent heteroaromatic group, and n1, n2, n3, and n4 are the same or different, and represent an integer of 1 or more.
Claims6
A compound represented by Formula (I):
- wherein Ar1, Ar2, Ar3, and Ar4 are the same or different, and represent an optionally substituted divalent aromatic group, and
- n1, n2, n3, and n4 are the same or different, and represent an integer of 1 to 30,
- with the proviso that in the case of Ar1=Ar2=Ar3=Ar4=1,4-phenylene, n1+n2+n3+n4 is a number other than 9, 12, and 18.
A compound represented by the following Formula (III):
- wherein Ar1, Ar2, Ar3, and Ar4 are the same or different, and represent an optionally substituted divalent aromatic group,
- M is the same or different, and represents Pt, Pd, or Ni,
- L is the same or different, and represents a ligand capable of coordinating with M, provided that, when M is Pt, L represents cyclooctadiene (cod), norbornadiene (nbd), ethylenediamine, and N-alkyl derivatives thereof, 2,2′-, 3,3′-, 4,4′-, 2,3′-, 2,4′-, or 3,4′-bipyridine, or alkyl-substituted derivatives thereof;
- 1,10-phenanthroline, triphenylphosphine, tributylphosphine, dimethylphenylphosphine, 1,1′-bis(diaryl)ferrocenylphosphine, such as 1,1′-bis(diphenylphosphino)ferrocene (dppf);
- diarylphosphinoethane, such as diphenylphosphinoethane;
- diphenylphosphinobutane, Xantphos, 2,2′-bis(diphenylphosphino)-1,1′-binaphthalene, tricyclohexylphosphine, cyclododecatriene, norbornene, 1,5-hexadiene, benzonitrile, butadiene, dimethyl acetylenedicarboxylate, dibenzylideneacetone, 1,5-bis(diphenylphosphino)pentane, diphenylmethylphosphine, and derivatives thereof, and
- n1, n2, n3, and n4 are the same or different, and represent an integer of 1 to 30.
A method for producing a compound of Formula (I), comprising eliminating M(L) from a compound of Formula (III):
- wherein Ar1, Ar2, Ar3, and Ar4 are the same or different, and represent an optionally substituted divalent aromatic group,
- n1, n2, n3, and n4 are the same or different, and represent an integer of 1 to 30,
- M is the same or different, and represents Pt, Pd, or Ni, and
- L is the same or different, and represents a ligand capable of coordinating with M.
Dependencies are inferred from the claim text.