Process of manufacturing benzobisthiazole building blocks for conjugated polymers
AssigneePhillips 66 Company
InventorHui Huang
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Abstract
A process comprising the step of synthesizing 2,6-dibromo-4,8-dihexylbenzo[1,2-d:4,5-d′]bis(thiazole) from 2,5-dihyxylbenzene-1,4-diamine.
Drawings
Claims9
A process comprising the step of:
- (a) synthesizing 2,6-dibromo-4,8-dihexylbenzo[1,2-d:4,5-d′]bis(thiazole) from 2,5-dihexylbenzene-1,4-diamine.
A process comprising the steps of:
- (a) synthesizing 2,5-dihexylbenzene-1,4-diamine from 1,4-dibromohexyl benzene;
- (b) synthesizing 1,1′-(2,5-dihexyl-1,4-phenylene)bis(thiourea) from 2,5-dihyxylbenzene-1,4-diamine;
- (c) synthesizing 4,8-dihexylbenzo[1,2-d:4,5-d′]bis(thiazole)-2,6-diamine from 1,1′-(2,5-dihexyl-1,4-phenylene)bis(thiourea);
- and
- (d) synthesizing 2,6-dibromo-4,8-dihexylbenzo[1,2-d:4,5-d′]bis(thiazole) from 4,8-dihexylbenzo[1,2-d:4,5-d′]bis(thiazole)-2,6-diamine.
A process comprising the steps of:
- (a) synthesizing 2,5-dihexylbenzene-1,4-diamine from 1,4-dibromohexyl benzene;
- (b) synthesizing N,N′-(((2,5-dihexyl-1,4-phenylene)bis(azanediyl))bis(carbonothioyl))dibenzamide from 2,5-dihyxylbenzene-1,4-diamine;
- (c) synthesizing 1,1′-(2,5-dihexyl-1,4-phenylene)bis(thiourea) from N,N′-(((2,5-dihexyl-1,4-phenylene)bis(azanediyl))bis(carbonothioyl))dibenzamide;
- (d) synthesizing 4,8-dihexylbenzo[1,2-d:4,5-d′]bis(thiazole)-2,6-diamine from 1,1′-(2,5-dihexyl-1,4-phenylene)bis(thiourea);
- and
- (e) synthesizing 2,6-dibromo-4,8-dihexylbenzo[1,2-d:4,5-d′]bis(thiazole) from 4,8-dihexylbenzo[1,2-d:4,5-d′]bis(thiazole)-2,6-diamine.
Dependencies are inferred from the claim text.