Acrylic adhesive composition, and pressure-sensitive adhesive sheet employing the same
AssigneeNational Institute for Materials Science
InventorsTakashi Oda, Kenji Tamura
Life of this patent
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Abstract
There is provided an acrylic adhesive composition which comprises: (A) a vinyl polymer comprising a homopolymer or a copolymer of an alkyl (meth)acrylate having a C4 to C14 alkyl group; (B) an organophilic layered double hydroxide organically treated with an organic anion; and (C) a crosslinking agent. Therefore the obtained adhesive composition has sufficient adhesiveness to an object, excellent heat resistance and excellent adhesive properties particularly at higher temperatures, and is substantially free from variations in adhesiveness.
Claims9
An acrylic pressure-sensitive adhesive composition comprising:
- (A) a copolymer of butyl acrylate and acrylic acid;
- (B) an organophilic layered double hydroxide organically treated with an organic anion;
- and
- (C) a crosslinking agent,
- wherein the layered double hydroxide to be organically treated to provide the component (B) is a non-stoichiometric compound represented by one of the following general formula (1) and (2):
- [M2+1-xM3+x(OH)2]x+[An−x/n.mH2O]x− (1)
- [Li+1-xM3+x(OH)2](2x−1)+[An−(2x-1)/n.mH2O](2x−1)− (2)
- wherein M2+ is a metal ion of at least one divalent metal selected from the group consisting of Mg, Ca, Mn, Fe, Co, Ni, Cu and Zn;
- M3+ is a metal ion of at least one trivalent metal selected from the group consisting of Al, Fe, Cr, Mn, Co, Ni, La and Ga;
- An− is an n-valent inorganic anion selected from the group consisting of OH−, ClO3−, ClO4−, F−, Cl−, Br−, I−, CO32−, NO3− and SO42−;
- x is a positive number with 0<x<0.5;
- m is a positive number with 0<m;
- and n is a valence of the inorganic anion,
- wherein the component (B) is present in a proportion of from 3 parts by weight to 5 parts by weight based on 100 parts by weight of the component (A),
- wherein the component (C) is present in a proportion of from 0.1 to 3 parts by weight based on 100 parts by weight of the component (A), and
- wherein an adhesive strength of the acrylic pressure sensitive adhesive at 23° C. is from 3.5 to 6.8 N/20 mm.
Dependencies are inferred from the claim text.