Pigment dispersion and method for producing resin-treated pigment in the pigment dispersion
AssigneesDainichiseika Color & Chemicals Mfg. Co., Ltd., Kyoto University
InventorsHiroyuki Shimanaka, Yoshikazu Murakami, Shinichiro Aoyagi, Atsushi Goto, Yoshinobu Tsujii
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Abstract
Disclosed are a resin-treated pigment characterized in that the resin-treated pigment comprises a pigment and a polymer of an unsaturated bond-containing monomer, a weight ratio of the pigment to the polymer (pigment:polymer) is from 50 to 95 to from 5 to 50, and the polymer is a block copolymer comprising from 5 to 70 mass % of an addition-polymerizable monomer having a UV-absorbing group; a production process of the resin-treated pigment; and a pigment dispersion using the resin-treated pigment.
Claims10
A pigment dispersion for use as a colorant for an oil-based product, the pigment dispersion comprising:
- a dispersion medium, which comprises at least one medium selected from the group consisting of monomers, organic solvents, thermoplastic resins, thermosetting resins, and UV/ER-curable resins;
- and
- a resin-treated pigment dispersed in the dispersion medium,
- wherein a resin-treated pigment comprises:
- a pigment;
- and
- a polymer of an unsaturated bond-containing monomer,
- wherein the polymer is an acrylic A-B block copolymer, which is formed of a polymer block A, which is formed of an A chain, and a polymer block B formed of a B chain that comprises an addition-polymerizable monomer having a UV-absorbing group in an amount from 5 to 70 mass % relative to a total amount of monomers constituting the polymer,
- wherein the UV-absorbing group is a UV-absorbing benzotriazole group, a UV-absorbing triazine group, or a UV-absorbing benzophenone group,
- the acrylic A-B block copolymer contains in its structure, a plenty of aromatic rings provided by the UV-absorbing group, and the aromatic rings are concentrated in the B chain of the acrylic A-B block copolymer,
- the polymer block A formed of the A chain in the A-B block copolymer is an acrylic polymer that is miscible with the dispersion medium, and
- the polymer block B formed of the B chain in the A-B block copolymer is an acrylic polymer comprising the addition-polymerizable monomer having the UV-absorbing group, and the polymer block B includes 70 mass % or more of a total mass of the addition-polymerizable monomer included in the A-B block copolymer, and
- a weight ratio of the pigment to the polymer (pigment:polymer) is from 50 to 95 of the pigment to from 50 to 5 of the polymer, wherein the pigment is encapsulated with the acrylic A-B block copolymer.
Dependencies are inferred from the claim text.