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US 8,894,911 B2Granted
Low melt flow index resins for injections-stretch-blow-moulding
AssigneeTotal Research & Technology Feluy
InventorsLaurent Duranel, Emmanuel Humbeeck
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Abstract
The present invention discloses a method for preparing vials, preferably medical vials by two-stage injection-stretch-blow-molding with a random copolymer of propylene having a melt index MI2 of from 1 to 3 dg/min and an ethylene content of from 2 to 3.5 wt % based on the weight of the resin, and wherein the preform injection temperature is of at least 280° C.
Claims15
A method for preparing vials comprising:
- providing a Ziegler-Natta formed random copolymer of propylene and from 2 to 3.5 wt. % ethylene exhibiting a melt index (MI2) of from 1 to 3 dg/min., wherein an entirety of the random copolymer is prepared with a Ziegler-Natta catalyst;
- and
- two-stage injection-stretch-blow-moulding the random copolymer to form a vial, wherein the two-stage injection-stretch-blow-moulding includes forming a perform at a preform injection temperature of at least 330° C. and a mould filling rate over gate diameter ratio that is at least 5 cc/s/mm;
- and wherein the two-stage-stretch-blow moulding comprises the following steps:
- providing the preform by injection moulding on a multi-cavity mould;
- cooling the preform to room temperature;
- transporting the preform to the stretch-blow moulding machine;
- re-heating the preform in the stretch-blow moulding machine;
- optionally passing the heated preform through an equilibration zone to allow the heat to disperse evenly through the preform wall;
- optionally, submitting the preform to a pre-blow step;
- and
- stretching the preform axially by a centre rod and simultaneously orienting the preform radially by high pressure air, wherein a ratio of the centre rod diameter to the diameter of the preform is within 3% of 2/3.
9 more elements
Dependencies are inferred from the claim text.