Laundry care compositions containing dyes

A laundry care composition comprising from about 0.00001 wt % to about 0.5 wt % thiophene azo carboxylate dye having the structure of Formula I:

• wherein R1 and R2 are independently selected from [(CH2CR′HO)x(CH2CR″HO)yQ], C1-12 alkyl, C6-10 aryl, or C7-C22 aryl alkyl, with the requirement that at least one of R1 and R2 is [(CH2CR′HO)x(CH2CR″HO)yQ],
• wherein R′ is selected from the group consisting of H, C1-4 alkyl, CH2O(CH2CH2O)zQ, phenyl and CH2OR5;
• wherein R″ is selected from the group consisting of H, C1-4 alkyl, CH2O(CH2CH2O)zQ, phenyl and CH2OR5;
• wherein 1≦x+y−50;
• wherein y≧1;
• wherein −z=0 to 20;
• and
• wherein Q is selected from the group consisting of H and Y wherein Y is as defined below;
• with the proviso that the dye comprises at least one Q group that is Y;
• each R5 is selected from the group consisting of C1-C16 linear or branched alkyl, C6-C14 aryl, C7-C16 arylalkyl and mixtures thereof;
• and wherein Y is an organic radical represented by Formula II
• wherein independently for each Y group,
• M is H or a charge balancing cation;
• m is 0 to 5;
• n is 0 to 5;
• the sum of m+n is 1 to 10;
• each R8 is independently selected from the group consisting of H and C3-18 alkenyl, and wherein at least one R8 group is not H, and a laundry care adjunct wherein the laundry care adjunct comprises a fluorescent agent selected from:
• sodium 2 (4-styryl-3-sulfophenyl)-2H-napthol[1,2-djtriazole, disodium 4,4′-bis{[(4-anilino-6-{N methyl-N-2 hydroxyethyl)amino 1,3,5-triazin-2-yl)]amino}stilbeno-2-2′ disulfonate, disodium 4,4′-bis[(4-anilino-6-morpholino-1,3,5-triazin-2-yl)amino]stilbene-2-2′ disulfonate, or disodium 4,4′-bis(2-sulfostyryl)biphenyl, in an amount of from about 0.005 to about 2 wt % of the laundry care composition.