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US 8,828,914 B2Granted
Methods for controlling depolymerization of polymer compositions
AssigneeRhodia Operations
InventorsSubramanian Kesavan, Gary Woodward, Adedamola Adedeji, Timothy Curtis, Francis Smith
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Abstract
A method of controlling or arresting the rate of depolymerization of a polymer composition during a biocide treatment by controlling the pH of the composition, and use of such methods in oilfield applications.
Claims21
A method of controlling the rate of depolymerization of a polymer in an aqueous polymer composition comprising:
- obtaining an aqueous mixture comprising a tetrakis(hydroxymethyl)phosphonium salt (THP salt) in an amount of 250 ppm or more,
- adjusting the pH of the THP salt-water mixture to a pH range of from about 4 to about 8;
- and contacting the THP salt-water mixture with the polymer to form an aqueous polymer composition, wherein the polymer is selected from the group consisting of guar, carboxymethyl guar, hydroxyethyl guar, hydroxypropyl guar, carboxymethylhydroxypropyl guar, cationic guar, hydrophobically modified guar, hydrophobically modified carboxymethyl guar, hydrophobically modified hydroxyethyl guar, hydrophobically modified hydroxypropyl guar, cationic hydrophobically modified hydroxypropyl guar, hydrophobically modified carboxymethylhydroxypropyl guar, and hydrophobically modified cationic guar.
A method of controlling the rate of depolymerization of a polymer during a biocide treatment in preparing an oil field application fluid, comprising:
- contacting a pH buffer with water to form a first aqueous mixture, wherein the pH buffer is present in an amount effective to maintain the first aqueous mixture within a pH range of from about 4 to about 8;
- contacting the first aqueous mixture with an amount of a THP salt to form a second aqueous mixture wherein the THP salt is present in an amount of 250 ppm or more and is effective to reduce bacteria count in the second aqueous mixture, wherein pH of the second aqueous mixture is maintained within a pH range of from about 4 to about 8, and contacting the second aqueous mixture with the polymer, wherein the polymer is selected from the group consisting of guar, carboxymethyl guar, hydroxyethyl guar, hydroxypropyl guar, carboxymethylhydroxypropyl guar, cationic guar, hydrophobically modified guar, hydrophobically modified carboxymethyl guar, hydrophobically modified hydroxyethyl guar, hydrophobically modified hydroxypropyl guar, cationic hydrophobically modified hydroxypropyl guar, hydrophobically modified carboxymethylhydroxypropyl guar, and hydrophobically modified cationic guar.
Dependencies are inferred from the claim text.