Lubricant composition, fluorine-based compound, and use thereof
AssigneeFUJIFILM Corporation
InventorsHiroki Sugiura, Masayuki Harada, Ken Kawata, Akiko Hattori, Atsushi Tatsugawa
Life of this patent
Estimating the term…
Abstract
Disclosed is a lubricant composition comprising at least one kind of compound represented by following formula (1): where X represents a cyclic group that may be substituted; Y represents a divalent or higher-valent linking group having at least one polar group and having no aromatic cyclic group; p1 represents an integer of 1 to 4; p2, p3, and p4 each represent an integer of 0 to 4; q represents an integer of 0 to 30; n represents an integer of 1 to 10; s represents an integer of 1 to 4; and t represents an integer of 2 to 10.
Claims35
A lubricant composition comprising at least one kind of compound represented by following formula (1):
- where X represents a cyclic group that may be substituted;
- Y represents a divalent or higher-valent linking group having at least one polar group and having no aromatic cyclic group;
- p1 represents an integer of 1 to 4;
- p2, p3, and p4 each represents an integer of 0 to 4;
- q represents an integer of 1 to 30;
- n represents an integer of 1 to 10;
- s represents an integer of 1 to 4;
- and t represents an integer of 2 to 10, provided that the binding sequence of —(CF2)p1—, —(CF)p2—, —[CF(CF3)]p3—, and —[C(CF3)2]p4— that constitute —{(CF2)p1(CF)p2[CF(CF3)]p3[C(CF3)2]p4O}— in formula (1) is not limited, and —{(CF2)p1(CF)p2[CF(CF3)]p3 [C(CF3)2]p4O}— means a perfluoroalkyleneoxy group in which a perfluoroalkylene unit selected from —(CF2)p1—, —(CF)p2—, —[CF(CF3)]p3—, and —[C(CF3)2]p4— and an oxygen atom are distributed randomly;
- when q is 2 or more, a plurality of —{(CF2)p1(CF)p2[CF(CF3)]p3[C(CF3)2]p4O}— may be the same as or different from each other;
- when s is 2 or more, a plurality of n's and q's may be the same as or different from each other;
- and when t is 2 or more, a plurality of s's and Y's may be the same as or different from each other;
- and when p2 is 1 or more, the perfluoroalkyleneoxy group has a branched structure.
A fluorine—based compound represented by following formula (1):
- where X represents a cyclic group which may be substituted;
- Y represents a divalent or higher-valent linking group having at least one polar group and having no aromatic cyclic group;
- p1 represents an integer of 1 to 4;
- p2, p3, and p4each represents an integer of 0 to 4;
- q represents an integer of 1 to 30;
- n represents an integer of 1 to 10;
- s represents an integer of 1 to 4;
- and t represents an integer of 2 to 10, provided that the binding sequence of —(CF2)p1—, —(CF)p2—, —[CF(CF3)]p3—, and —[C(CF3)2]p4— that constitute —{(CF2)p1(CF)p2[CF(CF3)]p3[C(CF3)2]p4O}— in the formula (1) is not limited, and —{(CF2)p1(CF)p2[CF(CF3)]p3[C(CF3)2]p4O}— means a perfluoroalkyleneoxy group in which a perfluoroalkylene unit selected from —(CF2)p1—, —(CF)p2—, —[CF(CF3)]p3—, and —[C(CF3)2]p4— and an oxygen atom are distributed randomly;
- when q is 2 or more, a plurality of —{(CF2)p1(CF)p2[CF(CF3)]p3[C(CF3)2]p4O}— may be the same as or different from each other;
- when s is 2 or more, a plurality of n's and q's may be the same as or different from each other;
- and when t is 2 or more, a plurality of s's and Y's may be the same as or different from each other;
- and when p2is 1 or more, the perfluoroalkyleneoxy group has a branched structure.
A fluorine-based compound represented by any of following formulae (1a) to (1f):
- where, in the formulae, X represents a cyclic group which may be substituted;
- W1 and W2 each represents a polar group, or a group having a polar group including one or more polar groups, one or more methylene groups (CH2), one or more methine groups (CH), one or more quaternary carbon atoms, or a group formed by combination of two or more thereof;
- k represents 0 or 1;
- L1 to L3 each represents —CH2—, —OCH2—, —CH2O—, or —C(═O)—;
- Z represents an oxygen atom or NH;
- m represents an integer of 2 to 4;
- n represents an integer of 1 to 10;
- t represents an integer of 2 to 10;
- and q represents an integer of 1 to 30, provided that a plurality of L1 to L3, k, W1, W2, Z, m, n, and q each present in the formula may be the same as or different from each other.
A fluorine-based compound represented by any of following formulae (1g) to (1l):
- where in the formulae, X represents a cyclic group which may be substituted;
- W1 and W2 each represents a polar group, or a group having a polar group including one or more polar groups, one or more methylene groups (CH2), one or more methine groups (CH), one or more quaternary carbon atoms, or a group formed by combination of two or more thereof;
- k represents 0 or 1;
- L1 to L3 each represents —CH2—, —OCH2—, —CH2O—, or —C(═O)—;
- Z represents an oxygen atom or NH;
- v represents an integer of 1 to 20;
- and w represents an integer of 1 to 20, provided that (v+w) is an integer of 1 to 30;
- the binding sequence of (CF2O) and (CF2CF2O) is not limited;
- n represents an integer of 1 to 10;
- and t represents an integer of 2 to 10, provided that a plurality of L1 to L3, k, W1, W2, Z, v, w, and n each present in the formula may be the same as or different from each other.
A fluorine-based compound of any of the following L-1 to L-14:
- where, in the formula (L-14), m represents an integer of 1 to 20, n represents an integer of 1 to 20, provided that (m+n) is an integer of 1 to 30and the binding sequence of (CF2O) and (CF2CF2O) is not limited.
Dependencies are inferred from the claim text.