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US 8,803,134 B2Granted
Biscarbazole derivatives and organic electroluminescence
AssigneeIdemitsu Kosan Co., Ltd.
InventorsTetsuya Inoue, Mitsunori Ito, Tomoki Kato, Kumiko Hibino, Kazuki Nishimura, Takayasu Sado
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Abstract
Provided are an organic electroluminescence device having high current efficiency and a long lifetime, and a biscarbazole derivative for realizing the device. The biscarbazole derivative has a specific substituent. The organic EL device has a plurality of organic thin-film layers including a light emitting layer between a cathode and an anode, and at least one layer of the organic thin-film layers contains the biscarbazole derivative.
Claims33
A biscarbazole derivative, which is represented by the following formula (1):
- in the formula (1):
- A1 and A2 each independently represent a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted aromatic heterocyclic group having 2 to 30 ring carbon atoms;
- Y1 to Y16 each independently represent C(R) or a nitrogen atom, and each R independently represents a hydrogen atom, a substituent, or a bond to a carbazole skeleton;
- and
- L1 and L2 each independently represent a single bond, a substituted or unsubstituted, divalent aromatic hydrocarbon group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted, divalent aromatic heterocyclic group having 2 to 30 ring carbon atoms,
- provided that:
- at least one of A1 and A2 represents a substituted or unsubstituted benzofuranyl group, a substituted or unsubstituted dibenzofuranyl group, a substituted or unsubstituted benzothiophenyl group, a substituted or unsubstituted dibenzothiophenyl group, a substituted or unsubstituted benzonaphthofuranyl group, or a substituted or unsubstituted benzonaphthothiophenyl group;
- when one of A1 and A2 represents a dibenzofuranyl group or a dibenzothiophenyl group, the other represents a substituted or unsubstituted aromatic hydrocarbon group having 6 to 30 ring carbon atoms, or a substituted or unsubstituted benzofuranyl group, a substituted or unsubstituted benzothiophenyl group, a substituted or unsubstituted benzonaphthofuranyl group, or a substituted or unsubstituted benzonaphthothiophenyl group;
- and
- when Y6 and Y11 are bonded to each other, the following conditions (i) and (ii) are satisfied:
- (i) when A1 represents a dibenzofuranyl group or a dibenzothiophenyl group, L1 represents an optionally substituted divalent aromatic hydrocarbon group having 6 to 30 ring carbon atoms;
- and
- (ii) when A2 represents a dibenzofuranyl group or a dibenzothiophenyl group, L2 represents an optionally substituted divalent aromatic hydrocarbon group having 6 to 30 ring carbon atoms.
10 more elements
Dependencies are inferred from the claim text.