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US 8,802,775 B2Granted
Silane-modified binder dispersions
AssigneeBayer MaterialScience AG
InventorsThomas Münzmay, Arno Nennemann, Christoph Irle, Nusret Yuva
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Abstract
The invention relates to aqueous formulations comprising silane-modified polymeric binders having a siloxane content and inorganic nanoparticles, a process for the preparation thereof and the use thereof for the preparation of aqueous coating compositions.
Claims8
A method for stabilizing inorganic nanoparticles, wherein the method comprises forming an aqueous formulation comprising
- A) a silane-modified copolymer a1) comprising groups of general formula (1)
- —Si(R1O)2R2 (1)
- wherein
- R1 is a C2- to C8-alkyl radical;
- and
- R2 is (R1O) or a C1- to C5-alkyl radical,
- and
- wherein the silane-modified copolymer is built up from
- I) a hydroxy-functional hydrophobic polymer containing as builder monomers
- Ia) (meth)acrylic acid esters having C1- to C18-hydrocarbon radicals in the alcohol part and/or vinylaromatics and/or vinyl esters;
- Ib) hydroxy-functional monomers;
- and
- IS1) silane-functional monomers capable of polymerization;
- and
- II) a hydroxy-functional hydrophilic polymer containing as builder components
- IIa) (meth)acrylic acid esters having C1- to C18-hydrocarbon radicals in the alcohol part and/or vinylaromatics and/or vinyl esters;
- IIb) hydroxy-functional monomers;
- and
- IIc) acid-functional monomers,
- and a polyorganosiloxane a2) containing hydroxyl groups;
- B) inorganic particles, which are optionally surface modified, and having an average particle size (z-mean), as determined by means of dynamic light scattering in dispersion, of less than 200 nm, wherein said inorganic particles B) are inorganic nanoparticles in a colloidally disperse form in organic solvents or in water;
- and
- C) water;
- wherein the inorganic particles are introduced by mechanical stirring.
21 more elements
Dependencies are inferred from the claim text.