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US 8,802,285 B2Granted
Organic electrolytic solution comprising cycloolefin monomer and lithium battery employing the same
AssigneeSamsung SDI Co., Ltd.
InventorsYoung-gyoon Ryu, Yoon-sok Kang, Dong-joon Lee, Seok-soo Lee, Seung-sik Hwang
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Abstract
An organic electrolytic solution includes a lithium salt; an organic solvent containing a high dielectric constant solvent; and a polymerizable cycloolefin monomer, and an lithium battery employing the same. The organic electrolytic solution prevents decomposition of an electrolyte, and thus the lithium battery employing the organic electrolytic solution has improved cycle characteristics and lifetime.
Claims2
A lithium battery, comprising:
- a cathode;
- an anode;
- and
- an organic electrolytic solution,
- wherein a film is present on a surface of the anode or cathode, the film being a polymerization product of a cycloolefin monomer, wherein the polymerization product of the cycloolefin monomer is a compound represented by Formula 13:
- wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, and R10 in Formula 13 are each independently a hydrogen atom, a halogen atom, a hydroxyl group, a carboxyl group, an amino group, a cyano group, a substituted or unsubstituted C1-20 alkyl group, a substituted or unsubstituted C1-20 alkoxy group, a substituted or unsubstituted C2-20 alkenyl group, a substituted or unsubstituted C2-20 alkynyl group, a substituted or unsubstituted C6-30 aryl group, a substituted or unsubstituted C7-30 arylalkyl group, a substituted or unsubstituted C7-30 alkylaryl group, a substituted or unsubstituted C1-20 heteroalkyl group, a substituted or unsubstituted C4-30 heteroaryl group, a C7-30 arylcarbonyl group, a C2-20 alkyloxycarbonyl group, a C2-20 alkylcarbonyl group, or a C2-20 alkylcarbonyloxy group,
- wherein R4 and R5 together may also represent ═O, R7 and R9 may also be bound to each other to form a five-membered ring or six-membered ring structure, or a hetero cyclic structure, and R8 and R10 together may also represent single bond, and
- n is an integer of 1 to 100,000.
5 more elements
A lithium battery, comprising:
- a cathode;
- an anode;
- and
- an organic electrolytic solution,
- wherein a film is present on a surface of the anode or cathode, the film being a polymerization product of a cycloolefin monomer, wherein the polymerization product of the cycloolefin monomer is a compound represented by Formula 14:
- wherein R1, R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, and R12 in Formula 14 are each independently a hydrogen atom, a halogen atom, a hydroxyl group, a carboxyl group, an amino group, a cyano group, a substituted or unsubstituted C1-20 alkyl group, a substituted or unsubstituted C1-20 alkoxy group, a substituted or unsubstituted C2-20 alkenyl group, a substituted or unsubstituted C2-20 alkynyl group, a substituted or unsubstituted C6-30 aryl group, a substituted or unsubstituted C7-30 arylalkyl group, a substituted or unsubstituted C7-30 alkylaryl group, a substituted or unsubstituted C1-20 heteroalkyl group, or a substituted or unsubstituted C4-30 heteroaryl group,
- wherein R4 and R5 together may also represent ═O, and R10 and R11 together may also represent ═O,
- n is an integer of from 1 to 100,000, and
- k is an integer of from 1 to 100,000.
6 more elements
Dependencies are inferred from the claim text.