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US 8,796,490 B2Granted
Method of producing a triarylamine compound
AssigneeFUJIFILM Corporation
InventorsKazunari Yagi, Kazumi Nii
Life of this patent
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Abstract
A production method of a triarylamine compound including: producing a particular triarylamine compound by performing a reaction between a specific halogenated triarylamine compound and a specific olefin in the presence of palladium and alkylphosphine.
Claims8
A production method of a triarylamine compound, comprising the steps of:
- providing a compound represented by following formula (5) and a compound represented by following formula (2);
- and
- allowing the compound represented by formula (5) to react with the compound represented by formula (2) in the presence of palladium and alkylphosphine, to form a compound represented by following formula (6),
- wherein, in formula (5), Ar2, Ar3, Ar5, and Ar6 each independently represent an aryl group which may have a methyl group, an ethyl group, a propyl group, and/or a butyl group;
- and Ar4 represents an arylene group or a heteroarylene group, each of which may be substituted, selected from the group consisting of the following groups 5-1 to 5-11:
- wherein, in the groups 5-1 to 5-11, * indicates a bonding site;
- X represents a halogen atom substituted onto Ar2, Ar3, Ar5 and/or Ar6;
- if a plurality of X is present, the plurality of X may be the same or different halogen atom from each other;
- and m is 3 to 4,
- wherein, in formula (2), R1 represents a hydrogen atom or an alkyl group;
- R2 represents a hydrogen atom or a methyl group;
- and R3 represents a hydrogen atom, an alkoxy group, an aryl group, an amino group, or an alkyl group, and
- wherein, in formula (6), Ar2, Ar3, Ar5, Ar6, X and m have the same meanings as those of formula (5), respectively;
- R1, R2 and R3 have the same meanings as those of formula (2), respectively;
- and n represents a natural number equal to or less than m.
12 more elements
A production method of a triarylamine compound, comprising the steps of:
- providing the following compound 202 and butyl acrylate;
- and
- allowing compound 202 to react with butyl acrylate in the presence of palladium and alkylphosphine, to form the following compound 203,
A production method of a triarylamine compound, comprising the steps of:
- providing a compound selected from the group consisting of formulae 1-1, 1-4 to 1-8, 1-12 to 1-14, 1-16 and 1-18 and a compound represented by formula (2);
- and
- allowing the compound selected from the group consisting of formulae 1-1, 1-4 to 1-8, 1-12 to 1-14, 1-16 and 1-18 to react with the compound represented by formula (2) in the presence of palladium and alkylphosphine,
- wherein, in formula (2), R1 represents a hydrogen atom or an alkyl group;
- R2 represents a hydrogen atom or a methyl group, and R3 represents a hydrogen atom, an alkoxy group, an aryl group, an amino group, or an alkyl group,
2 more elements
Dependencies are inferred from the claim text.