Fungicide hydroximoyl-tetrazole derivatives

A compound of formula (I)

• wherein
• X represents a hydrogen atom, a halogen atom, substituted or non-substituted C1-C8-alkyl, a substituted or non-substituted C1-C8-alkoxy, a cyano group, a methanesulfonyl group, a nitro group, a trifluoromethyl group or an aryl group;
• A represents a tetrazoyl group of formula (A1) or (A2):
• wherein Y represents substituted or non-substituted C1-C8-alkyl;
• and
• Het represents a pyridyl group of formula (Het1) or a thiazolyl group of formula (Het2);
• wherein
• R represents a hydrogen atom or a halogen atom and
• Q represents a group of formula Z;
• wherein
• Ra represents a hydrogen atom, a substituted or non-substituted C1-C8-alkyl;
• L1 represents CH2;
• L2 represents CH2;
• L3 represents an oxygen atom;
• K1, K2, K3 and K4 independently represent a hydrogen atom, a halogen atom, a nitro group, a hydroxy group, a cyano group, an isonitrile group, an amino group, a sulphanyl group, a formyl group, a substituted or non-substituted carbaldehyde O—(C1-C8-alkyl)oxime, a formyloxy group, a formylamino group, a carbamoyl group, a N-hydroxycarbamoyl group, a pentafluoro-λ6-sulphanyl group, a formylamino group, substituted or non-substituted C1-C8-alkyl, substituted or non-substituted C3-C8-cycloalkyl, substituted or non-substituted C1-C8-halogenoalkyl having 1 to 5 halogen atoms, substituted or non-substituted C3-C8-halogenocycloalkyl having 1 to 5 halogen atoms, substituted or non-substituted C2-C8-alkenyl, substituted or non-substituted C2-C8-alkynyl, substituted or non-substituted C1-C8-alkylamino, substituted or non-substituted di-C1-C8-alkylamino, substituted or non-substituted C1-C8-alkoxy, substituted or non-substituted C1-C8-halogenoalkoxy having 1 to 5 halogen atoms, substituted or non-substituted C1-C8-alkylsulphanyl, substituted or non-substituted C1-C8-halogenoalkylsulphanyl having 1 to 5 halogen atoms, substituted or non-substituted C2-C8-alkenyloxy, substituted or non-substituted C2-C8-halogenoalkenyloxy having 1 to 5 halogen atoms, substituted or non-substituted C3-C8-alkynyloxy, substituted or non-substituted C3-C8-halogenoalkynyloxy having 1 to 5 halogen atoms, substituted or non-substituted C1-C8-alkylcarbonyl, substituted or non-substituted C1-C8-alkylcarbamoyl, substituted or non-substituted di-C1-C8-alkylcarbamoyl, substituted or non-substituted C1-C8-alkoxycarbonyl, substituted or non-substituted (C1-C6-alkoxyimino)-C1-C6-alkyl, substituted or non-substituted (C1-C6-alkenyloxyimino)-C1-C6-alkyl, substituted or non-substituted (C1-C6-alkynyloxyimino)-C1-C6-alkyl, substituted or non-substituted (benzyloxyimino)-C1-C6-alkyl, substituted or non-substituted benzyloxy, substituted or non-substituted benzylsulphanyl, substituted or non-substituted benzylamino, substituted or non-substituted phenoxy, substituted or non-substituted phenylsulphanyl, substituted or non-substituted phenylamino, substituted or non-substituted aryl, substituted or non-substituted heterocyclyl, substituted or non-substituted tri(C1-C8-alkyl)-silyloxy, substituted or non-substituted tri(C1-C8alkyl)-silyl, substituted or non-substituted C5-C12-fused bicycloalkyl, or substituted or non-substituted C5-C12-fused bicycloalkenyl;
• or
• Q represents a group of formula Z1;
• and wherein R1, K1, K2, K3, K4;
• L1 L2 and L3 have the values described for (Z),
• or
• Q represents a group of formula Z2;
• wherein K1, K2, K3, K4, Ra, L1 and L3 have the values described for (Z);
• or
• Q represents also a group of formula Z3;
• wherein K1, K2, K3, K4, Ra, L1 and L2 have the values described for (Z), unless indicated otherwise, a group or a substituent that is substituted according to the invention can be substituted by one or more of the following groups or atoms:
• a halogen atom, a nitro group, a hydroxy group, a cyano group, an isocyano group, an amino group, a sulphenyl group, a pentafluoro-□6-sulphenyl group, a formyl group, a substituted or non-substituted carbaldehyde O—(C1-C8-alkyl)oxime, a formyloxy group, a formylamino group, a carbamoyl group, a N-hydroxycarbamoyl group, a formylamino group, a (hydroxyimino)-C1-C6-alkyl group, a C1-C8-alkyl, a tri(C1-C8-alkyl)silyl-C1-C8alkyl, C1-C8-cycloalkyl, tri(C1-C8-alkyl)silyl-C1-C8cycloalkyl, a C1-C8-halogenoalkyl having 1 to 5 halogen atoms, a C1-C8-halogenocycloalkyl having 1 to 5 halogen atoms, a C2-C8-alkenyl, a C2-C8-alkynyl, a C2-C8-alkenyloxy, a C2-C8-alkynyloxy, a C1-C8-alkylamino, a di-C1-C8-alkylamino, a C1-C8-alkoxy, a C1-C8halogenoalkoxy having 1 to 5 halogen atoms, a C1-C8alkylsulphenyl, a C1-C8halogenoalkylsulphenyl having 1 to 5 halogen atoms, a C2-C8-alkenyloxy, a C2-C8-halogenoalkenyloxy having 1 to 5 halogen atoms, a C3-C8-alkynyloxy, a C3-C8-halogenoalkynyloxy having 1 to 5 halogen atoms, a C1-C8-alkylcarbonyl, a C1-C8-halogenoalkylcarbonyl having 1 to 5 halogen atoms, a C1-C8-alkylcarbamoyl, a di-C1-C8alkylcarbamoyl, a N—C1-C8-alkyloxycarbamoyl, a C1-C8alkoxycarbamoyl, a N—C1-C8-alkyl-C1-C8-alkoxycarbamoyl, a C1-C8alkoxycarbonyl, a C1-C8-halogenoalkoxycarbonyl having 1 to 5 halogen atoms, a C1-C8-alkylcarbonyloxy, a C1-C8-halogenoalkylcarbonyloxy having 1 to 5 halogen atoms, a C1-C8-alkylcarbonylamino, a C1-C8-halogenoalkylcarbonylamino having 1 to 5 halogen atoms, substituted or non-substituted C1-C8alkoxycarbonylamino, substituted or non-substituted C1-C8-halogenoalkoxycarbonylamino having 1 to 5 halogen atoms, a C1-C8-alkylaminocarbonyloxy, a di-C1-C8-alkylaminocarbonyloxy, a C1-C8-alkyloxycarbonyloxy, a C1-C8-alkylsulphenyl, a C1-C8-halogenoalkylsulphenyl having 1 to 5 halogen atoms, a C1-C8-alkylsulphinyl, a C1-C8-halogenoalkylsulphinyl having 1 to 5 halogen atoms, a C1-C8-alkylsulphonyl, a C1-C8-halogenoalkylsulphonyl having 1 to 5 halogen atoms, a C1-C8-alkylaminosulfamoyl, a di-C1-C6alkylaminosulfamoyl, a (C1-C6-alkoxyimino)-C1-C6-alkyl, a (C1-C6-alkenyloxyimino)-C1-C6-alkyl, a (C1-C6-alkynyloxyimino)-C1-C6-alkyl, (benzyloxyimino)-C1-C6-alkyl, C1-C8-alkoxyalkyl, C1-C8-halogenoalkoxyalkyl having 1 to 5 halogen atoms, benzyloxy, benzylsulphenyl, benzylamino, phenoxy, phenylsulphenyl, or phenylamino;
• as well as salts, N-oxides or (E) and (Z) isomers and mixtures thereof.