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US 8,796,409 B2Granted
Use of temperature and ethylene partial pressure to introduce long chain branching in high density polyethylene
AssigneeExxonMobil Chemical Patents Inc.
InventorsMosha H. Zhao, Cesar A. Garcia-Franco, Patrick Brant
Life of this patent
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Abstract
The invention describes the preparation of long chain branching in high density polyethylene by using metallocene catalysts in the presence of ethylene.
Claims14
A long chain branched high density ethylene polymer having:
- at least 95 mol % ethylene;
- a density of from 0.950 g/cm3 to 0.96 g/cm3;
- an Mw/Mn of 4.5 or less;
- a melt index (190° C., 2.16 kg) of 5 dg/min or less;
- an Mw within a range of from 68,945 to 133,530;
- a g′(Zave) within a range of from 0.89 to 0.925;
- high load melt index (190° C., 21.6 kg) within a range of from 2.16 to 108.35 dg/min;
- a melt index ratio (MIR) within a range of from 31.43 to 64.73;
- and
- wherein polyethylene having an Mw of 1000 or less are present at less than 5 wt %, based upon the weight of the polyethylene polymer;
- and produced by a method of combining ethylene and a bridged or unbridged bis-indenyl or bis-tetrahydroindenyl metallocene catalyst compound.
8 more elements
Dependencies are inferred from the claim text.