Polymer product and interfacial polymerisation process using raft agent
AssigneeThe University of Sydney
InventorsBrian Stanley Hawkett, Christopher Henry Such, Duc Ngoc Nguyen
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Abstract
The invention provides a method of polymerizing monomer to form polymer at the surface of solid particulate material, said method comprising: providing a dispersion of said solid particulate material in a continuous hydrophilic liquid phase, said dispersion comprising a hydrophilic RAFT agent as a stabilizer for said solid particulate material, and said continuous hydrophilic liquid phase comprising one or more ethylenically unsaturated monomers; and polymerizing said one or more ethylenically unsaturated monomers under the control of said hydrophilic RAFT agent to thereby form polymer at the surface of said solid particulate material.
Claims14
Polymer encapsulated solid particulate material that is 100 microns or less in size, said solid particulate material being encapsulated in a substantially uniform and continuous coating of polymer that has at least in part been formed under the control of a hydrophilic RAFT agent of general formula (4) and thereby has a reaction residue of the agent covalently bound thereto:
- where each X is independently a polymerised residue of a hydrophilic ethylenically unsaturated monomer selected from acrylic acid, methacrylic acid, hydroxyethyl methacrylate, hydroxypropyl methacrylate, acrylamide, methacrylamide, hydroxyethyl acrylate, N-methylacrylamide, dimethylaminoethyl methacrylate, itaconic acid, p-styrene carboxylic acids, p-styrene sulfonic acids, vinyl sulfonic acid, vinyl phosphonic acid, ethacrylic acid, alpha-chloroacrylic acid, crotonic acid, fumaric acid, citraconic acid, mesaconic acid and maleic acid, 2-(dimethyl amino) ethyl and propyl acrylates and methacrylates, and corresponding 3-(diethylamino) ethyl and propyl acrylates and methacrylates, n is an integer ranging from 1 to 100, R1 is an organic group optionally substituted with one or more hydrophilic groups and Z is selected from optionally substituted alkoxy, optionally substituted aryloxy, optionally substituted alkyl, optionally substituted aryl, optionally substituted heterocyclyl, optionally substituted arylalkyl, optionally substituted alkylthio, optionally substituted arylalkylthio, dialkoxy- or diaryloxy-phosphinyl [—P(═O)OR22], dialkyl- or diaryl-phosphinyl [—P(═O)R22], optionally substituted acylamino, optionally substituted acylimino, optionally substituted amino, R1—(X)n—S— and a polymer chain, where R1, X and n are as defined above and R2 is selected from the group consisting of optionally substituted C1-C8 alkyl, optionally substituted C2-C8 alkenyl, optionally substituted aryl, optionally substituted heterocyclyl, optionally substituted aralkyl, and optionally substituted alkaryl;
- wherein Z, X, n and R1 are selected such that the RAFT agent is not capable of forming micelles in a hydrophilic liquid.
Polymer encapsulated solid particulate material that is 100 microns or less in size having the solid particulate material substantially uniformly distributed throughout the encapsulating polymer, wherein the encapsulating polymer has at least in part been formed under the control of a hydrophilic RAFT agent of general formula (4) and thereby has a reaction residue of the agent covalently bound thereto:
- where each X is independently a polymerised residue of a hydrophilic ethylenically unsaturated monomer selected from acrylic acid, methacrylic acid, hydroxyethyl methacrylate, hydroxypropyl methacrylate, acrylamide, methacrylamide, hydroxyethyl acrylate, N-methylacrylamide, dimethylaminoethyl methacrylate, itaconic acid, p-styrene carboxylic acids, p-styrene sulfonic acids, vinyl sulfonic acid, vinyl phosphonic acid, ethacrylic acid, alpha-chloroacrylic acid, crotonic acid, fumaric acid, citraconic acid, mesaconic acid and maleic acid, 2-(dimethyl amino) ethyl and propyl acrylates and methacrylates, and corresponding 3-(diethylamino) ethyl and propyl acrylates and methacrylates, n is an integer ranging from 1 to 100, R1 is an organic group optionally substituted with one or more hydrophilic groups and Z is selected from optionally substituted alkoxy, optionally substituted aryloxy, optionally substituted alkyl, optionally substituted aryl, optionally substituted heterocyclyl, optionally substituted arylalkyl, optionally substituted alkylthio, optionally substituted arylalkylthio, dialkoxy- or diaryloxy-phosphinyl [—P(═O)OR22], dialkyl- or diaryl-phosphinyl [—P(═O)R22], optionally substituted acylamino, optionally substituted acylimino, optionally substituted amino, R1—(X)n—S— and a polymer chain, where R1, X and n are as defined above and R2 is selected from the group consisting of optionally substituted C1-C8 alkyl, optionally substituted C2-C8 alkenyl, optionally substituted aryl, optionally substituted heterocyclyl, optionally substituted aralkyl, and optionally substituted alkaryl;
- wherein Z, X, n and R1 are selected such that the RAFT agent is not capable of forming micelles in a hydrophilic liquid.
Dependencies are inferred from the claim text.