# US 8,787,809 B2 · Pressure members comprising CNT/PFA nanocomposite coatings

> Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt

- Number: US 8,787,809 B2
- Document ID: US8787809B2
- Status: Granted
- Kind: B2
- Application number: 13/032,480
- Filed: 2011-02-22
- Published: 2012-08-23
- Granted: 2014-07-22
- Earliest claimed: 2011-02-22
- Assignees: Xerox Corporation
- Applicants: Yu Qi; Nan-Xing Hu
- Inventors: Yu Qi; Nan-Xing Hu
- Web page: https://patentgrep.com/patent/US8787809B2

## CPC

- G03G 15/206: {Structural details or chemical composition of the pressure elements and layers thereof}
- B32B 5/16: characterised by features of a layer formed of particles, e.g. chips, powder {or granules (layer formed of natural mineral particles B32B19/00; layer being formed of wood fibres, chips or particles B32B21/02)}
- B32B 27/08: of synthetic resin
- B32B 27/20: using fillers, pigments, thixotroping agents
- B32B 27/281: {comprising polyimides}
- B82Y 30/00: Nanotechnology for materials or surface science, e.g. nanocomposites
- B32B 2260/046: Synthetic resin
- B32B 2262/02: Synthetic macromolecular fibres
- B32B 2262/106: Carbon fibres, e.g. graphite fibres
- B32B 2327/18: PTFE, i.e. polytetrafluoroethylene
- B32B 2457/00: Electrical equipment
- Y10T 428/249952: At least one thermosetting synthetic polymeric material layer
- Y10T 428/254: Polymeric or resinous material
- Y10T 428/269: including synthetic resin or polymer layer or component
- Y10T 428/3154: Of fluorinated addition polymer from unsaturated monomers
- Y10T 428/31544: Addition polymer is perhalogenated
- Y10T 428/31663: As siloxane, silicone or silane
- Y10T 428/31931: Polyene monomer-containing
- G03G: ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- B32B: LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B82Y: SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

## Abstract

Exemplary embodiments provide a pressure member used in electrophotographic printing devices, wherein the pressure member can include a coated outermost layer containing fluoropolymers and carbon nanotubes (CNTs) each surrounded by an elastomeric material.

## Claims

### Claim 1

A pressure member comprising:
a substrate, and
an outermost layer disposed over the substrate, wherein the outermost layer comprises a plurality of carbon nanotubes (CNTs), each CNT surrounded by a shell comprising an elastomeric material, the elastomeric material being dispersed within a fluoroplastic material for providing the outermost layer a tensile strength of at least about 3000 psi, wherein the elastomeric material is at least partially crosslinked to form the shell independent of the fluoroplastic material, and
wherein the elastomeric material is selected from a group consisting of a fluoroelastomer, a perfluoroelastomer, a silicone, a fluorosilicone, a polysulfide, a polyphosphazene and a mixture thereof, and
wherein the fluoroplastic material is different from the elastomeric material, the fluoroplastic material comprising a repeating unit corresponding to a monomer that is selected from a group consisting of tetrafluoroethylene (TFE), hexafluoropropylene (HFP), perfluoropropyl vinyl ether (PPVE), perfluoroethyl vinyl ether (PEVE), perfluoromethyl vinyl ether (PMVE), chlorotrifluoroethylene (CTFE), vinyl fluoride (VF), and vinylidene fluoride (VDF), and a combination thereof.

### Claim 2 (depends on 1)

The member of claim 1, wherein the outermost layer has an ultimate elongation of at least about 100% and a toughness of at least about 3,000 in.-lbs./in.3.

### Claim 3 (depends on 1)

The member of claim 1, further comprising a shell thickness ranging from about 1 nanometer to about 5 micrometers.

### Claim 4 (depends on 1)

The member of claim 1, wherein each CNT has an inside diameter ranging from about 0.5 nanometers to about 20 nanometers, an outside diameter ranging from about 1 nanometer to about 80 nanometers, and an aspect ratio ranging from about 1 to about 10000.

### Claim 5 (depends on 1)

The member of claim 1, wherein the plurality of CNTs is present in an amount ranging from about 0.1 percent to about 20 percent by weight of the total outermost layer.

### Claim 6 (depends on 1)

The member of claim 1, wherein the elastomeric material further comprises a functional group capable of bonding with the plurality of CNTs, wherein the functional group is selected from the group consisting of a hydroxyl, a carboxylic acid, an aziridine, an azomethine ylide, an aryl diazonium cation, an oxazolidinone, and a mixture thereof.

### Claim 7 (depends on 1)

The member of claim 1, wherein the fluoroplastic is selected from the group consisting of polyfluoroalkoxypolytetrafluoroethylene (PFA), polytetrafluoroethylene (PTFE), fluorinated ethylenepropylene copolymer (FEP), and a combination thereof.

### Claim 8 (depends on 1)

The member of claim 1, wherein the outermost layer of the pressure member further comprises one or more filler particles dispersed within the outermost layer, the filler particles comprising metal oxides, silicon carbide, boron nitride, and graphite, wherein the metal oxides are selected from the group consisting of silicon oxide, aluminum oxide, zirconium oxide, zinc oxide, tin oxide, iron oxide, magnesium oxide, manganese oxide, nickel oxide, copper oxide, antimony pentoxide, indium tin oxide, and a mixture thereof.

### Claim 9 (depends on 1)

The member of claim 1, wherein the outermost layer of the pressure member has a thickness ranging from about 5 microns to about 250 microns.

### Claim 10 (depends on 1)

The member of claim 1, wherein the substrate comprises a polyimide selected from the group consisting of aromatic polyimide, polyamideimide, polyetherimide, siloxane polyetherimide block copolymer, and a mixture thereof.

### Claim 11 (depends on 1)

The member of claim 1, wherein a functional layer is disposed between the substrate and the outermost layer, wherein the functional layer comprises a conformal layer, an adhesive layer, or a combination thereof.

### Claim 12 (depends on 1)

The member of claim 1, wherein the elastomeric material is a fluoroelastomer, the fluoroelastomer being a cross-linked tetrapolymer of TFE, vinylidene fluoride (VF2) and HFP.

### Claim 13

A fusing apparatus comprising:
a fuser member; and
a pressure member configured to form a contact nip with the fuser member to fuse toner images on a print medium that passes through the contact nip, wherein the pressure member comprises:
a substrate, and
an outermost layer disposed over the substrate, wherein the outermost layer comprises a plurality of carbon nanotubes (CNTs) with each CNT surrounded by a shell comprising an elastomeric material and uniformly distributed in a fluoroplastic material to provide the outermost layer a toughness of at least about 3,000 in.-lbs./in.3, the elastomeric material being selected from a group consisting of a fluoroelastomer, a perfluoroelastomer, a silicone, a fluorosilicone, a polysulfide, a polyphosphazene and a mixture thereof, wherein the elastomeric material is at least partially crosslinked to form the shell independent of the fluoroplastic material, and
wherein the fluoroplastic material is different from the elastomeric material, the fluoroplastic material is selected from the group consisting of polyfluoroalkoxypolytetrafluoroethylene (PFA), polytetrafluoroethylene (PTFE), fluorinated ethylenepropylene copolymer (FEP), and a combination thereof.

### Claim 14 (depends on 13)

The apparatus of claim 13, wherein the outermost layer has a tensile strength of at least about 2000 psi and an ultimate elongation of at least about 100%.

### Claim 15 (depends on 13)

The apparatus of claim 13, wherein the elastomeric material is a fluoroelastomer, the fluoroelastomer being a cross-linked tetrapolymer of TFE, VF2 and HFP.

### Claim 16

An image forming apparatus comprising:
a photoreceptor for receiving an electrostatic latent image thereon;
a development component for applying toner to the photoreceptor to develop the electrostatic latent image, thereby forming a developed image on the photoreceptor;
a transfer component to transfer the developed image from the photoreceptor to a print medium; and
a fusing apparatus comprising a fuser member and a pressure member configured for forming a contact nip between the fuser member and the pressure member for fusing toner images on the print medium passing through the contact nip, wherein the pressure member comprises,
an outermost layer comprises a plurality of carbon nanotubes (CNTs) with each CNT surrounded by a shell comprising an elastomeric material and uniformly distributed in a fluoroplastic material to provide the outermost layer a tensile strength of at least about 3000 psi, an ultimate elongation of at least about 100%, and a toughness of at least about 3,000 in.-lbs./in.3, the elastomeric material being selected from a group consisting of a fluoroelastomer, a perfluoroelastomer, a silicone, a fluorosilicone, a polysulfide, a polyphosphazene and a mixture thereof, wherein the elastomeric material is at least partially crosslinked to form the shell independent of the fluoroplastic material, and
wherein the fluoroplastic material is different from the elastomeric material, the fluoroplastic material comprising a repeating unit corresponding to a monomer that is selected from a group consisting of tetrafluoroethylene (TFE), hexafluoropropylene (HFP), perfluoropropyl vinyl ether (PPVE), perfluoroethyl vinyl ether (PEVE), perfluoromethyl vinyl ether (PMVE), chlorotrifluoroethylene (CTFE), vinyl fluoride (VF), and vinylidene fluoride (VDF), and a combination thereof.

### Claim 17 (depends on 16)

The apparatus of claim 16, wherein the shell thickness is from about 1 nanometer to about 5 micrometers.

### Claim 18 (depends on 16)

The apparatus of claim 16, wherein the plurality of CNTs is present in an amount ranging from about 0.1 percent to about 20 percent by weight of the total outermost layer.

### Claim 19 (depends on 16)

The apparatus of claim 16, wherein the elastomeric material is a fluoroelastomer, the fluoroelastomer being a cross-linked tetrapolymer of TFE, VF2 and HFP.