# US 8,785,918 B2 · Organic light emitting device and organic light emitting display device using the same

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- Number: US 8,785,918 B2
- Document ID: US8785918B2
- Status: Granted
- Kind: B2
- Application number: 13/727,260
- Filed: 2012-12-26
- Published: 2014-04-17
- Granted: 2014-07-22
- Earliest claimed: 2012-10-15
- Assignees: LG Display Co., Ltd.
- Applicants: LG Display Co., Ltd.
- Inventors: Se Hee Lee; Kwan Soo Kim; Sang Dae Kim
- Web page: https://patentgrep.com/patent/US8785918B2

## CPC

- H10K 85/615: {Polycyclic condensed aromatic hydrocarbons, e.g. anthracene}
- H10K 50/828: Transparent cathodes, e.g. comprising thin metal layers
- H10K 85/657: {Polycyclic condensed heteroaromatic hydrocarbons}
- H10K 50/16: Electron transporting layers
- H10K 50/171: {Electron injection layers}
- H10K 59/12: Active-matrix OLED [AMOLED] displays
- H10K 85/30: Coordination compounds
- H10K 85/342: {comprising iridium}
- H10K 85/6572: {comprising only nitrogen in the heteroaromatic polycondensed ring system, e.g. phenanthroline or carbazole}
- H10K 2102/103: {comprising indium oxides, e.g. ITO}
- H10K: ORGANIC ELECTRIC SOLID-STATE DEVICES

## Abstract

Disclosed is a an organic light emitting device including a first electrode and a second electrode; and an organic layer formed between the first electrode and the second electrode, in which the organic layer includes a compound represented by Formula 1 and the second electrode is a double-layer structure comprised of LiF:Mg. Accordingly, an organic light emitting device which has excellent voltage efficiency and emission efficiency and may improve service-life characteristics, and an organic light emitting display device using the same may be provided.

## Claims

### Claim 1

An organic light emitting device, comprising:
a first electrode and a second electrode; and
an organic layer disposed between the first electrode and the second electrode,
wherein the organic layer comprises a compound represented by the following Formula 1, and the second electrode is a double layer comprised of LiF:Mg:
where, R1 and R2 are each independently or simultaneously a group derived from the group consisting of a hydrogen atom, an aliphatic hydrocarbon having 1 to 20 carbon atoms, phenyl, naphthyl, biphenyl, anthracenyl, an aromatic heterocyclic ring, or an aromatic ring,
Ar is a group derived from the group consisting of phenyl, naphthyl, biphenyl, anthracenyl, an aromatic heterocyclic ring, or an aromatic ring,
R3 is a group derived from the group consisting of a hydrogen atom, an alkyl group or aliphatic hydrocarbon having 1 to 6 carbon atoms, a substituted phenyl, naphthyl, biphenyl, anthracenyl, an aromatic heterocyclic ring, or an aromatic ring,
X is NR4, a sulfur atom, or an oxygen atom, and
R4 is a group derived from a hydrogen atom, an alkyl group or aliphatic hydrocarbon having 1 to 7 carbon atoms, phenyl, naphthyl, biphenyl, anthracenyl, or an aromatic heterocyclic ring.

### Claim 2 (depends on 1)

The organic light emitting device of claim 1, wherein the second electrode is a double layer structure in which Ag:Mg is formed on the upper portion of LiF:Mg.

### Claim 3 (depends on 1)

The organic light emitting device of claim 1, wherein the second electrode is formed at LiF:Mg=1:0.2 to 1:5.

### Claim 4 (depends on 1)

The organic light emitting device of claim 1, wherein the second electrode is a structure in which LiF:Mg is formed to have about 10 to about 50 Å.

### Claim 5 (depends on 2)

The organic light emitting device of claim 2, wherein the second electrode is a structure in which Ag:Mg is formed at 1:1 to 9:1.

### Claim 6 (depends on 2)

The organic light emitting device of claim 2, wherein the second electrode is a structure in which Ag:Mg is formed from about 100 Å to about 300 Å.

### Claim 7 (depends on 1)

The organic light emitting device of claim 1, wherein the organic layer comprises at least one layer selected from the group consisting of a hole injection layer, a hole transporting layer, an electron blocking layer, an emission layer, a hole blocking layer, an electron transporting layer and an electron injection layer, and the compound represented by Formula 1 is included in the electron injection layer or the electron transporting layer.

### Claim 8 (depends on 7)

The organic light emitting device of claim 7, further comprising a lithium quinolate (LiQ) monomer or Lithium quinolate (LiQ) trimer in one of the electron injection layer or the electron transporting layer.

### Claim 9 (depends on 1)

The organic light emitting device of claim 1, wherein the second electrode has a work function of 4.1 eV to 4.7 eV.

### Claim 10 (depends on 1)

The organic light emitting device of claim 1, wherein the first electrode is formed with a multilayer structure in which one opaque conductive material of aluminum (Al), silver (Ag) and magnesium (Mg), and a transparent conductive material comprising one of indium tin oxide (ITO), indium zinc oxide (IZO), zinc oxide (ZnO), indium gallium zinc oxide (IGZO) and In2O3 are stacked.

### Claim 11

An organic light emitting display device, comprising:
a substrate on which an active area having a plurality of pixel areas is defined;
a driving thin film transistor disposed on each of the plurality of pixel areas;
a passivation layer disposed on the driving thin film transistor;
a first electrode connected to a drain electrode exposed by a contact hole formed on the passivation layer;
an organic layer disposed on the first electrode and comprising a compound represented by the following Formula 1; and
a second electrode which is disposed on the organic layer and is a double-layer comprised of LiF:Mg:
where, R1 and R2 are each independently or simultaneously a group derived from the group consisting of a hydrogen atom, an aliphatic hydrocarbon having 1 to 20 carbon atoms, phenyl, naphthyl, biphenyl, anthracenyl, an aromatic heterocyclic ring, or an aromatic ring,
Ar is a group derived from the group consisting of phenyl, naphthyl, biphenyl, anthracenyl, an aromatic heterocyclic ring, or an aromatic ring,
R3 is a group derived from the group consisting of a hydrogen atom, an alkyl group or aliphatic hydrocarbon having 1 to 6 carbon atoms, a substituted phenyl, naphthyl, biphenyl, anthracenyl, an aromatic heterocyclic ring, or an aromatic ring,
X is NR4, a sulfur atom, or an oxygen atom, and
R4 is a group derived from a hydrogen atom, an alkyl group or aliphatic hydrocarbon having 1 to 7 carbon atoms, phenyl, naphthyl, biphenyl, anthracenyl, or an aromatic heterocyclic ring.
