# US 8,785,102 B2 · Toner compositions

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- Number: US 8,785,102 B2
- Document ID: US8785102B2
- Status: Granted
- Kind: B2
- Application number: 13/453,542
- Filed: 2012-04-23
- Published: 2013-10-24
- Granted: 2014-07-22
- Earliest claimed: 2012-04-23
- Assignees: Xerox Corporation
- Applicants: Robert D. Bayley; Maura A. Sweeney; Grazyna E. Kmiecik-Lawrynowicz; Daniel W. Asarese
- Inventors: Robert D. Bayley; Maura A. Sweeney; Grazyna E. Kmiecik-Lawrynowicz; Daniel W. Asarese
- Web page: https://patentgrep.com/patent/US8785102B2

## CPC

- G03G 9/09708: {Inorganic compounds}
- G03G 9/0804: {whereby the components are brought together in a liquid dispersing medium}
- G03G 9/0819: {characterised by the dimensions of the particles}
- G03G 9/0823: {Electric parameters}
- G03G 9/0827: {characterised by their shape, e.g. degree of sphericity}
- G03G 9/08797: {characterised by their physical properties, e.g. viscosity, solubility, melting temperature, softening temperature, glass transition temperature}
- G03G: ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY

## Abstract

A toner having charge control agents which impart excellent triboelectric charging characteristics. In embodiments, the toner particles are made by a process in which charge control agent is added and adhered to the particle surface through washing steps and is maintained through the drying steps. The process of the present embodiments impart desirable charging characteristics to the toner particles.

## Claims

### Claim 1

A process for producing toner comprising:
adding an optional colorant and an optional wax to an emulsion comprising at least one resin to form particles;
aggregating the particles to form aggregated particles;
coalescing the aggregated particles to form toner particles;
dispersing the toner particles in water to form a toner slurry;
adding a dispersion to the toner slurry, the dispersion comprising one or more charge control agents;
heating the toner slurry to above a glass transition temperature of the toner particles while mixing;
cooling the toner slurry while mixing; and
washing the toner slurry to recover the toner particles.

### Claim 2 (depends on 1)

The process of claim 1, wherein the at least one resin is selected from the group consisting of styrenes, acrylates, methacrylates, butadienes, isoprenes, acrylic acids, methacrylic acids, acrylonitriles, and combinations thereof, and wherein the optional colorant comprises dyes, pigments, combinations of dyes, combinations of pigments, and combinations of dyes and pigments.

### Claim 3 (depends on 1)

The process of claim 1, wherein the one or more charge control agents is selected from the group consisting of zinc acetate, zinc butyrate, zinc chlorate, zinc chloride, zinc bromide, zinc citrate, zinc fluoride, zinc salicylate, zinc fluoride tetrahydrate, aluminum salicylate, zinc 3,5-diteriarybutylsalicylic acid, aluminum 3,5-ditertiarybutylsalicylic acid, and combinations thereof.

### Claim 4 (depends on 1)

The process of claim 1, wherein the toner particles possess a triboelectric charge of from about −2 μC/g to about −60 μC/g.

### Claim 5 (depends on 4)

The process of claim 4, wherein the toner particles possess a triboelectric charge of from about −10 μC/g to about −45 μC/g.

### Claim 6 (depends on 1)

The process of claim 1, wherein the dispersion comprising one or more charge control agents is added in an amount of from about 0.1 to about 10 percent by weight of the total weight of the toner particles.

### Claim 7 (depends on 6)

The process of claim 6, wherein the dispersion comprising one or more charge control agents is added in an amount of from about 0.5 to about 8 percent by weight of the total weight of the toner particles.

### Claim 8 (depends on 1)

The process of claim 1, wherein the glass transition temperature is above 70° C.

### Claim 9 (depends on 8)

The process of claim 8, wherein the glass transition temperature is from about 40° C. to about 65° C.

### Claim 10 (depends on 1)

The process of claim 1, wherein the toner slurry is mixed at a speed of from about 1,000 RPM to about 10,000 RPM.

### Claim 11 (depends on 10)

The process of claim 10, wherein the toner slurry is mixed at a speed of from about 4,000 RPM to about 7,000 RPM.

### Claim 12 (depends on 1)

The process of claim 1, wherein the toner slurry is heated to above the glass transition temperature of the toner particles while mixing for up to one hour.

### Claim 13 (depends on 1)

The process of claim 1 further including washing the toner particles in a solution before dispersing the toner particles in water to form the toner slurry.

### Claim 14

A process for producing toner comprising:
adding an optional colorant and an optional wax to an emulsion comprising at least one resin to form particles;
aggregating the particles to form aggregated particles;
coalescing the aggregated particles to form toner particles;
dispersing the toner particles in water to form a toner slurry;
adding a dispersion to the toner slurry, the dispersion comprising one or more charge control agents;
heating the toner slurry to above a glass transition temperature of the toner particles while mixing;
cooling the toner slurry while mixing;
washing the toner slurry to recover the toner particles; and
drying the recovered toner particles, wherein the one or more charge control agents remain adhered to the surface of the recovered toner particles.

### Claim 15 (depends on 14)

The process of claim 14, wherein one or more charge control agents are visible on the surface of the recovered toner particles through scanning electron microscopy.

### Claim 16 (depends on 14)

The process of claim 14, wherein one or more charge control agents are visible on the surface of the recovered toner particles through scanning electron microscopy at a magnification of from about 1.00K to about 30.00K.