# US 8,784,988 B2 · Polymer inorganic-particulate composite fibers

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- Number: US 8,784,988 B2
- Document ID: US8784988B2
- Status: Granted
- Kind: B2
- Application number: 12/623,330
- Filed: 2009-11-20
- Published: 2010-05-27
- Granted: 2014-07-22
- Earliest claimed: 2008-11-25
- Assignees: Dow Global Technologies LLC
- Applicants: Leonardo C. Lopez; Scott T. Matteucci
- Inventors: Leonardo C. Lopez; Scott T. Matteucci
- Web page: https://patentgrep.com/patent/US8784988B2

## CPC

- D01F 1/10: Other agents for modifying properties
- D01F 6/78: from copolycondensation products
- Y10T 428/249921: Web or sheet containing structurally defined element or component
- Y10T 428/25: Web or sheet containing structurally defined element or component and including a second component containing structurally defined particles
- Y10T 428/2913: Rod, strand, filament or fiber
- Y10T 428/2915: including textile, cloth or fabric
- Y10T 428/2927: including structurally defined particulate matter
- Y10T 428/2929: Bicomponent, conjugate, composite or collateral fibers or filaments [i.e., coextruded sheath-core or side-by-side type]
- Y10T 428/2967: Synthetic resin or polymer
- Y10T 428/2969: Polyamide, polyimide or polyester
- Y10T 442/674: Nonwoven fabric with a preformed polymeric film or sheet
- D01F: CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION

## Abstract

The instant invention generally provides polymer inorganic-particulate composite fiber comprising a molecularly self-assembling material and an inorganic-particulate, and a process of making and an article comprising the polymer inorganic-particulate composite fiber.

## Claims

### Claim 1

A polymer inorganic-particulate composite fiber comprising a molecularly self-assembling (MSA) material and an inorganic particulate dispersed in the MSA material, wherein the inorganic particulate comprises a metal hydroxide or an inorganic clay, the inorganic clay consisting of a cation exchanging layered material and inorganic cations, the cation exchanging layered material having a cation exchanging capacity, the polymer inorganic-particulate composite fiber having an average diameter and the inorganic particulate having at least two dimensions that are less than 10% of the average diameter of polymer inorganic-particulate composite fiber, the inorganic particulate comprising from 1 weight percent (wt %) to 90 wt % of the polymer inorganic-particulate composite fiber based on total weight of the polymer inorganic-particulate composite fiber, and the MSA comprises repeat units of formula I:
and at least one second repeat unit selected from the ester-amide units of Formula II and III:
and the ester-urethane units for Formula IV:
or combinations thereof wherein:
R is at each occurrence, independently a C2-C20 non-aromatic hydrocarbylene group, a C2-C20 non-aromatic heterohydrocarbylene group, or a polyalkylene oxide group having a group molecular weight of from about 100 grams per mole to about 5000 grams per mole;
R1 at each occurrence independently is a bond or a C1-C20 non-aromatic hydrocarbylene group;
R2 at each occurrence independently is a C1-C20 non-aromatic hydrocarbylene group;
RN is —N(R3)-Ra-N(R3)-, where R3 at each occurrence independently is H or a C1-C6 alkylene and Ra is a C2-C20 non-aromatic hydrocarbylene group, or RN is a C2-C20 heterocycloalkyl group containing the two nitrogen atoms, wherein each nitrogen atom is bonded to a carbonyl group according to formula (III) above;
n is at least 1 and has a mean value less than 2; and
w represents the ester mol fraction of Formula I, and x, y and z represent the amide or urethane mole fractions of Formulas II, III, and IV, respectively, where w+x+y+z=1, and
0<w<1, and at least one of x, y and z is greater than zero but less than 1.

### Claim 2 (depends on 1)

The polymer inorganic-particulate composite fiber as in claim 1, wherein the inorganic particulate comprises the inorganic clay.

### Claim 3 (depends on 1)

The polymer inorganic-particulate composite fiber as in claim 1, wherein the inorganic particulate comprises the metal hydroxide.

### Claim 4 (depends on 1)

The polymer inorganic-particulate composite fiber as in claim 1, wherein the polymer inorganic-particulate composite fiber has an average diameter of from 0.010 micrometer (μm) to 30 μm.

### Claim 5 (depends on 1)

The polymer inorganic-particulate composite fiber as in claim 1, wherein when the MSA material is in a form of a melt, the polymer inorganic-particulate composite fiber being characterized by a zero shear viscosity of less than 10,000,000 Pascal-seconds at from above Tm up to about 40° C. above Tm of the MSA material.

### Claim 6 (depends on 1)

The polymer inorganic-particulate composite fiber as in claim 1, wherein the molecularly self-assembling material is a polyester-amide, polyether-amide, polyester-urethane, polyether-urethane, polyetherurea, polyester-urea, or a mixture thereof.

### Claim 7 (depends on 1)

The polymer inorganic-particulate composite fiber as in claim 1, wherein the MSA material comprises self-assembling units comprising multiple hydrogen bonding arrays.

### Claim 8 (depends on 1)

The polymer inorganic-particulate composite fiber as in claim 1, wherein the MSA material is of Formula II or III:
wherein:
R is at each occurrence, independently a C2-C20 non-aromatic hydrocarbylene group, a C2-C20 non-aromatic heterohydrocarbylene group, or a polyalkylene oxide group having a group molecular weight of from about 100 grams per mole to about 5000 grams per mole;
R1 at each occurrence independently is a bond or a C1-C20 non-aromatic hydrocarbylene group;
R2 at each occurrence independently is a C1-C20 non-aromatic hydrocarbylene group;
RN is —N(R3)-Ra-N(R3)-, where R3 at each occurrence independently is H or a C1-C6 alkylene and Ra is a C2-C20 non-aromatic hydrocarbylene group, or RN is a C2-C20 heterocycloalkyl group containing the two nitrogen atoms, wherein each nitrogen atom is bonded to a carbonyl group according to formula (III) above;
n is at least 1 and has a mean value less than 2; and
x and y represent mole fraction wherein x+y=1, and 0≦x≦1, and 0≦y≦1.

### Claim 9 (depends on 1)

The polymer inorganic-particulate composite fiber as in claim 1, wherein the number average molecular weight (Mn) of the molecularly self-assembling material is between about 1000 grams per mole and about 50,000 grams per mole.

### Claim 10 (depends on 1)

The polymer inorganic-particulate composite fiber as in claim 1, wherein the MSA material itself is characterized by a melt viscosity of less than 100 pascal-seconds (Pa.sec.) at from above melting temperature (Tm) up to about 40 degrees Celsius (° C.) above Tm.

### Claim 11 (depends on 1)

The polymer inorganic-particulate composite fiber as in claim 1, wherein the MSA material itself is characterized by a melting temperature (Tm) greater than 60° C. or glass transition temperature (Tg) greater than −80° C.

### Claim 12 (depends on 1)

An article comprising the polymer inorganic-particulate composite fiber of claim 1.

### Claim 13 (depends on 12)

The article as in claim 12, the article comprising a porous filter medium, wound dressing, textile, carpeting, structure reinforcing material, antistatic medium, conductive medium, catalyst medium, packaging, blow molded article, thermal insulation, electrical insulation, or electrical conductor.

### Claim 14 (depends on 12)

The article as in claim 12, the article comprising a medical gown, medical tissue scaffold, cosmetic applicator, sound insulation, barrier material, diaper coverstock, adult incontinence pants, training pants, underpad, feminine hygiene pad, wiping cloth, durable paper, fabric softener, home furnishing, floor covering backing, geotextile, apparel, apparel interfacing, apparel lining, shoe, industrial garment, protective garments and fabrics, agricultural fabric, automotive fabric, automotive component, coating substrate, laminating substrate, leather, or electronic component.