# US 8,784,584 B2 · Perchlorate-free yellow signal flare composition

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- Number: US 8,784,584 B2
- Document ID: US8784584B2
- Status: Granted
- Kind: B2
- Application number: 13/935,069
- Filed: 2013-07-03
- Published: 2013-11-07
- Granted: 2014-07-22
- Earliest claimed: 2008-06-25
- Assignees: The United States of America as represented by the Secretary of the Navy
- Applicants: Christina M. Yamamoto; Robert G. Shortridge
- Inventors: Christina M. Yamamoto; Robert G. Shortridge
- Web page: https://patentgrep.com/patent/US8784584B2

## CPC

- C06B 33/14: at least one being an inorganic nitrogen-oxygen salt
- C06B 33/04: the material being an inorganic nitrogen-oxygen salt
- C06C 15/00: Pyrophoric compositions; Flints (chemical lighters C06C9/00)
- C06B: EXPLOSIVES OR THERMIC COMPOSITIONS (blasting F42D); MANUFACTURE THEREOF; USE OF SINGLE SUBSTANCES AS EXPLOSIVES (compounds in general C01, C07 or C08; {demolition agents based on cementitious or like materials C04B41/0009})
- C06C: DETONATING OR PRIMING DEVICES; FUSES (ammunition fuzes F42C); CHEMICAL LIGHTERS; PYROPHORIC COMPOSITIONS

## Abstract

Perchlorate-free flare compositions are disclosed which, when burned, produce yellow smoke and flames. Methods of producing the compositions are also disclosed.

## Claims

### Claim 1

A flare composition for producing a yellow flame, the composition comprising, by weight,
a magnesium fuel within the range of approximately eighteen percent (18%) to approximately thirty percent (30%) of the composition, the magnesium fuel including particles sizes selected from the group consisting of granulation 15, granulation 17, granulation 18, and mixtures thereof,
a magnesium-aluminum alloy within the range of approximately zero percent (0%) to approximately five percent (5%) of the composition,
a sodium nitrate within the range of approximately eighteen percent (18%) to approximately thirty-eight percent (38%) of the composition,
a barium nitrate within the range of approximately twenty-six percent (26%) to approximately thirty-six percent (36%) of the composition,
a polyvinyl chloride within the range of approximately seven percent (7%) to approximately twelve percent (12%) of the composition,
an asphaltum within the range of approximately zero percent (0%) to approximately five percent (5%) of the composition, and
a two-part curable binder system within the range of approximately four percent (4%) to approximately seven point five percent (7.5%) of the composition, the binder system including within the range of approximately seventy percent (70%) to approximately eighty percent (80%) epoxy and within the range of approximately twenty percent (20%) to approximately thirty percent (30%) curing agent;
wherein the curing agent includes polyamide resin.

### Claim 2 (depends on 1)

The composition of claim 1, wherein the magnesium fuel is approximately twenty percent (20%) of the composition.

### Claim 3 (depends on 2)

The composition of claim 2, wherein the magnesium fuel includes mixtures of particle sizes.

### Claim 4 (depends on 1)

The composition of claim 1, wherein the sodium nitrate is approximately thirty-seven percent (37%) of the composition.

### Claim 5 (depends on 1)

The composition of claim 1, wherein the barium nitrate is approximately twenty-seven percent (27%) of the composition.

### Claim 6 (depends on 1)

The composition of claim 1, wherein the polyvinyl chloride is approximately eleven percent (11%) of the composition.

### Claim 7 (depends on 1)

The composition of claim 1, wherein the binder system is approximately five percent (5%) of the composition.

### Claim 8 (depends on 1)

The composition of claim 1, wherein the epoxy is approximately three point five percent (3.5%) of the composition.

### Claim 9 (depends on 1)

The composition of claim 1, wherein the curing agent is approximately one point five percent (1.5%) of the composition.

### Claim 10

A flare composition for producing a yellow flame, the composition comprising, by weight,
a magnesium fuel within the range of approximately eighteen percent (18%) to approximately thirty percent (30%) of the composition, the magnesium fuel including particles sizes selected from the group consisting of granulation 15, granulation 17, granulation 18, and mixtures thereof,
a magnesium-aluminum alloy within the range of approximately zero percent (0%) to approximately five percent (5%) of the composition,
a sodium nitrate within the range of approximately eighteen percent (18%) to approximately thirty-eight percent (38%) of the composition,
a barium nitrate within the range of approximately twenty-six percent (26%) to approximately thirty-six percent (36%) of the composition,
a polyvinyl chloride within the range of approximately seven percent (7%) to approximately twelve percent (12%) of the composition,
an asphaltum within the range of approximately zero percent (0%) to approximately five percent (5%) of the composition, and
a two-part curable binder system within the range of approximately four percent (4%) to approximately seven point five percent (7.5%) of the composition, the binder system including within the range of approximately seventy percent (70%) to approximately eighty percent (80%) epoxy and within the range of approximately twenty percent (20%) to approximately thirty percent (30%) curing agent;
wherein the epoxy includes a liquid bisphenol-A based epoxy resin diluted with cresyl glycidyl ether.

### Claim 11 (depends on 1)

The composition of claim 1, wherein the polyamide resin includes a reactive polyamide resin derived from dimerized fatty acid and polyamindes.

### Claim 12 (depends on 1)

The composition of claim 1, wherein the composition excludes perchlorate.

### Claim 13 (depends on 1)

The composition of claim 1, wherein the composition excludes calcium nitrate.

### Claim 14 (depends on 10)

The composition of claim 10, wherein the magnesium fuel is approximately twenty percent (20%) of the composition.

### Claim 15 (depends on 14)

The composition of claim 14, wherein the magnesium fuel includes mixtures of particle sizes.

### Claim 16 (depends on 10)

The composition of claim 10, wherein the sodium nitrate is approximately thirty-seven percent (37%) of the composition.

### Claim 17 (depends on 10)

The composition of claim 10, wherein the barium nitrate is approximately twenty-seven percent (27%) of the composition.

### Claim 18 (depends on 10)

The composition of claim 10, wherein the polyvinyl chloride is approximately eleven percent (11%) of the composition.

### Claim 19 (depends on 10)

The composition of claim 10, wherein the binder system is approximately five percent (5%) of the composition.

### Claim 20 (depends on 10)

The composition of claim 10, wherein the epoxy is approximately three point five percent (3.5%) of the composition.

### Claim 21 (depends on 10)

The composition of claim 10, wherein the curing agent is approximately one point five percent (1.5%) of the composition.
