# US 8,784,516 B2 · Process for the production of hydrogen with intermediate-pressure purging

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- Number: US 8,784,516 B2
- Document ID: US8784516B2
- Status: Granted
- Kind: B2
- Application number: 13/187,844
- Filed: 2011-07-21
- Published: 2012-01-26
- Granted: 2014-07-22
- Earliest claimed: 2010-07-23
- Assignees: Ifp Energies Nouvelles
- Applicants: Beatrice Fischer; Fabrice Giroudiere; Jean-Louis Ambrosino; Michel Thomas
- Inventors: Beatrice Fischer; Fabrice Giroudiere; Jean-Louis Ambrosino; Michel Thomas
- Web page: https://patentgrep.com/patent/US8784516B2

## CPC

- C01B 3/384: with external heating of the catalyst
- C01B 3/48: followed by reaction of water vapour with carbon monoxide
- C01B 3/52: by contacting with liquids; Regeneration of used liquids
- C01B 3/56: by contacting with solids; Regeneration of used solids
- C01B 2203/0227: containing a catalytic reforming step
- C01B 2203/0283: containing a CO-shift step, i.e. a water gas shift step
- C01B 2203/0415: Purification by absorption in liquids
- C01B 2203/043: Regenerative adsorption process in two or more beds, one for adsorption, the other for regeneration
- C01B 2203/047: the impurity being carbon monoxide
- C01B 2203/0475: the impurity being carbon dioxide
- C01B 2203/048: the impurity being an organic compound
- C01B 2203/0495: the impurity being water
- C01B 2203/0822: the fuel containing hydrogen
- C01B 2203/0827: at least part of the fuel being a recycle stream
- C01B 2203/148: involving a recycle stream to the feed of the process for making hydrogen or synthesis gas
- C01B 2203/84: Energy production
- C01B 2203/86: Carbon dioxide sequestration
- Y02C 20/40: of CO2
- Y02P 20/10: Process efficiency
- Y02P 20/151: Reduction of greenhouse gas [GHG] emissions, e.g. CO2
- Y02P 30/00: Technologies relating to oil refining and petrochemical industry
- C01B: NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; {METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C}
- Y02C: CAPTURE, STORAGE, SEQUESTRATION OR DISPOSAL OF GREENHOUSE GASES [GHG]
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

## Abstract

This invention relates to a process for the production of hydrogen from a hydrocarbon feedstock and water vapor comprising: A stage for the production of a synthetic gas in a vapor reforming unit of the hydrocarbon feedstock in the presence of water vapor, with a fuel that provides the heat that is necessary to the reaction, A stage for conversion to vapor of the synthetic gas that is obtained in the preceding stage producing a hydrogen stream that contains methane and carbon dioxide, A stage for recovering carbon dioxide that is present in the stream that is obtained in the stage for conversion to vapor, making it possible to separate the carbon dioxide from the hydrogen stream, A stage for recovery and recycling to the vapor reforming stage of impurities that are present in the hydrogen stream, comprising a decompression phase.

## Claims

### Claim 1

Process for the production of hydrogen from a hydrocarbon feedstock and water vapor that comprises:
A stage for the production of a synthetic gas in a vapor reforming unit of the hydrocarbon feedstock in the presence of water vapor, with a fuel that provides the heat that is necessary to the reaction,
A stage for conversion to vapor of the synthetic gas that is obtained in the preceding stage producing a hydrogen stream that contains methane and carbon dioxide,
A stage for recovering carbon dioxide that is present in the stream that is obtained in the stage for conversion to vapor, making it possible to separate the carbon dioxide from the hydrogen stream,
A stage for recovery and recycling to the vapor reforming of impurities that are present in the hydrogen stream, comprising a decompression phase that is carried out at a pressure of between 0.2 MPa and 1.4 MPa 1.4 MPa; and wherein the phase for decompression and regeneration of the adsorber is produced in the following way:
Isolation of the first adsorber and putting the second adsorber on line,
Decompression of the first adsorber, recompression and flushing of the first adsorber, with a hydrocarbon feedstock stream that is designed to serve as feedstock in the vapor reforming unit, and heated by exchange with the water vapor that is also intended for the vapor reforming unit, up to a temperature that is greater by at least 20° C. than the condensation temperature of the water vapor,
Regeneration of the reheated adsorber and desorption of impurities by circulation of water vapor that is superheated by at least 20° C. intended for the vapor reforming unit,
Elimination of the water vapor that is present in the adsorber that is regenerated by a flushing of the adsorber with a pure and hot hydrogen stream,
Flushing of the adsorber from which water vapor is removed by a pure and cold hydrogen stream.

### Claim 2 (depends on 1)

Process for the production of hydrogen according to claim 1, in which the stage for recovery and recycling of impurities is carried out in an adsorption unit that comprises at least two adsorbers and comprises at least the following successive phases:
Adsorption of impurities on the first adsorber,
Decompression and regeneration of the first adsorber,
Adsorption of impurities on the second adsorber.

### Claim 3 (depends on 1)

Process for the production of hydrogen according to claim 1, in which the decompression phase is carried out at a temperature of between 20° C. and 100° C.

### Claim 4 (depends on 1)

Process for the production of hydrogen according to claim 1, in which the decompression phase is carried out at a speed of between 0.05 MPa per minute and 2 MPa per minute.

### Claim 5 (depends on 1)

Process for the production of hydrogen according to claim 1, in which the decompression phase produces a hydrogen stream that is burned in the vapor reforming unit.

### Claim 6 (depends on 1)

Process for the production of hydrogen according to claim 1, in which the decompression phase produces a hydrogen stream that is sent in a mixture with a portion of a hydrogen stream that is hot and saturated with water vapor, obtained after the flushing of the regenerated adsorber, which is burned in the vapor reforming unit.

### Claim 7 (depends on 1)

Process for the production of hydrogen according to claim 1, in which, at the end of the elimination of the water vapor, a portion of the hydrogen stream that is obtained and that is hot and saturated by water vapor is sent, which is burned in the reforming unit, and the other portion of the stream is sent in a mixture with the dilution water vapor to a gas turbine to produce electricity.

### Claim 8 (depends on 1)

Process for the production of hydrogen according to claim 1, in which, at the end of the elimination of water vapor, a portion of the hydrogen stream that is obtained after the flushing of the regenerated adsorber is sent to an outside unit, while the rest of the hydrogen is used for the hot flushing and then sent to the burners of the reforming unit.

### Claim 9 (depends on 1)

Process for the production of hydrogen according to claim 1, in which, at the end of flushing with cold hydrogen, the stream of reheated hydrogen that is obtained after the cooling phase of the adsorber is again reheated by exchange with the water vapor and used in the phase for elimination of the water vapor that is present in the adsorber.

### Claim 10 (depends on 1)

Process for the production of hydrogen according to claim 1, in which the hydrocarbon feedstock is natural gas.

### Claim 11 (depends on 1)

Process for the production of hydrogen according to claim 1, in which the adsorbed impurities are methane, carbon dioxide, and carbon monoxide.

### Claim 12 (depends on 1)

Process for the production of hydrogen according to claim 1, in which the stage for production of synthetic gas is produced at a pressure of between 2.5 MPa and 3.5 MPa.

### Claim 13 (depends on 1)

Process for the production of hydrogen according to claim 1, in which the stage for recovery of carbon dioxide is carried out in an amine unit that uses methyl diethylamine and at least one other amine.