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US 8,778,466 B2Granted
Liquid-crystal display
AssigneeMerck Patent GmbH
InventorsGeorg Bernatz, Andreas Taugerbeck
Life of this patent
Estimating the term…
Abstract
The present invention relates to a liquid-crystal display of the PSA (polymer sustained alignment) type, and to novel liquid-crystal media and novel polymerizable compounds for use in PSA displays.
Claims32
A polymer sustained alignment (PSA) liquid-crystal (LC) display comprising:
- an LC cell having two substrates, wherein at least one substrate is transparent to light and at least one substrate has an electrode layer, and a layer of a low-molecular-weight LC medium positioned between said substrates,
- said LC medium comprising one or more polymerised compounds, wherein said polymerised compound(s) is (are) obtained by polymerisation of one or more polymerisable compounds between the substrates of the LC cell in the LC medium with application of an electrical voltage,
- wherein at least one of the polymerisable compounds has a biaryl structural element of Formula I
- which is linked at at least one position to one or more polymerisable groups, optionally via an organic group or a spacer group,
- wherein A and B are each, independently of one another, an aromatic or fully or partially saturated ring, in which, in the individual rings, one or more CH groups are each optionally replaced by N, and one or more CH2 groups are each optionally replaced by O or S in such a way that O and/or S atoms are not linked directly to one another, and where the individual rings may also be mono- or polysubstituted, and
- wherein said at least one polymerisable compound which contains a structural element of Formula I is employed as a racemate.
3 more elements
A LC medium comprising:
- one or more polymerised compounds, wherein said polymerised compound(s) is (are) obtained by polymerisation of one or more polymerisable compounds with application of an electrical voltage,
- wherein at least one of the polymerisable compounds has a biaryl structural element of Formula I
- which is linked at at least one position to one or more polymerisable groups, optionally via an organic group or a spacer group,
- wherein A and B are each, independently of one another, an aromatic or fully or partially saturated ring, in which, in the individual rings, one or more CH groups are each optionally replaced by N, and one or more CH2 groups are each optionally replaced by O or S in such a way that O and/or S atoms are not linked directly to one another, and where the individual rings may also be mono- or polysubstituted, and
- wherein said at least one polymerisable compound which contains a structural element of Formula I is employed as a racemate.
2 more elements
A polymerisable compound selected from formula I1b1
- in which
- A and B are each, independently of one another, an aromatic or fully or partially saturated ring, in which, in the individual rings, one or more CH groups are each optionally replaced by N, and one or more CH2 groups are each optionally replaced by O or S in such a way that O and/or S atoms are not linked directly to one another, and where the individual rings may also be mono- or polysubstituted,
- Y1-2 are each, independently of one another, H, halogen, SF5, NO2, a carbon group or a hydrocarbon group, and Y1 and Y2 contain or is a polymerisable group,
- L is F, Cl, Br, I, —CN, —NO2, —NCO, —NCS, —OCN, —SCN, —C(═O)N(Rx)2, —C(═O)Y7, —C(═O)Rx, —N(Rx)2, optionally substituted silyl, aryl having 6 to 40, straight-chain or branched alkyl having 1 to 25 C atoms, alkoxy having 1 to 25 C atoms, alkylcarbonyl having up to 25 C atoms, alkoxycarbonyl having up to 25 C atoms having up to 25 C atoms, alkylcarbonyloxy having up to 25 C atoms, or alkoxycarbonyloxy having up to 25 C atoms, in which one or more H atoms are each optionally replaced by F or Cl,
- Rx is H, halogen, a straight-chain, branched or cyclic alkyl chain having 1 to 25 C atoms, in which, in addition, one or more non-adjacent C atoms are each optionally replaced by —O—, —S—, —CO—, —CO—O—, —O—CO—, —O—CO—O— and in which one or more H atoms are each optionally replaced by fluorine, or an optionally substituted aryl having 6 to 40 C atoms, aryloxy having 6 to 40 C atoms, heteroaryl having 2 to 40 C atoms, or heteroaryloxy group having 2 to 40 C atoms, and
- Y7 is halogen, and
- r11 and r22 are each 0 or 1.
4 more elements
Dependencies are inferred from the claim text.