# US 8,772,760 B2 · Organic light emitting diode device and method for manufacturing the same > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 8,772,760 B2 - Document ID: US8772760B2 - Status: Granted - Kind: B2 - Application number: 12/950,100 - Filed: 2010-11-19 - Published: 2011-08-11 - Granted: 2014-07-08 - Earliest claimed: 2010-02-09 - Assignees: Samsung Display Co., Ltd. - Applicants: Kie Hyun Nam; Sang-Joon Seo; Sung-Guk An - Inventors: Kie Hyun Nam; Sang-Joon Seo; Sung-Guk An - Web page: https://patentgrep.com/patent/US8772760B2 ## CPC - H10K 59/805: {Electrodes} - H10K 59/8722: {Peripheral sealing arrangements, e.g. adhesives, sealants} - H10K 59/873: {Encapsulations} - H10K: ORGANIC ELECTRIC SOLID-STATE DEVICES ## Abstract An organic light emitting diode device and a manufacturing method thereof. The organic light emitting diode device includes a substrate main body, a transparent electrode formed on the substrate main body, an organic emission layer formed on the transparent electrode, a cover electrode formed on the organic emission layer and made of a metal, and a sealant formed on the substrate main body to overlap an edge of the cover electrode and cover a side surface of the organic emission layer. ## Claims ### Claim 1 An organic light emitting diode device, comprising: a substrate main body; a transparent electrode formed on the substrate main body; an organic emission layer formed on the transparent electrode; a cover electrode formed on the organic emission layer and made of a metal, the cover electrode including an oxide film formed on a first surface of the cover electrode opposite to a second surface of the cover electrode facing the organic emission layer, the oxide film being formed by oxidation of the metal of the first surface, the cover electrode having a thickness in a range of approximately 150 nm to approximately 5000 nm, the oxide film being thin in comparison with the metal of the cover electrode; and a sealant formed on the substrate main body to overlap an edge of the cover electrode and cover a side surface of the organic emission layer, the cover electrode and the sealant effectively suppressing the permeation of moisture or oxygen into the organic emission layer. ### Claim 2 An organic light emitting diode device, comprising: a substrate main body; a transparent electrode formed on the substrate main body; an organic emission layer formed on the transparent electrode; a cover electrode formed on the organic emission layer and being formed of at least one metal selected from aluminum (Al), silver (Ag), gold (Au), and magnesium (Mg), the cover electrode including an oxide film formed on a first surface of the cover electrode opposite to a second surface of the cover electrode facing the organic emission layer, the oxide film being formed by oxidation of the metal of the first surface, the cover electrode having a thickness in a range of approximately 150 nm to approximately 5000 nm, the oxide film being thin in comparison with the metal of the cover electrode; and a sealant formed on the substrate main body to overlap an edge of the cover electrode and cover a side surface of the organic emission layer, the cover electrode and the sealant effectively suppressing the permeation of moisture or oxygen into the organic emission layer. ### Claim 3 (depends on 1) The organic light emitting diode device of claim 1, the transparent electrode being formed of at least one material selected from indium tin oxide (ITO), indium zinc oxide (IZO), zinc oxide (ZnO), and indium oxide (In2O3). ### Claim 4 (depends on 1) The organic light emitting diode device of claim 1, the sealant being made of a frit including inorganic particles. ### Claim 5 (depends on 4) The organic light emitting diode device of claim 4, the inorganic particle being formed of at least one material selected from silicon oxide (SiO2), barium oxide (BaO), bismuth oxide (Bi2O3), aluminum oxide (Al2O3), titanium oxide (TiO2), tantalum oxide (Ta2O5), and zinc oxide (ZnO). ### Claim 6 (depends on 1) The organic light emitting diode device of claim 1, the cover electrode including a plurality of metal layers. ### Claim 7 (depends on 6) The organic light emitting diode device of claim 6, the plurality of metal layers of the cover electrode being made of different metals. ### Claim 8 (depends on 6) The organic light emitting diode device of claim 6, an oxide film being formed on an interface between two neighboring metal layers by oxidation of a metal layer surface. ### Claim 9 A method for manufacturing an organic light emitting diode device, comprising: providing a substrate main body; forming a transparent electrode on the substrate main body; forming an organic emission layer on the transparent electrode; forming a cover electrode including an oxide film by forming a metal layer on the organic emission layer and oxidizing a first surface of the metal layer opposite to a second surface of the metal layer facing the organic emission layer, the cover electrode having a thickness in a range of approximately 150 nm to approximately 5000 nm, the oxide film being thin in comparison with the metal of the cover electrode; and forming a sealant covering a side surface of the organic emission layer on the substrate main body, the cover electrode and the sealant effectively suppressing the permeation of moisture or oxygen into the organic emission layer. ### Claim 10 (depends on 9) The method of claim 9, the cover electrode being formed of at least one metal selected from aluminum (Al), silver (Ag), gold (Au), and magnesium (Mg). ### Claim 11 (depends on 9) The method of claim 9, the transparent electrode being formed of at least one material selected from indium tin oxide (ITO), indium zinc oxide (IZO), zinc oxide (ZnO), and indium oxide (In2O3). ### Claim 12 (depends on 9) The method of claim 9, the cover electrode being formed through sputtering. ### Claim 13 (depends on 9) The method of claim 9, the cover electrode being formed through thermal deposition. ### Claim 14 (depends on 13) The method of claim 13, the organic emission layer being formed through thermal deposition. ### Claim 15 (depends on 9) The method of claim 9, the forming of the sealant including: coating a sealing mixture including a frit, inorganic particles, an organic binder, and a solvent on the substrate main body to cover an edge of the cover electrode; drying the sealing mixture through heat to remove part of the organic binder and the solvent; firstly irradiating a laser beam to the dried sealing mixture to remove the remaining part of the organic binder and the solvent; and secondly irradiating the laser beam to harden the sealing mixture without the organic binder, thereby forming the sealant. ### Claim 16 (depends on 15) The method of claim 15, the inorganic particle being formed of at least one material selected from silicon oxide (SiO2), barium oxide (BaO), bismuth oxide (Bi2O3), aluminum oxide (Al2O3), titanium oxide (TiO2), tantalum oxide (Ta2O5), and zinc oxide (ZnO). ### Claim 17 (depends on 9) The method of claim 9, the cover electrode including a plurality of metal layers. ### Claim 18 (depends on 17) The method of claim 17, the plurality of metal layers of the cover electrode being made of different metals. ### Claim 19 (depends on 17) The method of claim 17, an oxide film being formed on an interface between two neighboring metal layers by oxidation of a metal layer surface.