# US 8,772,374 B2 · Preparation of silica reinforced rubber composition and tire with component thereof > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 8,772,374 B2 - Document ID: US8772374B2 - Status: Granted - Kind: B2 - Application number: 13/656,773 - Filed: 2012-10-22 - Published: 2014-04-24 - Granted: 2014-07-08 - Earliest claimed: 2012-10-22 - Assignees: The Goodyear Tire & Rubber Company - Applicants: Giorgio Agostini; Marc Weydert; Elena Sperotto - Inventors: Giorgio Agostini; Marc Weydert; Elena Sperotto - Web page: https://patentgrep.com/patent/US8772374B2 ## CPC - C08L 7/00: Compositions of natural rubber - B60C 1/0016: {Compositions of the tread} - C08K 5/548: containing sulfur {(C08K5/5477 takes precedence)} - C08K 9/06: with silicon-containing compounds - C08L 9/00: Compositions of homopolymers or copolymers of conjugated diene hydrocarbons - C08L 9/06: Copolymers with styrene - C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06) - B60C: VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES - C08K: Use of inorganic or non-macromolecular organic substances as compounding ingredients (paints, inks, varnishes, dyes, polishes, adhesives C09) ## Abstract The invention relates to the preparation of a rubber composition containing a pre-treated precipitated silica and a tire having a component comprised of such rubber composition. The pre-treated silica is a precipitated silica having been pre-treated with a silica coupling agent comprised of an alkoxyorganomercaptosilane to form a precipitated silica/coupling agent composite prior to its blending with a rubber composition. The rubber composition preparation involves reacting said pretreated silica/coupling agent composite with a combination of bis(3-triethoxysilylpropyl) polysulfides in situ within the rubber composition. ## Claims ### Claim 1 A process of preparing a rubber composition is provided which comprises the steps of: (A) blending a rubber composition, in at least one preliminary blending step, comprised of: (1) 100 phr of at least one conjugated diene-based elastomer, (2) from about 25 to about 120 phr of reinforcing filler comprised of pretreated silica, and (3) from about 0.3 to about 8 phr of a combination of two bis(3-triethoxysilylpropyl) polysulfides comprised of: (a) a first bis(3-triethoxysilylpropyl) polysulfide having an average of from 2 to about 2.4 connecting sulfur atoms in its polysulfidic bridge, and (b) a second bis(3-triethoxysilylpropyl) polysulfide having an average of from 3.4 to about 3.8 connecting sulfur atoms in its polysulfidic bridge, wherein a ratio in a range of from about 20/80 to about 80/20 of said first and second bis(3-triethoxysilylpropyl) polysulfides is used, followed by: (B) blending, in a subsequent blending step, with the rubber composition from said preliminary blending step(s) a sulfur curative comprised of elemental sulfur; wherein said pre-treated silica is a precipitated silica treated with a silica coupling agent to form a composite of precipitated silica/coupling agent prior to addition to said rubber composition, wherein said silica coupling agent for said composite is comprised of a siloxyorganomercaptosilane. ### Claim 2 (depends on 1) The process of claim 1 where said diene-based elastomer is comprised of at least one of cis 1,4-polyisoprene, cis 1,4-polybutadiene rubber, styrene-butadiene rubber, styrene-isoprene-butadiene terpolymer rubber, styrene-isoprene rubber and isoprene-butadiene rubber. ### Claim 3 (depends on 1) The process of claim 1 wherein at least one of said elastomers is a tin or silicon coupled diene-based elastomer of styrene and 1,3-butadiene monomers or of 1,3-butadiene monomer. ### Claim 4 (depends on 2) The process of claim 2 wherein at least one of said elastomers is a tin coupled styrene/butadiene elastomer prepared by organic solvent polymerization in the presence of a suitable tin-based catalyst complex using styrene and 1,3-butadiene monomers. ### Claim 5 (depends on 1) The process of claim 1 wherein at least one of said diene-based elastomers is an in-chain or end functionalized diene-based elastomer, wherein said functionalized elastomer contains one or more functional groups comprised of at least one of hydroxyl groups, carboxyl groups, amine groups, siloxy groups, and epoxy groups which are available to participate in a reaction with hydroxyl groups on the said precipitated silica. ### Claim 6 (depends on 5) The process of claim 5 wherein said functionalized elastomer is a styrene/butadiene elastomer containing at least one of amine and siloxy groups. ### Claim 7 (depends on 5) The process of claim 5 wherein said functionalized elastomer is comprised of a tin coupled styrene/butadiene elastomer containing siloxy end functionalization. ### Claim 8 (depends on 3) The process of claim 3 wherein at least one of said diene-based elastomers is an in-chain or end functionalized diene-based elastomer, wherein said functionalized elastomer contains one or more functional groups comprised of at least one of hydroxyl groups, carboxyl groups, amine groups, siloxy groups, and epoxy groups which are available to participate in a reaction with hydroxyl groups on the said precipitated silica.