# US 8,772,115 B2 · Semiconductor device having selectively nitrided gate insulating layer and method of fabricating the same > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 8,772,115 B2 - Document ID: US8772115B2 - Status: Granted - Kind: B2 - Application number: 13/770,709 - Filed: 2013-02-19 - Published: 2013-11-28 - Granted: 2014-07-08 - Earliest claimed: 2012-05-24 - Assignees: Samsung Electronics Co., Ltd. - Applicants: Samsung Electronics Co., Ltd. - Inventors: HyeokJun Son; Sangjin Hyun; Sangbom Kang; SungKee Han; Sughun Hong; Hyung-seok Hong - Web page: https://patentgrep.com/patent/US8772115B2 ## CPC - H10D 84/038: {using silicon technology, e.g. SiGe} - H10D 84/0181: {Manufacturing their gate insulating layers} - H10D: INORGANIC ELECTRIC SEMICONDUCTOR DEVICES ## Abstract A semiconductor device including a selectively nitrided gate insulating layer may be fabricated by a method that includes forming a first gate insulating layer on a substrate having a first region and a second region, performing a nitridation process on the first gate insulating layer, removing the first gate insulating layer from at least a portion of the first region to expose at least a portion of the substrate, forming a second gate insulating layer on at least the exposed portion of the first region of the substrate, thermally treating the first and second gate insulating layers in an oxygen atmosphere, forming a high-k dielectric on the first and second gate insulating layers, and forming a metal gate electrode on the high-k dielectric. ## Claims ### Claim 1 A method of fabricating a semiconductor device, comprising: forming a first gate insulating layer on a substrate having a first region and a second region; performing a nitridation process on the first gate insulating layer; removing the first gate insulating layer from at least a portion of the first region to expose at least a portion of the substrate; forming a second gate insulating layer on at least the exposed portion of the first region of the substrate; thermally treating the first and second gate insulating layers in an oxygen atmosphere; forming a high-k dielectric on the first and second gate insulating layers; and forming a metal gate electrode on the high-k dielectric. ### Claim 2 (depends on 1) The method of claim 1, further comprising forming an interlayered insulating layer having a first trench and a second trench on the substrate, before forming the first gate insulating layer, and wherein forming the interlayered insulating layer comprises: forming a first dummy gate pattern on the first region of the substrate; forming a second dummy gate pattern on the second region of the substrate; forming the interlayered insulating layer to expose top surfaces of the first and second dummy gate patterns; and removing the first and second dummy gate patterns to expose the substrate. ### Claim 3 (depends on 2) The method of claim 2, further comprising fowling spacers on sidewalls of the first and second dummy gate patterns. ### Claim 4 (depends on 2) The method of claim 2, wherein the first and second gate insulating layers are formed on bottom surfaces of the first and second trenches, respectively. ### Claim 5 (depends on 1) The method of claim 1, wherein the first region is a PMOS region and the second region is an NMOS region. ### Claim 6 (depends on 5) The method of claim 5, wherein the first gate insulating layer has a thickness that is greater than that of the second gate insulating layer. ### Claim 7 (depends on 1) The method of claim 1, wherein forming the first gate insulating layer is achieved by at least one process selected from thermal oxidation, radical oxidation, rapid thermal oxidation, ultra-violet oxidation, oxidation using a solution containing oxygenated water and ammonium hydroxide, and ozone oxidation. ### Claim 8 (depends on 1) The method of claim 1, wherein the nitridation of the first gate insulating layer is achieved using at least one process selected from plasma nitridation and rapid thermal nitridation. ### Claim 9 (depends on 1) The method of claim 1, further comprising thermally treating the first gate insulating layer in an oxygen atmosphere after performing the nitridation process and before removing the first gate insulating layer from the first region. ### Claim 10 (depends on 1) The method of claim 1, wherein removing the first gate insulating layer from the first region is performed using hydrogen fluoride. ### Claim 11 (depends on 1) The method of claim 1, wherein forming the second gate insulating layer is achieved by at least one process selected from rapid thermal oxidation, ultra-violet oxidation, oxidation using a solution containing oxygenated water and ammonium hydroxide, and ozone oxidation. ### Claim 12 (depends on 1) The method of claim 1, wherein the thermal treatment of the first and second gate insulating layers in the oxygen atmosphere is performed by at least one process selected from rapid thermal annealing, spike-rapid thermal annealing, flash-rapid thermal annealing, and low-pressure annealing. ### Claim 13 (depends on 1) The method of claim 1, further comprising forming a hydroxyl group on the first and second gate insulating layers, before forming the high-k dielectric. ### Claim 14 (depends on 1) The method of claim 1, wherein the high-k dielectric comprises at least one composition selected from hafnium oxide, hafnium silicon oxide, lanthanum oxide, zirconium oxide, zirconium silicon oxide, tantalum oxide, titanium oxide, barium strontium titanium oxide, barium titanium oxide, strontium titanium oxide, lithium oxide, aluminum oxide, lead scandium tantalum oxide, and lead zinc niobate. ### Claim 15 (depends on 1) The method of claim 1, wherein the metal gate electrode comprises at least one composition selected from titanium (Ti), titanium nitride (TiN), tantalum (Ta), tantalum nitride (TaN), tungsten (W), copper (Cu), aluminum (Al), and mixtures thereof. ### Claim 16 A method of fabricating a semiconductor device, comprising: injecting nitrogen into a first gate insulating layer on a substrate having a first region and a second region via a nitridation process; forming a second gate insulating layer on a portion of the first region of the substrate that is exposed and not covered by the first gate insulating layer; thermally treating the first and second gate insulating layers in an oxygen atmosphere, wherein the thermal treatment moves the nitrogen further away from an interface between the substrate and the first gate insulating layer; forming a high-k dielectric on the first and second gate insulating layers; and forming a metal gate electrode on the high-k dielectric.