# US 8,772,059 B2 · Inline method to monitor ONO stack quality

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- Number: US 8,772,059 B2
- Document ID: US8772059B2
- Status: Granted
- Kind: B2
- Application number: 13/430,631
- Filed: 2012-03-26
- Published: 2013-07-11
- Granted: 2014-07-08
- Earliest claimed: 2011-05-13
- Assignees: Cypress Semiconductor Corporation
- Applicants: Yu Yang; Krishnaswamy Ramkumar
- Inventors: Yu Yang; Krishnaswamy Ramkumar
- Web page: https://patentgrep.com/patent/US8772059B2

## CPC

- H10D 30/69: IGFETs having charge trapping gate insulators, e.g. MNOS transistors
- H10D 30/0413: {of FETs having charge-trapping gate insulators, e.g. MNOS transistors}
- H10P 74/207: {Electrical properties, e.g. testing or measuring of resistance, deep levels or capacitance-voltage characteristics}
- H10D: INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- H10P: GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10

## Abstract

Embodiments of structures and methods for determining operating characteristics of a non-volatile memory transistor comprising a charge-storage-layer and a tunneling-layer are described. In one embodiment, the method comprises: forming on a substrate a structure including a nitrided tunneling-layer and a charge-storage-layer overlying the tunneling-layer comprising a first charge-storage layer adjacent to the tunneling-layer, and a second charge-storage layer overlying the first charge-storage layer, wherein the first charge-storage layer is separated from the second charge-storage layer by a anti-tunneling layer comprising an oxide; depositing a positive charge on the charge-storage-layer and determining a first voltage to establish a first leakage current through the charge-storage-layer and the tunneling-layer; depositing a negative charge on the charge-storage-layer and determining a second voltage to establish a second leakage current through the charge-storage-layer and the tunneling-layer; and determining a differential voltage by calculating a difference between the first and second voltages.

## Claims

### Claim 1

A method comprising:
forming on a substrate a test structure including a tunneling-layer comprising a nitrided oxide and a charge-storage-layer overlying the tunneling-layer, the charge-storage-layer comprising a first charge-storage layer adjacent to the tunneling-layer, and a second charge-storage layer overlying the first charge-storage layer, wherein the first charge-storage layer is separated from the second charge-storage layer by a thin anti-tunneling layer comprising an oxide;
depositing a positive charge at a first site on the uppermost surface of the charge-storage-layer and determining a positive tunneling voltage for the structure;
depositing a negative charge at a second site on the uppermost surface of the charge-storage-layer and determining a negative tunneling voltage for the structure;
determining a differential tunneling voltage by calculating a difference between the positive and negative tunneling voltages.

### Claim 2 (depends on 1)

The method of claim 1, wherein the first charge-storage layer comprises nitride.

### Claim 3 (depends on 2)

The method of claim 2, wherein the second charge-storage layer comprises a high K dielectric.

### Claim 4 (depends on 1)

The method of claim 1, wherein the first site is proximal to the second site.

### Claim 5 (depends on 1)

The method of claim 1, wherein forming the structure comprises forming the structure on a product substrate on which the non-volatile memory transistor is fabricated.

### Claim 6

A method comprising:
forming on a substrate a test structure including a tunneling-layer comprising a nitrided oxide and a charge-storage-layer overlying the tunneling-layer, the charge-storage-layer comprising a first charge-storage layer adjacent to the tunneling-layer, and a second charge-storage layer overlying the first charge-storage layer, wherein the first charge-storage layer is separated from the second charge-storage layer by a thin anti-tunneling layer comprising an oxide;
depositing a positive charge on the uppermost surface of the charge-storage-layer and determining a positive tunneling voltage for the structure;
depositing a negative charge on the uppermost surface of the charge-storage-layer and determining a negative tunneling voltage for the structure;
determining a differential tunneling voltage by calculating a difference between the positive and negative tunneling voltages,
wherein forming the structure comprises removing a blocking-dielectric-layer comprising a high K dielectric overlying the charge-storage-layer.

### Claim 7

A method comprising:
forming on a substrate a test structure including a tunneling-layer comprising a nitrided oxide and a charge-storage-layer overlying the tunneling-layer, the charge-storage-layer comprising a first charge-storage layer adjacent to the tunneling-layer, and a second charge-storage layer overlying the first charge-storage layer, wherein the first charge-storage layer is separated from the second charge-storage layer by a thin anti-tunneling layer comprising an oxide;
depositing a positive charge on the uppermost surface of the charge-storage-layer and determining a positive tunneling voltage for the structure;
depositing a negative charge on the uppermost surface of the charge-storage-layer and determining a negative tunneling voltage for the structure;
determining a differential tunneling voltage by calculating a difference between the positive and negative tunneling voltages; and
determining from the differential tunneling voltage an operating characteristic of a non-volatile memory non-volatile memory transistor comprising a charge-storage-layer and a tunneling-layer fabricated concurrently with the charge-storage-layer and tunneling-layer of the structure,
wherein forming the structure comprises forming the structure on a monitor substrate processed concurrently with a product substrate on which the non-volatile memory transistor is fabricated.

### Claim 8

A method comprising: forming on a substrate a test structure including a tunneling-layer comprising a nitrided oxide and a charge-storage-layer overlying the tunneling-layer, the charge-storage-layer comprising a first charge-storage layer adjacent to the tunneling-layer, and a second charge- storage layer overlying the first charge-storage layer, wherein the first charge-storage layer is separated from the second charge-storage layer by a thin anti-tunneling layer comprising an oxide;
depositing a positive charge on the uppermost surface of the charge-storage-layer and determining a positive tunneling voltage for the structure;
depositing a negative charge on the uppermost surface of the charge-storage-layer and determining a negative tunneling voltage for the structure;
determining a differential tunneling voltage by calculating a difference between the positive and negative tunneling voltage; and
determining from the differential tunneling voltage an operating characteristic of a non-volatile memory transistor comprising a charge-storage-layer and a tunneling-layer fabricated concurrently with the charge-storage-layer and tunneling-layer of the structure; and
halting fabrication of non-volatile memory transistors formed concurrently with the structure when the differential tunneling voltage is outside a specified range of voltages.

### Claim 9 (depends on 8)

The method of claim 8, wherein the second charge-storage layer comprises a high K dielectric.

### Claim 10 (depends on 8)

The method of claim 8, wherein the non-volatile memory transistor further comprises a blocking dielectric layer overlying the charge-storage-layer, wherein the blocking layer comprises a high K dielectric.

### Claim 11 (depends on 8)

The method of claim 8, wherein forming the structure comprises forming the structure on a monitor substrate processed concurrently with a product substrate on which the non-volatile memory transistor is fabricated.

### Claim 12 (depends on 11)

The method of claim 11, wherein the second charge-storage layer comprises a high K dielectric.

### Claim 13 (depends on 8)

The method of claim 8, wherein forming the structure comprises forming the structure on a product substrate on which the non-volatile memory transistor is fabricated.

### Claim 14

A method comprising:
forming a structure including a charge-storage-layer overlying a tunneling-layer on a substrate;
depositing a positive charge at a first site on the uppermost surface of the charge-storage-layer and determining a first voltage to establish a first leakage current through the charge-storage-layer and the tunneling-layer;
depositing a negative charge at a second site on the uppermost surface of the charge-storage-layer and determining a second voltage to establish a second leakage current through the charge-storage-layer and the tunneling-layer; and
determining a differential voltage by calculating a difference between the first and second voltages,
wherein forming the structure comprises removing a blocking-dielectric-layer comprising a high K dielectric overlying the charge-storage-layer.

### Claim 15 (depends on 14)

The method of claim 14, wherein forming the charge-storage-layer comprises a first charge-storage layer adjacent to the tunneling-layer, and a second charge-storage layer overlying the first charge-storage layer.

### Claim 16 (depends on 15)

The method of claim 15, wherein the first charge-storage layer is separated from the second charge-storage layer by a thin anti-tunneling layer comprising an oxide.

### Claim 17 (depends on 14)

The method of claim 14, wherein forming the tunneling-layer comprises forming a tunneling-layer comprising a nitrided oxide.
