# US 8,771,802 B1 · Device and materials fabrication and patterning via shaped slot electrode control of direct electrostatic powder deposition

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- Number: US 8,771,802 B1
- Document ID: US8771802B1
- Status: Granted
- Kind: B1
- Application number: 13/866,100
- Filed: 2013-04-19
- Granted: 2014-07-08
- Earliest claimed: 2012-04-20
- Assignees: Xactiv, Inc.
- Applicants: Xactiv Inc.
- Inventors: Dan A. Hays; James Mason; Peter J. Mason
- Web page: https://patentgrep.com/patent/US8771802B1

## CPC

- B05C 19/025: {Combined with electrostatic means}
- B05D 1/007: {using an electrostatic field (B05D1/02 - B05D1/16 take precedence)}
- B41J 2/4155: {for direct electrostatic printing [DEP]}
- G03G 15/0907: {with bias voltage (G03G15/065 takes precedence)}
- G03G 15/346: {by modulating the powder through holes or a slit}
- B05C: APPARATUS FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL (spraying apparatus, atomising apparatus, nozzles B05B; plant for applying liquids or other fluent materials to objects by electrostatic spraying B05B5/08)
- B05D: PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL (conveying articles or workpieces through baths of liquid B65G, e.g. B65G49/02)
- B41J: TYPEWRITERS; SELECTIVE PRINTING MECHANISMS, i.e. MECHANISMS PRINTING OTHERWISE THAN FROM A FORME; CORRECTION OF TYPOGRAPHICAL ERRORS
- G03G: ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY

## Abstract

An object fabricating apparatus is comprised of at least one charged powder cloud generating system, at least one electrode proximate to the powder cloud generating system and comprising at least one shaped slot, and a voltage supply in communication with each electrode to electrostatically modulate the flow of charged powder to a conductive substrate electrically biased to provide an electrostatic attraction of the charged powder to the substrate. An object fabricating method is also disclosed that uses the object fabricating apparatus.

## Claims

### Claim 1

A method of fabricating an object, the method comprising:
a) causing the formation of a cloud of charged powder having single electrical polarity and proximate to an electrode comprising at least one shaped slot, the electrode disposed between the cloud and a conductive substrate positioned to receive a portion of the charged powder;
b) applying a first bias voltage of a polarity opposite the polarity of the charged powder to the conductive substrate to cause movement of a portion of the charged powder of the single electrical polarity from the cloud through the at least one shaped slot of the electrode to the substrate;
c) applying a second bias voltage of between zero and a non-zero voltage of the same single polarity as the charged powder to the electrode; and
d) varying the magnitude of one of the first and second bias voltages, thereby causing variation in the rate of movement of the portion of the charged powder from the cloud through the at least one shaped slot to the substrate while forming a first part of the object on the substrate.

### Claim 2 (depends on 1)

The method of claim 1, wherein the formation of the cloud of charged powder is caused proximate to a plurality of electrodes, each of the electrodes comprised of at least one shaped slot that can be independently electrically biased.

### Claim 3 (depends on 1)

The method of claim 1, further comprising moving the substrate relative to the electrode.

### Claim 4 (depends on 3)

The method of claim 3, wherein the at least one shaped slot of the electrode has a longitudinal axis perpendicular to the direction of relative motion of the substrate.

### Claim 5 (depends on 3)

The method of claim 3, further comprising moving the substrate past the electrode at least two times, thereby depositing multiple portions of charged powder onto the substrate.

### Claim 6 (depends on 1)

The method of claim 1, further comprising moving the electrode with the substrate.

### Claim 7 (depends on 1)

The method of claim 1, further comprising causing the formation of a plurality of clouds of charged powder proximate to at least a first electrode and a second electrode, each of the electrodes disposed between the clouds and the conductive substrate.

### Claim 8 (depends on 7)

The method of claim 7, wherein the plurality of clouds of charged powder are formed from a plurality of different powder materials.

### Claim 9 (depends on 8)

The method of claim 8, wherein each of the electrodes is comprised of at least one shaped slot for controlling the flow of charged powder from at least one of the clouds of charged powder.

### Claim 10 (depends on 1)

The method of claim 1, wherein the formation of the cloud of charged powder having the single electrical polarity is caused by a magnetic brush deposition system containing a mixture of magnetic carrier beads and triboelectrically charged powder.

### Claim 11 (depends on 10)

The method of claim 10, further comprising causing the formation of a magnetic brush by a rotating magnetic field.

### Claim 12 (depends on 10)

The method of claim 10, further comprising causing magnetic carrier beads to be permanently magnetized.

### Claim 13 (depends on 10)

The method of claim 10, wherein the triboelectrically charged powder is insulating.

### Claim 14 (depends on 10)

The method of claim 10, wherein the triboelectrically charged powder has a charge relaxation time of about 100 milliseconds.

### Claim 15 (depends on 10)

The method of claim 10, wherein the mixture of powder and magnetic carrier beads is comprised of at least about 60 weight percent of magnetic carrier beads.

### Claim 16 (depends on 10)

The method of claim 10, wherein the magnetic carrier beads have an average size of from about 20 micrometers to about 1000 micrometers.

### Claim 17 (depends on 1)

The method of claim 1, wherein the conductive substrate is comprised of a conductive backing layer.

### Claim 18 (depends on 1)

The method of claim 1, wherein the magnitude of the bias voltage applied to the electrode is varied to cause variation in the rate of movement of the portion of the charged powder from the cloud through the at least one shaped slot to the substrate.

### Claim 19 (depends on 1)

The method of claim 1, wherein the powder is selected from insulative powders and charge relaxing powders, and combinations thereof.

### Claim 20 (depends on 1)

The method of claim 1, wherein the at least one shaped slot of the electrode is an elongated slot having a longitudinal axis.

### Claim 21 (depends on 20)

The method of claim 20, further comprising moving the substrate relative to the shaped slot electrode in a direction perpendicular to the longitudinal axis of the at least one shaped slot.

### Claim 22 (depends on 20)

The method of claim 20, wherein the slot is comprised of a central section having opposed first and second parallel edges, a first end section comprised of first and second adjacent arcuate sectors intersected respectively by first ends of the first and second parallel edges, and third and fourth adjacent arcuate sectors intersected respectively by second ends of the first and second parallel edges.