# US 8,771,631 B2 · Method for producing perovskite type composite oxide

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- Number: US 8,771,631 B2
- Document ID: US8771631B2
- Status: Granted
- Kind: B2
- Application number: 13/401,994
- Filed: 2012-02-22
- Published: 2012-08-30
- Granted: 2014-07-08
- Earliest claimed: 2011-02-25
- Assignees: Murata Manufacturing Co., Ltd.
- Applicants: Toshiharu Nakagawa; Norikazu Tachibana; Yasunari Nakamura
- Inventors: Toshiharu Nakagawa; Norikazu Tachibana; Yasunari Nakamura
- Web page: https://patentgrep.com/patent/US8771631B2

## CPC

- H01G 4/1227: {based on alkaline earth titanates}
- B32B 18/00: Layered products essentially comprising ceramics, e.g. refractory products
- C01G 23/006: {Alkaline earth titanates}
- C04B 35/4682: {based on BaTiO3 perovskite phase}
- C04B 35/62685: {characterised by the order of addition of constituents or additives}
- C01P 2002/54: one element only
- C04B 2235/3206: Magnesium oxides or oxide-forming salts thereof
- C04B 2235/3208: Calcium oxide or oxide-forming salts thereof, e.g. lime
- C04B 2235/3215: Barium oxides or oxide-forming salts thereof
- C04B 2235/3224: Rare earth oxide or oxide forming salts thereof, e.g. scandium oxide
- C04B 2235/3232: Titanium oxides or titanates, e.g. rutile or anatase
- C04B 2235/3262: Manganese oxides, manganates, rhenium oxides or oxide-forming salts thereof, e.g. MnO
- C04B 2235/3418: Silicon oxide, silicic acids or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
- C04B 2235/442: Carbonates
- C04B 2235/443: Nitrates or nitrites
- C04B 2235/449: Organic acids, e.g. EDTA, citrate, acetate, oxalate
- C04B 2235/6025: Tape casting, e.g. with a doctor blade
- C04B 2235/761: Unit-cell parameters, e.g. lattice constants
- C04B 2235/765: Tetragonal symmetry
- C04B 2237/346: Titania or titanates
- H01G: CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE (selection of specified materials as dielectric H01B3/00; capacitors having potential barriers H10D1/62, H10K10/10)
- B32B: LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- C01G: COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F (metal hydrides {monoborane, diborane or addition complexes thereof} C01B6/00; salts of oxyacids of halogens C01B11/00; peroxides, salts or peroxyacids C01B15/00; thiosulfates, dithionites, polythionates C01B17/64; compounds containing selenium, or tellurium C01B19/00; binary compounds of nitrogen with metals C01B21/06; azides C01B21/08; {compounds containing nitrogen, other non-metals and metal C01B21/082}; metal amides C01B21/092; nitrites C01B21/50; {compounds of noble gases C01B23/0005}; phosphides C01B25/08; salts of oxyacids of phosphorus C01B25/16; carbides C01B32/90; compounds containing silicon C01B33/00; compounds containing boron C01B35/00; compounds having molecular sieve properties but not having base-exchange properties C01B37/00; compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites, C01B39/00; cyanides C01C3/08; salts of cyanamide C01C3/16; thiocyanates C01C3/20)
- C04B: LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE {(roofing granules E04D7/005)}; CERAMICS (devitrified glass-ceramics C03C10/00); REFRACTORIES; TREATMENT OF NATURAL STONE
- C01P: INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS

## Abstract

A method is provided which includes a reaction step of reacting at least titanium oxide, a calcium compound, and barium hydroxide in a slurry solution so as to produce a perovskite-type composite oxide. The perovskite-type composite oxide is represented by (Ba1-xCax)mTiO3, and x is within a range of 0<x≦0.125. In addition, the method provides a perovskite-type composite oxide in which a water-soluble calcium compound is used as the calcium compound, and when the perovskite-type composite oxide is represented by (Ba1-xCax)mTiO3, x is within a range of 0<x≦0.20.

## Claims

### Claim 1

A method for producing a perovskite composite oxide represented by ABO3, wherein A comprises Ba and Ca, the amount of Ca is up to 0.125 moles based on the total moles of Ba and Ca, and B comprises Ti, the method comprising: reacting titanium oxide, calcium carbonate, and barium hydroxide in a slurry so as to produce a perovskite composite oxide.

### Claim 2 (depends on 1)

The method for producing a perovskite composite oxide according to claim 1, further comprising applying a heat treatment to the perovskite composite oxide.

### Claim 3 (depends on 2)

The method for producing a perovskite composite oxide according to claim 2, wherein the heat treatment is applied at a temperature of 800° C. to 1050° C.

### Claim 4 (depends on 2)

The method for producing a perovskite composite oxide according to claim 2, wherein the heat treatment is applied so as to produce a tetragonal perovskite composite oxide.

### Claim 5

A method for producing a perovskite composite oxide represented by ABO3, wherein A comprises Ba and Ca, the amount of Ca is up to 0.125 moles based on the total moles of Ba and Ca, and B comprises Ti, the method comprising: reacting titanium oxide, a water-soluble calcium compound having a water solubility of calcium acetate or greater, and barium hydroxide in a slurry so as to produce a perovskite composite oxide.

### Claim 6 (depends on 5)

The method for producing a perovskite composite oxide according to claim 5, wherein the water-soluble calcium compound is calcium acetate or calcium nitrate.

### Claim 7 (depends on 5)

The method for producing a perovskite composite oxide according to claim 5, further comprising applying a heat treatment to the perovskite composite oxide.

### Claim 8 (depends on 7)

The method for producing a perovskite composite oxide according to claim 7, wherein the heat treatment is applied at a temperature of 800° C. to 1050° C.

### Claim 9 (depends on 7)

The method for producing a perovskite composite oxide according to claim 7, wherein the heat treatment is applied so as to produce a tetragonal perovskite composite oxide.

### Claim 10 (depends on 5)

The method for producing a perovskite composite oxide according to claim 5, wherein the amount of Ca is at least 0.075 moles based on the total moles of Ba and Ca.

### Claim 11 (depends on 10)

The method for producing a perovskite composite oxide according to claim 10, comprising applying a heat treatment at a temperature of 800° C. to 1050° C. to the perovskite-type composite oxide.

### Claim 12 (depends on 1)

The method for producing a perovskite composite oxide according to claim 1, wherein the amount of Ca is 0.05 to 0.15 moles based on the total moles of Ba and Ca.

### Claim 13 (depends on 12)

The method for producing a perovskite composite oxide according to claim 12, comprising applying a heat treatment at a temperature of 800° C. to 1050° C. to the perovskite composite oxide.
