# US 8,771,630 B2 · Method for the preparation of graphene

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- Number: US 8,771,630 B2
- Document ID: US8771630B2
- Status: Granted
- Kind: B2
- Application number: 13/358,912
- Filed: 2012-01-26
- Published: 2013-08-01
- Granted: 2014-07-08
- Earliest claimed: 2012-01-26
- Assignees: Enerage Inc.
- Applicants: Yi-Shuen Wu; Cheng-Yu Hsieh; Cheng-Shu Peng; Jing-Ru Chen; Jun-Meng Lin; Geng-Wei Lin
- Inventors: Yi-Shuen Wu; Cheng-Yu Hsieh; Cheng-Shu Peng; Jing-Ru Chen; Jun-Meng Lin; Geng-Wei Lin
- Web page: https://patentgrep.com/patent/US8771630B2

## CPC

- C01B 32/192: starting from graphitic oxides
- B82Y 30/00: Nanotechnology for materials or surface science, e.g. nanocomposites
- B82Y 40/00: Manufacture or treatment of nanostructures
- C01B 32/00: Carbon; Compounds thereof (C01B21/00, C01B23/00 take precedence; percarbonates C01B15/10; carbon black C09C1/48)
- C04B 35/532: containing a carbonisable binder
- C01B: NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; {METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C}
- B82Y: SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- C04B: LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE {(roofing granules E04D7/005)}; CERAMICS (devitrified glass-ceramics C03C10/00); REFRACTORIES; TREATMENT OF NATURAL STONE

## Abstract

A method for the preparation of graphene is provided, which includes: (a) oxidizing a graphite material to form graphite oxide; (b) dispersing graphite oxide into water to form an aqueous suspension of graphite oxide; (c) adding a dispersing agent to the aqueous suspension of graphite oxide; and (d) adding an acidic reducing agent to the aqueous suspension of graphite oxide, wherein graphite oxide is reduced to graphene by the acidic reducing agent, and graphene is further bonded with the dispersing agent to form a graphene dispersion containing a surface-modified graphene. The present invention provides a method for the preparation of graphene using an acidic reducing agent. The obtained graphene can be homogeneously dispersed in water, an acidic solution, a basic solution, or an organic solution.

## Claims

### Claim 1

A method for the preparation of graphene, comprising:
(a) oxidizing a graphite material to form graphite oxide;
(b) dispersing graphite oxide into water to form an aqueous suspension of graphite oxide;
(c) adding a dispersing agent to the aqueous suspension of graphite oxide; and (d) adding an acidic reducing agent to the aqueous suspension of graphite oxide, graphite oxide being reduced to graphene by the acidic reducing agent, graphene being further bonded with the dispersing agent to form a grapheme dispersion including a surface-modified graphene,
wherein the dispersing agent has two terminal ends, and has a cholic acid group at its one terminal end, and has a phenyl group at its another terminal end, the cholic acid group at one terminal end of the dispersing agent is bonded to the surface of graphene, and thereby the surface of graphene is modified by the presence of the phenyl group at another terminal end of the dispersing agent, and the acidic reducing agent is selected from the group consisting of ascorbic acid, citric acid, and polyphenol.

### Claim 2 (depends on 1)

The method according to claim 1, wherein, the graphite material is selected from the group consisting of natural graphite, expandable graphite, artificial graphite, graphite fiber, carbon nano-tube, and mesophase carbon micro-bead.

### Claim 3 (depends on 1)

The method according to claim 1, wherein the dispersing agent is selected from the group consisting of cholate, deoxycholate, and taurodeoxycholate.

### Claim 4 (depends on 1)

The method according to claim 1, further comprising the step of: (e) drying the graphene dispersion to obtain graphene powder including the surface-modified graphene.