# US 8,771,598 B2 · Ammonia storage system

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- Number: US 8,771,598 B2
- Document ID: US8771598B2
- Status: Granted
- Kind: B2
- Application number: 12/653,490
- Filed: 2009-12-15
- Published: 2010-07-08
- Granted: 2014-07-08
- Earliest claimed: 2009-01-02
- Assignees: Sensirion AG
- Applicants: Felix Mayer; Mark Hornung; Lukas Bürgi; Pascal Gerner
- Inventors: Felix Mayer; Mark Hornung; Lukas Bürgi; Pascal Gerner
- Web page: https://patentgrep.com/patent/US8771598B2

## CPC

- F01N 3/2066: {Selective catalytic reduction [SCR]}
- F01N 2560/023: for measuring or detecting HC
- F01N 2560/025: for measuring or detecting O2, e.g. lambda sensors
- F01N 2610/14: Arrangements for the supply of substances, e.g. conduits
- F01N 2610/1406: Storage means for substances, e.g. tanks or reservoirs
- Y02A 50/20: Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
- Y02T 10/12: Improving ICE efficiencies
- F01N: GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR MACHINES OR ENGINES IN GENERAL; GAS-FLOW SILENCERS OR EXHAUST APPARATUS FOR INTERNAL-COMBUSTION ENGINES (arrangements in connection with gas exhaust of propulsion units in vehicles B60K13/00; combustion-air intake silencers specially adapted for, or arranged on, internal-combustion engines F02M35/00; protecting against, or damping, noise in general G10K11/16)
- Y02A: TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02T: CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION

## Abstract

A system for storing ammonia comprises gas detector that is able to detect gases other than ammonia. The system further comprises thermally activatable ammonia stores, which can be activated to release ammonia upon heating. When the ammonia stores are not heated, the system is below ambient pressure and any leak will cause external gas to enter the system. Therefore, the gas detector is used to detect the presence of such external gas, which allows to detect leaks. The gas detector may be embodied as a thermal detector using a single heater and two temperature sensors for detecting a gas flow as well as external gas.

## Claims

### Claim 1

An ammonia storage system comprising:
an ammonia containing section;
a thermally activatable ammonia store disposed in said ammonia containing section;
a valve, wherein opening of the valve allows ammonia gas to flow out of the ammonia containing section through the valve and wherein when said valve is closed, in the absence of a leak, the ammonia containing section contains pure ammonia;
a duct of the ammonia containing section connecting the ammonia store to the valve;
a heater for thermally activating said ammonia store, wherein thermal activation of the ammonia store by the heater releases ammonia into said ammonia containing section, and further comprising
a gas detector disposed in the ammonia containing section at the duct and configured to detect a thermal conductivity of gas within the ammonia containing section;
wherein the system is adapted to issue an alert if the detector detects a thermal conductivity different from the thermal conductivity of pure ammonia.

### Claim 2 (depends on 1)

The ammonia storage system of claim 1 wherein the gas detector is adapted for measuring a gas flow in said duct.

### Claim 3 (depends on 1)

The ammonia storage system of claim 1 wherein the gas detector comprises a heater, and wherein said heater is adapted for measuring a gas flow in said duct.

### Claim 4 (depends on 3)

The ammonia storage system of claim 3 wherein the gas detector comprises at least one temperature sensor adapted to measure a temperature change induced by said heater.

### Claim 5 (depends on 4)

The ammonia storage system of claim 4 further comprising at least a first and a second temperature sensor located at different positions in respect to said heater with said heater being arranged between said first and second temperature sensor such that one of said temperature sensors is arranged upstream and the other one of said temperature sensors is arranged downstream of said heater.

### Claim 6 (depends on 5)

The ammonia storage system of claim 5 further comprising a control unit designed for calculating said gas flow by using a difference between signals from said first and said second temperature sensor and designed for detecting the presence of a gas other than ammonia from the signal of at least one of said temperature sensors.

### Claim 7 (depends on 6)

The ammonia storage system of claim 6 wherein said control unit is designed for detecting the presence of a gas other than ammonia by using a sum of signals from said first and said second temperature sensor.

### Claim 8 (depends on 2)

The ammonia storage system of claim 2 further comprising a system controller adapted to detect a leak downstream from said flow detector by detecting a non-zero flow at said flow detector when said valve is closed.

### Claim 9 (depends on 1)

A method for operating the ammonia storage system of claim 1 wherein said gas detector is operated at least when said ammonia store is not being activated in order to detect said gas other than ammonia.

### Claim 10 (depends on 9)

The method of claim 9 wherein a thermal flow detector is a duct of said ammonia containing section is used for measuring an ammonia flow in said duct as well as for detecting said gas other than ammonia.

### Claim 11 (depends on 10)

The method of claim 10 wherein said flow detector is used for measuring a leak downstream from said flow detector by detecting a non-zero flow or a downstream-upstream flow.

### Claim 12 (depends on 1)

Use of the system of claim 1 as an ammonia source in a vehicle for controllably releasing ammonia in a Selective Catalytic Reduction (SCR) process for the catalytic decomposition of NOx compounds.

### Claim 13 (depends on 1)

The ammonia storage system of claim 1, wherein the storage system is provided in a vehicle for controllably releasing ammonia in a Selective Catalytic Reduction (SCR) process for the catalytic decomposition of NOx compounds.

### Claim 14

An ammonia storage system comprising:
an ammonia containing section;
a thermally activatable ammonia store disposed in said ammonia containing section;
a valve, wherein opening of the valve allows ammonia gas to flow out of the ammonia containing section through the valve and wherein when said valve is closed, in the absence of a leak, the ammonia containing section contains pure ammonia;
a duct of the ammonia containing section connecting the ammonia store to the valve;
a heater for thermally activating said ammonia store, wherein thermal activation of the ammonia store by the heater releases ammonia into said ammonia containing section, and further comprising
a gas detector disposed in the ammonia containing section at the duct,
wherein said gas detector is adapted to detect the presence of a gas other than ammonia in said ammonia containing section by measuring a heat capacity of gas within the ammonia containing section.

### Claim 15 (depends on 1)

The ammonia storage system of claim 1, wherein said thermally activatable ammonia store comprises ammonia physically or chemically bound in a solid storage matrix.

### Claim 16 (depends on 2)

The ammonia storage system of claim 2, wherein said thermally activatable ammonia store comprises ammonia physically or chemically bound in a solid storage matrix.

### Claim 17 (depends on 3)

The ammonia storage system of claim 3, wherein said thermally activatable ammonia store comprises ammonia physically or chemically bound in a solid storage matrix.

### Claim 18 (depends on 7)

The ammonia storage system of claim 7, wherein said thermally activatable ammonia store comprises ammonia physically or chemically bound in a solid storage matrix.

### Claim 19 (depends on 8)

The ammonia storage system of claim 8, wherein said thermally activatable ammonia store comprises ammonia physically or chemically bound in a solid storage matrix.

### Claim 20 (depends on 14)

The ammonia storage system of claim 14, wherein said thermally activatable ammonia store comprises ammonia physically or chemically bound in a solid storage matrix.