# US 8,771,474 B2 · Crude treatment system

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- Number: US 8,771,474 B2
- Document ID: US8771474B2
- Status: Granted
- Kind: B2
- Application number: 12/927,887
- Filed: 2010-11-29
- Published: 2011-07-14
- Granted: 2014-07-08
- Earliest claimed: 2010-01-12
- Assignees: Jgc Corporation
- Applicants: Naoaki Sawai
- Inventors: Naoaki Sawai
- Web page: https://patentgrep.com/patent/US8771474B2

## CPC

- C10G 75/00: Inhibiting corrosion or fouling in apparatus for treatment or conversion of hydrocarbon oils, in general (C10G7/10, C10G9/16 take precedence)
- C10G 7/00: Distillation of hydrocarbon oils
- C10G 7/10: Inhibiting corrosion during distillation
- C10G: CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION (cracking to hydrogen or synthesis gas C01B; cracking or pyrolysis of hydrocarbon gases to individual hydrocarbons or mixtures thereof of definite or specified constitution C07C; cracking to cokes C10B); RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES

## Abstract

A crude treatment system includes a primary and second distillation tower for treating crude containing corrosive material. The primary distillation tower fractionates first crude into a target fraction. The secondary distillation tower fractionates second crude having a corrosive material content greater than that of the first crude into a light fraction and a remaining heavy fraction. Corrosive material in the light fraction is insufficient to corrode the primary distillation tower. A light fraction supply line supplies the light fraction from the secondary distillation tower to the primary distillation tower for treatment. The secondary distillation tower and the supply line are made from a corrosion resistant material.

## Claims

### Claim 1

A crude treatment system comprising:
a primary distillation tower which fractionates first crude supplied from a first crude supply line into a target fraction;
a secondary distillation tower which fractionates second crude into a light fraction and a remaining heavy fraction, the light fraction having a first content of naphthenic acid, the second crude being supplied from a second crude supply line and including naphthenic acid as a corrosive material at a content greater than in the first crude; and
a light fraction supply line which supplies the light fraction to the primary distillation tower to be treated; and
wherein the second crude supply line and the secondary distillation tower are made from a first material having corrosion resistance with respect to the naphthenic acid in an environment in which the second crude supply line and the secondary distillation tower contact naphthenic acid from either one or both of the second crude and the heavy fraction; and
wherein the first crude supply line and the primary distillation tower are made from a second material having lesser corrosion resistance against naphthenic acid than the first material.

### Claim 2 (depends on 1)

The crude treatment system according to claim 1, further comprising:
a vacuum distillation tower which distills the heavy fraction into a target fraction in a vacuum condition; and
a heavy fraction supply line which supplies the heavy fraction from the secondary distillation tower to the vacuum distillation tower to be processed; and
wherein the vacuum distillation tower and the heavy fraction supply line are made from a third material having corrosion resistance with respect to the naphthenic acid in an environment in which the vacuum distillation tower and the heavy fraction supply line contact the heavy fraction; and
wherein the second material of the first crude supply line and the primary distillation tower has lower corrosion resistance against naphthenic acid than the third material.

### Claim 3 (depends on 2)

The crude treatment system according to claim 2, further comprising:
a residue fraction supply line which supplies a residue fraction, fractionated from the bottom portion of the primary distillation tower, to the vacuum distillation tower to be processed.

### Claim 4 (depends on 1)

The crude treatment system according to claim 1,
wherein said first material, from which the second crude supply line and the secondary distillation tower are made, is selected from the group consisting of stainless steel type 317, 317L, 316 (where Mo content is 2.5% or more) and 316L (where Mo content is 2.5% or more).

### Claim 5 (depends on 1)

The crude treatment system according to claim 1,
wherein the naphthenic acid is contained in acid materials of which the content is specified by a total acid number.

### Claim 6 (depends on 5)

The crude treatment system according to claim 5,
wherein the total acid number of the light fraction is 0.5 mg-KOH/g or less.

### Claim 7 (depends on 5)

The crude treatment system according to claim 5,
wherein the material having corrosion resistance is used for a portion where the inner temperature is 230° C. or more.

### Claim 8 (depends on 1)

The crude treatment system according to claim 1,
wherein the second crude includes crude selected from a crude group consisting of Mayan crude, Orinoco tar, and oil sand/bitumen.

### Claim 9 (depends on 2)

The crude treatment system according to claim 2, wherein the third material from which the vacuum distillation tower and the heavy fraction supply line are made is selected from the group consisting of stainless steel type 317, 317L, 316 (where Mo content is 2.5% or more), and 316L (where Mo content is 2.5% or more).

### Claim 10 (depends on 1)

The crude treatment system according to claim 1, wherein the first crude supply line and the primary distillation tower are made from a second material having corrosion resistance for the sulfidation corrosion.

### Claim 11 (depends on 10)

The crude treatment system according to claim 10, wherein the first material from which the first crude supply line and the primary distillation tower are made is selected from the group consisting of 5Cr—0.5Mo steel and 18Cr steel.
