# US 8,770,267 B2 · Adsorption module and method of manufacturing the same > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 8,770,267 B2 - Document ID: US8770267B2 - Status: Granted - Kind: B2 - Application number: 11/904,585 - Filed: 2007-09-27 - Published: 2008-04-03 - Granted: 2014-07-08 - Earliest claimed: 2006-09-29 - Assignees: Denso Corporation - Applicants: Hisao Nagashima; Masaaki Tanaka; Satoshi Inoue; Hiroshi Mieda; Seiji Inoue; Katsuya Komaki - Inventors: Hisao Nagashima; Masaaki Tanaka; Satoshi Inoue; Hiroshi Mieda; Seiji Inoue; Katsuya Komaki - Web page: https://patentgrep.com/patent/US8770267B2 ## CPC - F28D 7/16: the conduits being arranged in parallel spaced relation ({F28D7/0008 - F28D7/0058 take precedence}; F28D7/02 - F28D7/10 take precedence) - B22F 3/11: Making porous workpieces or articles - F25B 35/04: using a solid as sorbent - F28F 13/003: {by using permeable mass, perforated or porous materials (F28F13/18 takes precedence)} - Y10T 29/49384: Internally finned - F28D: HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT (fluid heaters having heat generating means and heat transferring means F24H; furnaces F27; details of heat-exchange apparatus of general) - B22F: WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER (making alloys by powder metallurgy C22C); APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER - F25B: REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS - F28F: DETAILS OF HEAT-EXCHANGE AND HEAT-TRANSFER APPARATUS, OF GENERAL APPLICATION (water and air traps, air venting F16) - Y10T: TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION ## Abstract An adsorption module has heat medium pipes through which a fluid flows, a porous heat transferring member, and adsorbent. The porous heat transferring member is a sintered body formed by sintering a metallic material that is in a form of one of powders, particles and fibers, and has pores for allowing an adsorbed medium to pass through. The porous heat transferring member is disposed on peripheries of the heat medium pipes and bonded to outer surfaces of the heat medium pipes by sintering. The adsorbent is disposed in the pores. The porous heat transferring member further has an adsorbed medium passage for allowing the adsorbed medium to pass through. The adsorbed medium passage is located between the heat medium pipes, and extends straight and parallel to axes of the heat medium pipes. ## Claims ### Claim 1 An adsorption module comprising: a casing having an adsorbed medium inlet and an adsorbed medium outlet; a plurality of heat medium pipes disposed within the casing allowing a heat exchange medium to pass through; a porous heat transferring member disposed within the casing and on peripheries of the heat medium pipes, the porous heat transferring member being a sintered body that is formed by sintering a metallic material in a form of one of powders, particles and fibers, and being connected to outer surfaces of the heat medium pipes by metal-to-metal bonding, the porous heat transferring member including pores allowing an adsorbed medium to pass through; adsorbent different than the adsorbed medium disposed in the pores of the porous heat transferring member; and a plurality of adsorbed medium passages formed by the porous heat transferring member, each passage allowing the adsorbed medium to flow through the passage, wherein the adsorbed medium passages extend straight and parallel to axes of the heat medium pipes; each of the heat medium pipes being encircled by two or more adsorbed medium passages; the adsorbent has a porous structure providing pores absorbing and desorbing the adsorbed medium which is gas-phase refrigerant; the sintered body of the porous heat transferring member is formed with three-dimensional mesh-like small holes which provide the pores of the porous heat transferring member, the adsorbent is substantially evenly filled in the pores of the porous heat transferring member; the casing has a communication space in communication with both the adsorbed medium inlet and the adsorbed medium outlet; and the adsorbed medium passages are open to and in communication with the communication space. ### Claim 2 (depends on 1) The adsorption module according to claim 1, wherein the adsorbed medium passages and the heat medium pipes are arranged such that each of a heat transferring distance and an osmotic distance is at least 0.5 mm and at most 6 mm, the heat transferring distance being defined by half of a distance between an outer surface of one heat medium pipe and an outer surface of an adjacent heat medium pipe, and the osmotic distance being defined by a distance from an inner surface of one of the adsorbed medium passages to an outer surface of an adjacent heat medium pipe. ### Claim 3 (depends on 2) The adsorption module according to claim 2, wherein each of the heat transferring distance and the osmotic distance is at least 0.8 mm and at most 4.8 mm. ### Claim 4 (depends on 3) The adsorption module according to claim 3, wherein each of the heat transferring distance and the osmotic distance is at least 1.5 mm and at most 3.8 mm. ### Claim 5 (depends on 1) The adsorption module according to claim 1, wherein each of the heat medium pipes has a flat tubular shape. ### Claim 6 (depends on 1) The adsorption module according to claim 1, wherein the adsorbed medium passages are disposed parallel to axes of the heat medium pipes and allows the adsorbed medium to flow at least in one direction. ### Claim 7 (depends on 1) The adsorption module according to claim 1, wherein each of the adsorbed medium passages includes a plurality of passage portions extending in a direction parallel to axes of the heat medium pipes and in a direction intersecting the axes of the heat medium pipes, and the plurality of passage portions are in communication with each other. ### Claim 8 (depends on 7) The adsorption module according to claim 7, wherein each of the plurality of passage portions has an annular shape in a cross-section defined in a direction perpendicular to the axes of the heat medium pipes. ### Claim 9 (depends on 1) The adsorption module according to claim 1, wherein the porous heat transferring member includes a plurality of peripheral portions, each of which is disposed on a periphery of the heat medium pipe, and each of the adsorbed medium passages include a plurality of passage portions, each of which entirely surrounds the peripheral portion. ### Claim 10 (depends on 1) The adsorption module according to claim 1, wherein: the adsorbed medium inlet is in communication with an evaporator and the adsorbed medium outlet that is in communication with a condenser; and the porous heat transferring member and the adsorbed medium passages are housed in the casing in a vacuum condition such that the adsorbed medium flows therein from the evaporator through the adsorbed medium inlet pipe during an adsorption and flows out from the casing toward the condenser through the adsorbed medium outlet pipe during a desorption. ### Claim 11 (depends on 1) The adsorption module according to claim 1, wherein the metallic material is one of copper and copper alloy, and the heat medium pipes are made of one of copper and copper alloy. ### Claim 12 (depends on 1) The adsorption module according to claim 1, wherein the adsorbent is in the form of fine particles which can be contained in the pores of the heat transferring member. ### Claim 13 (depends on 1) The adsorption module according to claim 1, wherein the adsorbent is silica gel or zeolite. ### Claim 14 (depends on 1) The adsorption module according to claim 1, wherein the plurality of adsorbed medium passages encircle each of the heat medium pipes via the sintered body of the porous heat transferring member. ### Claim 15 (depends on 1) The adsorption module according to claim 1, wherein the sintered body of the porous heat transferring member is located between the plurality of adsorbed medium passages and each of the heat medium pipes. ### Claim 16 (depends on 1) The adsorption module according to claim 1, wherein the adsorbent is substantially evenly filled in the porous heat transferring member. ### Claim 17 (depends on 12) The adsorption module according to claim 12, wherein the fine particles of the adsorbent are substantially evenly filled in the pores heat transferring member. ### Claim 18 (depends on 1) The adsorption module according to claim 1, wherein the adsorbent absorbs and desorbs only the gas-phase refrigerant. ### Claim 19 An adsorption module comprising: a plurality of heat medium pipes allowing a heat exchange medium to pass through; a porous heat transferring member disposed on peripheries of the heat medium pipes, the porous heat transferring member being a sintered body of a metallic material in a form of one of powders, particles and fibers, the porous heat transferring member being connected to outer surfaces of the heat medium pipes by metal-to-metal bonding, the porous heat transferring member being formed with three-dimensional mesh-like small pores allowing vapor-state adsorbed medium to pass through; adsorbent being substantially evenly filled in the three-dimensional mesh-like small pores of the porous heat transferring member, the adsorbent being one of silica gel and zeolite having a porous structure absorbing and desorbing the vapor-state adsorbed medium; a plurality of adsorbed medium passages formed by the porous heat transferring member, each passage allowing the vapor-state adsorbed medium to flow through the passage and being in communication with the three-dimensional mesh-like small pores of the porous heat transferring member, the adsorbed medium passages extend straight and parallel to axes of the heat medium pipes, each of the heat medium pipes being encircled by two or more adsorbed medium passages; and a casing including a casing body, an adsorbed medium inlet pipe that is to be communicated with an evaporator and an adsorbed medium outlet pipe that is to be communicated with a condenser; wherein the heat medium pipes, the porous heat transferring member and the adsorbed medium passages are housed in the casing body in a vacuum condition such that the vapor-state adsorbed medium from the evaporator is supplied to the porous heat transferring member and the adsorbed medium passages through the adsorbed medium inlet pipe during an adsorption and flows out from the casing toward the condenser through the adsorbed medium output pipe during a desorption; the adsorbed medium passages extend from a first end to a second end of the porous heat transferring member; the adsorbed medium inlet pipe and the adsorbed medium outlet pipes are coupled to the casing body adjacent to the first end of the porous heat transferring member disposed in the casing body; the casing body has an adsorbed medium inlet to which the adsorbed medium inlet pipe is coupled and an adsorbed medium outlet to which the adsorbed medium outlet pipe is coupled; the casing has a communication space adjacent the first end of the porous heat transfer member; the communication space faces and is in direct communication with both the adsorbed medium inlet and the adsorbed medium outlet; the first end of the porous heat transferring member including ends of the adsorbed medium passages faces and is in direct communication with the communication space; during the adsorption, the vapor-state adsorbed medium from the adsorbed medium inlet flows in the porous heat transferring member and the adsorbed medium passages via the communication space; and during the desorption, the vapor-state adsorbed medium desorbed from the adsorbent flows through the porous heat transferring member and the adsorbed medium passages and flows to the adsorbed medium outlet via the communication space. ### Claim 20 (depends on 19) The adsorption module according to claim 19, wherein the adsorbent adsorbs and desorbs only the vapor-state adsorbed medium.