# US 8,769,967 B2 · Electrocaloric heat transfer > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 8,769,967 B2 - Document ID: US8769967B2 - Status: Granted - Kind: B2 - Application number: 12/999,182 - Filed: 2010-09-03 - Published: 2012-03-08 - Granted: 2014-07-08 - Earliest claimed: 2010-09-03 - Assignees: Empire Technology Development LLC - Applicants: Ezekiel Kruglick - Inventors: Ezekiel Kruglick - Web page: https://patentgrep.com/patent/US8769967B2 ## CPC - F25B 21/00: Machines, plants or systems, using electric or magnetic effects - F25B 2321/001: by using electro-caloric effects - Y02B 30/00: Energy efficient heating, ventilation or air conditioning [HVAC] - F25B: REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS - Y02B: CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO BUILDINGS, e.g. HOUSING, HOUSE APPLIANCES OR RELATED END-USER APPLICATIONS ## Abstract A heat pump, including first and second chambers enclosing phase change material, each chamber having an evaporator end with hydrophilic material and a condenser end with a hybrid hydrophobic/hydrophilic material. Each chamber is also operably connected to a respective electrocaloric element. ## Claims ### Claim 1 A heat pump to transfer heat from a heat source to a heat destination, comprising: a first electrocaloric element adapted to receive heat from the heat source; a first chamber having a first evaporator on a first evaporator end and a first condenser on a first condenser end, the first evaporator being operably coupled to the first electrocaloric element and comprised of at least one of a hydrophilic material or a super-hydrophilic material, and the first condenser comprising a hybrid hydrophobic/hydrophilic material; a first phase change material enclosed in the first chamber, the first phase change material adapted to be at least one of a first liquid state or a first vapor state, the first phase change material adapted to flow from the first evaporator to the first condenser when in the first vapor state, and further adapted to flow from the first condenser to the first evaporator when in the first liquid state; a second electrocaloric element operably coupled to the first condenser; a second chamber having a second evaporator on a second evaporator end and a second condenser on a second condenser end, the second evaporator comprised of at least one of a hydrophilic material or a super-hydrophilic material and being operably coupled to the second electrocaloric element, the second condenser end being adapted to transfer heat to the heat destination, and the second condenser comprising the hybrid hydrophobic/hydrophilic material; and a second phase change material enclosed in the second chamber, the second phase change material adapted to be at least one of a second liquid state or a second vapor state, the second phase change material adapted to flow from the second evaporator to the second condenser when in the second vapor state, and further adapted to flow from the second condenser to the second evaporator when in the second liquid state. ### Claim 2 (depends on 1) The heat pump of claim 1, wherein the first phase change material comprises water, the first liquid state comprises liquid water and the first vapor state comprises water vapor. ### Claim 3 (depends on 1) The heat pump of claim 1, wherein the second phase change material comprises water, the second liquid state comprises liquid water and the second vapor state comprises water vapor. ### Claim 4 (depends on 1) The heat pump of claim 1, wherein the hybrid hydrophobic/hydrophilic material is comprised of micro-fabricated pillars on a surface of a hydrophilic wick substrate, wherein at least one of the first evaporator or second evaporator is configured to reach nucleate boiling at a lower temperature than one of the first condenser or the second condenser. ### Claim 5 (depends on 1) The heat pump of claim 1, wherein the first electrocaloric element comprises a first electrocaloric film. ### Claim 6 (depends on 5) The heat pump of claim 5, wherein the first electrocaloric film is comprised of at least one of lead zirconate titanate, lead-scandium, barium titanate, a polymer, a pyroelectric material, a ferroelectric material, or an antiferroelectric material. ### Claim 7 (depends on 1) The heat pump of claim 1, wherein the second electrocaloric element comprises a second electrocaloric film. ### Claim 8 (depends on 7) The heat pump of claim 7, wherein the second electrocaloric film is comprised of at least one of lead zirconate titanate, lead-scandium, barium titanate, a polymer, a pyroelectric material, a ferroelectric material, or an antiferroelectric material. ### Claim 9 (depends on 1) The heat pump of claim 1, further comprising: a first voltage source operably coupled to the first electrocaloric element, the first voltage source adapted to apply a first voltage to the first electrocaloric element, wherein the first voltage may cause the first electrocaloric element to transfer heat from the heat source to the first chamber; and a second voltage source operably coupled to the second electrocaloric element, the second voltage source adapted to apply a second voltage to the second electrocaloric element, wherein the second voltage may cause the second electrocaloric element to transfer heat from the first chamber to the second chamber. ### Claim 10 (depends on 9) The heat pump of claim 9, wherein the first voltage is applied to the first electrocaloric element at a first time period and the second voltage is applied to the second electrocaloric element at a second time period. ### Claim 11 (depends on 10) The heat pump of claim 10, wherein the first time period and the second time period are non-overlapping time periods. ### Claim 12 A heat pump to transfer heat from a heat source to a heat destination, comprising: an electrocaloric element adapted to receive heat from the heat source; a chamber having an evaporator comprised of at least one of a hydrophilic material or a super-hydrophilic material on a first end and a condenser comprised of a hybrid hydrophobic/hydrophilic material on a second end, the evaporator being operably coupled to the electrocaloric element, the second end being adapted to transfer heat to the heat destination; and a phase change material enclosed in the chamber, the phase change material adapted to be at least one of a liquid state or a vapor state, the phase change material adapted to flow from the evaporator to the condenser when in the vapor state and the phase change material adapted to flow from the condenser to the evaporator when in the liquid state, wherein the hybrid hydrophobic/hydrophilic material is comprised of micro-fabricated pillars on a surface of a hydrophilic wick substrate that enables the evaporator to reach nucleate boiling at a lower temperature than the condenser. ### Claim 13 (depends on 12) The heat pump of claim 12, further comprising: a voltage source operably coupled to the electrocaloric element, the voltage source adapted to apply a voltage to the electrocaloric element to cause the electrocaloric element to transfer heat from the heat source to the chamber. ### Claim 14 A method to transfer heat from a heat source to a heat destination via a first heat pump and a second heat pump serially coupled, the first heat pump comprising a first electrocaloric element operably coupled to a first chamber at least partially containing a first phase change material and having a first evaporator and a first condenser, and the second heat pump comprising a second electrocaloric element operably coupled to a second chamber at least partially containing a second phase change material and having a second evaporator and a second condenser, the method comprising: providing the first and second evaporators with one of a hydrophilic material or a super hydrophilic material, and the first and second condensers with a hybrid hydrophobic/hydrophilic material; for a first time period, applying a first voltage to the second electrocaloric element and reducing a second voltage from the first electrocaloric element to cause the second evaporator to reach nucleate boiling at a lower temperature than the second condenser; and for a second time period, applying the second voltage to the first electrocaloric element and reducing the first voltage from the second electrocaloric element to cause the first evaporator to reach nucleate boiling at a lower temperature than the first condenser. ### Claim 15 (depends on 14) The method of claim 14, wherein the first time period and the second time period comprise non-overlapping time periods. ### Claim 16 (depends on 14) The method of claim 14, wherein the hybrid hydrophobic/hydrophilic material is comprised of micro-fabricated pillars on a surface of a hydrophilic wick substrate. ### Claim 17 (depends on 14) The method of claim 14, wherein the applying the first voltage to the second electrocaloric element and reducing the second voltage from the first electrocaloric element causes the second evaporator to operate in a nucleate boiling state. ### Claim 18 (depends on 17) The method of claim 17, wherein heat is transferred from the first heat pump to the second heat pump in response to operation of the second evaporator in the nucleate boiling state. ### Claim 19 (depends on 14) The method of claim 14, wherein the applying the second voltage to the first electrocaloric element and reducing the first voltage from the second electrocaloric element causes the first evaporator to operate in a nucleate boiling state. ### Claim 20 (depends on 19) The method of claim 19, wherein heat is transferred from the heat source to the first chamber in response to operation of the first evaporator in the nucleate boiling state.