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US 8,758,498 B2Granted
Silanes blend
AssigneeDow Corning Corporation
InventorsRalf Zastrau, Rolf Danzebrink, Peter Cheshire Hupfield, Samantha J. Reed
Life of this patent
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Abstract
The present invention relates to a composition comprising at least two fluorosilanes and at least one aminosilane, a condensation product of said fluorosilanes and said aminosilane, and a surface protective agent made thereof.
Claims19
A reactive composition comprising
- (a) at least two different fluorosilanes each of the same general formula I
- Rtf—SiX3 (formula I),
- wherein
- X is selected from the group of alkoxy, halide, oxime, carboxyl, phenoxide and polyether, and
- Rtf is a straight, branched or cyclic residue of the general formula II or III
- —Y—Rf (formula II) or
- —Y—(SiR1R2O)xSiR1R2—Y—Rf (formula III),
- wherein
- Y is a moiety selected from the group of —(CH2)n—, —CO2—, —O—, —CONH—, —Ph—, —SO2—, and —SO2NH—, —(CH2)o—O—(CH2)m, —(CH2)o—CONH—(CH2)m, —(CH2)o—Ph—(CH2)m, —(CH2)oSO2—(CH2)m, —(CH2)o—SO2NH—(CH2)m, —SO2—O— and —SO2NH—, wherein o is an integer from 1 to 30, m is a number in the range from 0 to 30 and, wherein n is an integer from 1 to 30,
- Rf is a C2 to C7 linear or branched perfluoralkylene group, wherein the fluorosilanes differ in their number of carbon atoms in Rf at least by 2,
- R1 and R2 are independently selected from monovalent organic residues,
- x is an integer from 0 to 5, and
- (b) and at least one aminosilane of the general formula IV
- Ra—SiR3R4R5 (formula IV),
- where
- Ra is a straight, branched or cyclic alkyl residue comprising 1 to 7 carbon atoms and at least one primary, secondary, ternary or quaternary amino-group,
- R3 and R4 are independently selected from —Ra, —OR6 and/or —R6, and
- R5 is —OR6, and
- R6 is a straight, branched or cyclic alkyl residue comprising 1 to 3 carbon atoms.
16 more elements
Dependencies are inferred from the claim text.