Method and device for biomass combustion without carbon dioxide emission
AssigneeGas Natural SDG, S.A.
InventorsJuan Carlos Abanades Garcia, Mónica Alonso Carreño, Nuria Rodriguez Gómez
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Abstract
The invention relates to a device and a method for biomass combustion and simultaneous CO2 capture for capturing the CO2 generated in said combustion to generate a substantially pure CO2 stream (9) which can be subsequently stored. The device comprises a combustor-carbonator reactor (a) which is fed with biomass and air; at least one solids recycling cyclone (b, c) which separates solids (5) returning to the combustor-carbonator and from which there exits a solids and gases stream (4). The device comprises a calciner B which regenerates CaO, a fluidized bed (d) and means for feeding fresh CaCO3 (12) and for purging solids (11).
Claims2
A method for biomass combustion and simultaneous capture of CO2 generated in the combustion, the method comprising the steps of:
- (a) feeding biomass and air into a circulating fluidized bed combustor-carbonator;
- (b) effecting in the combustor-carbonator a biomass combustion and simultaneous CaO carbonation to generate CaCO3 at a temperature between 550 and 700° C.;
- (c) separating a first stream of solids and gases from the combustor-carbonator in a first cyclone into a first solids stream and a second stream of solids and gases and recycling the first solids stream to the combustor-carbonator;
- (d) separating the second stream of solids and gases in a second cyclone into a second solids stream and a gas stream and leading the second solids stream to a calciner;
- (e) continuously calcining CaCO3 contained in the second solids stream and separating a resulting CO2-containing stream from the calciner into a CO2 stream and a third solids stream;
- (f) sending the third solids stream to a fluidized bed, the fluidized bed being fluidized with steam or CO2;
- (g) continuously feeding fresh limestone to the fluidized bed;
- (h) continuously purging a fifth solids stream from the fluidized bed;
- and
- (i) removing a fourth solids stream from the fluidized bed and feeding the fourth solids stream to the combustor-carbonator, the fourth solids stream comprising between 5 and 20 times a molar flow of carbon fed with the biomass, and the combustor-carbonator containing an amount of CaO, in particle form, of at least 500 kg for every square meter cross-section of the combustor-carbonator, the CaO amount remaining stable in the fluidized bed.
Dependencies are inferred from the claim text.