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US 8,747,659 B2Granted
Hydrotreating process
AssigneeExxonMobil Research and Engineering Company
InventorsGabor Kiss, Lulian Nistor, John Zengel
Life of this patent
Estimating the term…
Abstract
A process for hydrotreating a first aromatics- and sulfur-containing hydrocarbon feed using a fresh supported CoMo catalyst, includes treating the fresh catalyst under first hydrotreating conditions with a second hydrocarbon feed having a lower aromatics content than the first feed.
Claims6
A process for hydrotreating a first aromatics- and sulfur-containing hydrocarbon feed boiling in the diesel fuel range using a fresh supported CoMo catalyst, the process comprising:
- treating a fresh, sulfided CoMo hydrotreating catalyst having a support of amorphous alumina, silica or alumina-silica, under first hydrotreating conditions including a temperature of about 300° C. to about 350° C., a pressure of about 1.5 MPaq to about 3.5 MPaq, and an LHSV of about 0.3 hr−1 to about 1.0 hr−1 with a second hydrocarbon feed having a lower aromatics content than said first feed, the second hydrocarbon feed having an aromatics content of less than 20 wt % to reduce the activity of the catalyst by at least 5% and, following the treatment with the second hydrocarbon feed,
- hydrotreating the first feed using the treated catalyst under hydrotreating conditions including a temperature of about 300° C. to about 380° C., a pressure of about 1.5 MPag to about 3.5 MPaq, and an LHSV of about 0.2 hr−1 to about 0.8 hr−to reduce the sulfur content of said first feed to 15 wppm or less.
Dependencies are inferred from the claim text.