# US 8,739,878 B2 · Method of enhancing fracture conductivity > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 8,739,878 B2 - Document ID: US8739878B2 - Status: Granted - Kind: B2 - Application number: 13/782,952 - Filed: 2013-03-01 - Published: 2013-07-11 - Granted: 2014-06-03 - Earliest claimed: 2008-10-09 - Assignees: Baker Hughes Incorporated - Applicants: Harold Dean Brannon; Brian N. Ward - Inventors: Harold Dean Brannon; Brian N. Ward - Web page: https://patentgrep.com/patent/US8739878B2 ## CPC - E21B 43/267: reinforcing fractures by propping - C09K 8/602: {containing surfactants} - C09K 8/62: Compositions for forming crevices or fractures - C09K 8/68: containing organic compounds - C09K 8/80: Compositions for reinforcing fractures, e.g. compositions of proppants used to keep the fractures open - C09K 8/90: of natural origin, e.g. polysaccharides, cellulose - C09K 2208/24: Bacteria or enzyme containing gel breakers - C09K 2208/26: Gel breakers other than bacteria or enzymes - C09K 2208/30: Viscoelastic surfactants [VES] - E21B: EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS - C09K: MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE ## Abstract The method disclosed herein includes the introduction of proppant-free stage and a proppant laden stage into the wellbore and/or subterranean formation. The method increases the effective fracture width and enhances fracture conductivity within the formation. Either the proppant-free stage or the proppant laden stage contains a breaker. The other stage contains a viscosifying polymer or viscoelastic surfactant to which the breaker has affinity. The proppant-free stage may be introduced prior to introduction of the proppant laden stage into the wellbore and/or formation. Alternatively, the proppant laden stage may be introduced into the wellbore and/or formation prior to introduction of the proppant-free stage. ## Claims ### Claim 1 A method of hydraulically fracturing a subterranean formation comprising pumping into the formation at least two stages wherein a first stage is a proppant-free fluid and a second stage is a proppant laden slurry wherein (i) either the first stage or second stage contains a breaker, (ii) each of the stages contains at least one member selected from the group consisting of a viscosifying polymer and viscoelastic surfactant; and (iii) the breaker has less affinity for the viscosifying polymer or viscoelastic surfactant of the stage containing the breaker than the viscosifying polymer or viscoelastic surfactant of the other stage. ### Claim 2 (depends on 1) The method of claim 1, wherein the first stage is introduced into the formation prior to the second stage. ### Claim 3 (depends on 1) The method of claim 1, wherein the second stage is introduced into the formation prior to the first stage. ### Claim 4 (depends on 1) The method of claim 1, wherein the first stage or second stage contains a friction reduction polymer. ### Claim 5 (depends on 1) The method of claim 1, wherein the breaker is at least one enzyme or oxidative breaker. ### Claim 6 (depends on 1) The method of claim 1, wherein the proppant laden slurry is introduced into the formation at a concentration sufficient to achieve a partial monolayer fracture and further wherein a partial monolayer fracture is created in the formation. ### Claim 7 (depends on 1) The method of claim 1, wherein the breaker is selected from the group consisting of ammonium persulfate, ammonium peroxydisulfate, sodium persulfate, sodium bromate, encapsulated ammonium persulfate, potassium persulfate, encapsulated potassium persulfate, sodium persulfate, sodium bromate, inorganic peroxides, encapsulated inorganic peroxides, organic peroxides, encapsulated organic peroxides, sodium perborate, magnesium perborate, calcium perborate, encapsulated sodium perborate, hydrolases, lyases, transferases and oxidoreductases. ### Claim 8 (depends on 1) The method of claim 1, wherein the at least one member is a gelled and/or crosslinked fluid and/or viscoelastic surfactant. ### Claim 9 (depends on 1) The method of claim 1, wherein the at least one member in the first stage and/or the second stage is selected from the group consisting of galactomannan gums, welan gum, guars, derivatized guars, cellulose and cellulose derivatives, starch, starch derivatives, xanthan, derivatized xanthan, scleroglucan, diutan and mixtures thereof. ### Claim 10 (depends on 1) The method of claim 1, wherein the proppant of the proppant laden slurry is: (a) selected from the group consisting of silica, quartz sand grains, glass and ceramic beads, walnut shell fragments, aluminum, polyamide, resin-coated sand, synthetic organic particles, glass microspheres, sintered bauxite, resin coated ceramics, resin-coated sintered bauxite, ground or crushed shells of nuts, ground or crushed seed shells of seeds of fruits or plants and processed wood materials or is a plastic or a composite thereof, a thermoplastic or composite thereof, a resin or an aggregate containing a binder or a mixture thereof; and/or (b) has an apparent specific gravity less than or equal to 2.25. ### Claim 11 (depends on 10) The method of claim 10, wherein the apparent specific gravity of the proppant is less than or equal to 1.75. ### Claim 12 (depends on 11) The method of claim 11, wherein the apparent specific gravity of the proppant is less than or equal to 1.25. ### Claim 13 (depends on 1) The method of claim 1, wherein the proppant-free gelled and/or crosslinked fluid initiates a fracture in the formation and further wherein the proppant laden slurry contains a breaker, wherein a filter cake is deposited onto the fracture face of the formation, the filter cake being composed at least in part by the at least one polymer and/or viscoelastic surfactant and further wherein the at least one breaker degrades at least a portion of the filter cake. ### Claim 14 A method of hydraulically fracturing a subterranean formation comprising: (a) pumping into either the formation or into a wellbore penetrating the formation a proppant-free gelled and/or crosslinked fluid containing at least one viscosifying polymer and/or viscoelastic surfactant and initiating a fracture therein; (b) introducing into the wellbore or formation a proppant laden slurry which contains at least one breaker and a viscosifying polymer and/or viscoelastic surfactant; (c) degrading the at least one viscosifying polymer and/or viscoelastic surfactant in the proppant-free fluid with the at least one breaker wherein the at least one breaker has greater affinity for the at least one viscosifying polymer and/or viscoelastic surfactant in the proppant-free fluid than the viscosifying polymer and/or viscoelastic surfactant present in the proppant laden slurry. ### Claim 15 (depends on 14) The method of claim 14, wherein the first stage is introduced into the formation prior to the second stage. ### Claim 16 (depends on 14) The method of claim 14, wherein the second stage is introduced into the formation prior to the first stage. ### Claim 17 (depends on 14) The method of claim 14, wherein the first viscosifying polymer and/or second viscosifying polymer is a crosslinked. ### Claim 18 (depends on 14) The method of claim 14, wherein the apparent specific gravity of the proppant is less than or equal to 2.25. ### Claim 19 (depends on 18) The method of claim 18, wherein the apparent specific gravity of the proppant is less than or equal to 1.75. ### Claim 20 A method of hydraulically fracturing a subterranean formation comprising: (a) pumping into the formation at least two stages wherein a first stage is a proppant-free fluid and a second stage is a proppant laden slurry and further wherein one of the stages contains a first viscosifying polymer and a crosslinking agent and the other stage contains a breaker and a second viscosifying polymer and/or viscoelastic surfactant; and (b) degrading the first viscosifying polymer with the breaker wherein the breaker has greater affinity for the first viscosifying polymer than the second viscosifying polymer and/or viscoelastic surfactant present in the stage containing the breaker; and further wherein (i) the first viscosifying polymer is selected from the group consisting of cellulose, cellulose derivatives, starch, starch derivatives, xanthan, derivatized xanthan and mixtures thereof; and (ii) the crosslinking agent contains a metal selected from the group consisting of aluminum, antimony, zirconium and titanium.