# US 8,739,512 B2 · Combined cycle power plant

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- Number: US 8,739,512 B2
- Document ID: US8739512B2
- Status: Granted
- Kind: B2
- Application number: 12/157,067
- Filed: 2008-06-06
- Published: 2009-05-14
- Granted: 2014-06-03
- Earliest claimed: 2007-06-06
- Assignees: Areva Solar, Inc.
- Applicants: David R. Mills
- Inventors: David R. Mills
- Web page: https://patentgrep.com/patent/US8739512B2

## CPC

- F01K 23/10: with exhaust fluid of one cycle heating the fluid in another cycle (F01K17/025 takes precedence)
- F01K 3/00: Plants characterised by the use of steam or heat accumulators, or intermediate steam heaters, therein (regenerating exhaust steam F01K19/00)
- F01K 3/12: having two or more accumulators
- F02C 6/18: using the waste heat of gas-turbine plants outside the plants themselves, e.g. gas-turbine power heat plants (using waste heat as source of energy for refrigeration plants F25B27/02; using the waste heat of a gasturbine for steam generation or in a steam cycle see F01K23/10)
- F22B 3/04: by drop in pressure of high-pressure hot water within pressure-reducing chambers, e.g. in accumulators
- Y02E 10/46: Conversion of thermal power into mechanical power, e.g. Rankine, Stirling or solar thermal engines
- Y02E 20/16: Combined cycle power plant [CCPP], or combined cycle gas turbine [CCGT]
- F01K: STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES (gas-turbine or jet-propulsion plants F02; nuclear power plants, engine arrangements therein G21D)
- F02C: GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS (construction of turbines F01D; jet-propulsion plants F02K; construction of compressors or fans F04; generating combustion products of high pressure or high velocity F23R; using gas turbines in compression refrigeration plants F25B11/00)
- F22B: METHODS OF STEAM GENERATION; STEAM BOILERS
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

Combined cycle power plants and related methods are disclosed here. In the plants, a mediating thermal energy storage unit is used to store waste or residual thermal energy recovered from a heat engine employing a top thermodynamic cycle of the combined cycle power plant, so that the stored residual thermal energy may be used as an energy source in a bottom thermodynamic cycle of the power plant. In the combined cycle power plants described here, the heat engine employing a top cycle may comprise a Brayton cycle heat engine and the heat engine employing the bottom thermodynamic cycle may be a Rankine cycle heat engine.

## Claims

### Claim 1

A method of generating electrical energy, the method comprising:
employing a top thermodynamic cycle comprising the steps of:
heating a refractory material of a receiver with a concentrated solar light beam and storing the heat in the refractory material, the refractory material being selected from the group consisting of refractory metal, ceramic, cermet, alumina, silica, magnesia, zirconia, silicon carbide, titanium carbide, tantalum carbide, chromium carbide, niobium carbide, zirconium carbide, molybdenum disilicide, calcium oxide, chromite, dolomite, magnesite, quartzite, aluminium silicate, tungsten, molybdenum, niobium, tantalum, rhenium, beryllium, and combinations thereof;
compressing a first working fluid;
heating the first working fluid by passing it through the heated refractory material; and
expanding the first working fluid in a turbine to generate electrical energy in a first generator;
transferring at least a portion of the thermal energy from the first working fluid after expansion to a mediating thermal storage unit by passing exhaust from the turbine through the thermal storage unit to build up a store of residual thermal energy; and
transferring the stored residual thermal energy from the mediating thermal storage unit and the stored heat in the refractory material to a second working fluid at a later time for use in a bottom thermodynamic cycle to generate electrical energy in a second generator, wherein the thermal storage unit is in the form of an aggregate, a powder, a solid mass or a liquid and comprises a material selected from the group consisting of rocks, minerals, quartz, aggregates, sand, concrete, molten salts including nitrate salts, hydroxide salt, carbonate salt, sulphate salt and combinations thereof.

### Claim 2 (depends on 1)

The method of claim 1, wherein the concentrated solar light beam is produced by a high concentration central receiver type solar array or a parabolic dish solar array.

### Claim 3 (depends on 1)

The method of claim 1, further comprising the step of diverting a portion of the residual thermal energy for immediate use in the bottom thermodynamic cycle.

### Claim 4 (depends on 1)

The method of claim 1, further comprising the step of adjusting a storage time of the residual thermal energy so that a combined electrical output of heat engines employing the top and bottom thermodynamic cycles meets a fluctuating demand.

### Claim 5 (depends on 1)

The method of claim 1, further comprising the step of adjusting a storage time of the residual thermal energy so that a combined electrical output of heat engines employing the top and bottom thermodynamic cycles meets a baseline demand.

### Claim 6 (depends on 1)

The method of claim 1, further comprising the step of adjusting a storage time of the residual thermal energy so that a combined output of heat engines employing the top and bottom thermodynamic cycles meets a peak demand.

### Claim 7 (depends on 1)

The method of claim 1, further comprising the step of expanding the second working fluid in multiple stages through a multi-stage turbine.

### Claim 8 (depends on 7)

The method of claim 7, further comprising the step of reheating the second working fluid between expansion stages.

### Claim 9 (depends on 1)

The method of claim 1, further comprising the step of transferring heat energy to the second working fluid by transfer from the refractory material, either between expansion stages or before the first expansion.

### Claim 10 (depends on 1)

The method of claim 1, further comprising the step of storing at least a portion of the heated compressed first working fluid before expanding the first working fluid to produce electrical energy.

### Claim 11 (depends on 1)

The method of claim 1, further comprising the step of storing at least a portion of the heated second working fluid before using the heated second working fluid to generate electrical energy.

### Claim 12 (depends on 1)

The method of claim 1, further comprising the step of supplementing the top thermodynamic cycle with energy from a fossil fuel or a biomass-derived fuel.

### Claim 13 (depends on 3)

The method of claim 3, wherein a degree of diversion of residual thermal energy for immediate use is configured to provide a combined efficiency from the top and bottom thermodynamic cycles of about 65% or greater.

### Claim 14 (depends on 3)

The method of claim 3, further comprising the step of providing a plurality of top thermodynamic cycles and storing residual energy from the first working fluid associated with some or all of the plurality of top thermodynamic cycles and using the accumulated stored residual energy to generate electrical energy in the bottom thermodynamic cycle.

### Claim 15 (depends on 14)

The method of claim 14, wherein some or all of the cycles in the plurality of thermodynamic cycles comprise Brayton cycles.

### Claim 16 (depends on 1)

The method of claim 1, further comprising the step of using an industrial Brayton or Ericsson turbine in the top thermodynamic cycle.

### Claim 17 (depends on 1)

The method of claim 1, further comprising the step of using an aeroderivative Brayton or Ericcson turbine in the top thermodynamic cycle.

### Claim 18 (depends on 1)

The method of claim 1, further comprising the step of using a Rankine or Kalina cycle as the bottom thermodynamic cycle.

### Claim 19

An electrical power plant comprising:
a solar concentrator for concentrating a solar light beam;
a receiver comprising a refractory material for receiving the concentrated solar light beam and converting the concentrated solar light beam to heat energy and storing the heat energy, the refractory material being selected from the group consisting of refractory metal, ceramic, cermet, alumina, silica, magnesia, zirconia, silicon carbide, titanium carbide, tantalum carbide, chromium carbide, niobium carbide, zirconium carbide, molybdenum disilicide, calcium oxide, chromite, dolomite, magnesite, quartzite, aluminium silicate, tungsten, molybdenum, niobium, tantalum, rhenium, beryllium, and combinations thereof;
a first top cycle heat engine employing a top thermodynamic cycle configured to generate electrical energy, the first top cycle heat engine comprising:
a first compressor configured to compress a first working fluid;
a first heating stage for heating the compressed first working fluid via the refractory material; and
a first turbine configured to expand the first working fluid to drive a first generator;
a mediating thermal energy storage unit configured to store residual thermal energy recovered from the expanded first working fluid of the first top cycle heat engine by passing exhaust from the first turbine through the thermal storage unit;
a heat exchange apparatus operable to transfer heat from the heat stored in the refractory material and the mediating thermal energy storage unit to a second working fluid;
a first bottom cycle heat engine employing a bottom thermodynamic cycle and configured to generate electrical energy using the second working fluid heated by the stored thermal energy in the refractory material and the mediating thermal energy storage unit, wherein the thermal storage unit is in the form of an aggregate, a powder, a solid mass or a liquid and comprises a material selected from the group consisting of rocks, minerals, quartz, aggregates, sand, concrete, molten salts including nitrate salts, hydroxide salt, carbonate salt, sulphate salt and combinations thereof.

### Claim 20 (depends on 19)

The electrical power plant of claim 19, wherein the first bottom cycle heat engine comprises:
a second compressor configured to compress the second working fluid;
a second heating stage for heating the compressed second working fluid; and
a second turbine configured to expand the second working fluid to drive a second generator.

### Claim 21 (depends on 20)

The electrical power plant of claim 20, wherein the second turbine comprises multiple expansion stages.

### Claim 22 (depends on 21)

The electrical power plant of claim 21, further comprising a reheating stage configured to reheat the second working fluid between expansion stages.

### Claim 23 (depends on 19)

The electrical power plant of claim 19, wherein the first top cycle heat engine is one of a plurality of top cycle heat engines, and the mediating thermal energy storage unit is configured to accumulate and store thermal energy from some or all of the plurality of heat engines.

### Claim 24 (depends on 23)

The electrical power plant of claim 23, wherein some or all of the heat engines in the plurality of to cycle heat engines employ a Brayton cycle.

### Claim 25 (depends on 19)

The electrical power plant of claim 19, wherein the first top cycle heat engine comprises an industrial gas turbine.

### Claim 26 (depends on 19)

The electrical power plant of claim 19, wherein the first top cycle heat engine comprises an aeroderivative gas turbine.

### Claim 27 (depends on 19)

The electrical power plant of claim 19, wherein the first bottom cycle heat engine comprises a Rankine or Kalina cycle turbine.

### Claim 28 (depends on 19)

The electrical power plant of claim 19, configured to output electrical energy at an efficiency of about 65% or higher.

### Claim 29 (depends on 19)

The electrical power plant of claim 19, configured as a load following power plant.

### Claim 30 (depends on 19)

The electrical power plant of claim 19, configured to supply a baseline amount of electrical energy.

### Claim 31 (depends on 19)

The electrical power plant of claim 19, configured to supply peak amounts of electrical energy.

### Claim 32 (depends on 19)

The electrical power plant of claim 19, wherein the heat exchange system is provided to facilitate transfer of heat from the receiver core or the thermal storage unit to the second working fluid between expansion stages in the first bottom cycle heat engine.

### Claim 33 (depends on 19)

The electrical power plant of claim 19, wherein the first top cycle heat engine is configured to be heated with a fossil fuel or a biomass-derived fuel.

### Claim 34 (depends on 19)

The electrical power plant of claim 19, wherein the receiver comprises a refractory core configured to store the thermal energy converted from the concentrated solar light beam.

### Claim 35 (depends on 34)

The electrical power plant of claim 34, wherein the core further comprises one or more fluid channels in and/or around the core to convey a working fluid to facilitate extraction of stored thermal energy from the core.

### Claim 36 (depends on 19)

The electrical power plant of claim 19, wherein the receiver is tower mounted.

### Claim 37 (depends on 36)

The electrical power plant of claim 36, wherein the receiver and the first compressor are tower mounted.

### Claim 38 (depends on 19)

The electrical power plant of claim 19, further comprising an elevated reflector configured to reflect concentrated solar radiation to the receiver, itself mounted on the ground.

### Claim 39

An electrical power plant comprising a compressor to compress a first working fluid,
a solar concentrator to form a concentrated light beam,
a receiver comprising a refractory material for converting solar radiation from the concentrated light beam into heat and storing the heat to effect heating of the first working fluid following its compression, the refractory material being selected from the group consisting of refractory metal, ceramic, cermet, alumina, silica, magnesia, zirconia, silicon carbide, titanium carbide, tantalum carbide, chromium carbide, niobium carbide, zirconium carbide, molybdenum disilicide, calcium oxide, chromite, dolomite, magnesite, quartzite, aluminium silicate, tungsten, molybdenum, niobium, tantalum, rhenium, beryllium, and combinations thereof,
a first turbine coupled to a first electrical generator for generating electrical energy, wherein the first working fluid in operation expands through the first turbine to drive the first electrical generator,
a thermal energy storage unit arranged to store residual thermal energy contained in the first working fluid following its expansion through the first turbine by passing exhaust from the first turbine through the thermal storage unit,
a second turbine coupled to a second electrical generator and arranged to receive a second working fluid that in operation is expanded through the second turbine to drive the second generator, and
wherein the second working fluid is in operation heated by use of stored thermal energy extracted from the thermal energy storage unit and the refractory material of the receiver, wherein the thermal storage unit is in the form of an aggregate, a powder, a solid mass or a liquid and comprises a material selected from the group consisting of rocks, minerals, quartz, aggregates, sand, concrete, molten salts including nitrate salts, hydroxide salt, carbonate salt, sulphate salt and combinations thereof.