UV absorbers soluble in polar media
AssigneeBayer MaterialScience AG
InventorsBirgit Meyer Zu Berstenhorst, Serguei Kostromine
Life of this patent
Estimating the term…
Abstract
The invention relates to triazine-based special organic UV absorbers modified in such a way as to be soluble in polar coating compositions. The invention further relates to coatings, e.g. sol-gel based ones, containing said novel UV absorbers as well as to the use of said coatings for permanently protecting materials, especially plastics, from photochemical degradation.
Claims19
A coating composition comprising a lacquer and an UV-absorbing compound which is soluble in polar media and having the formula (I)
- A-X(-T-Q-P)n (I),
- wherein
- A represents
- wherein
- Y1 and Y2, independently of one another, represent substituents having the formula
- wherein
- r is 0 or 1,
- R1, R2, and R3, independently of one another, represent H, OH, C1-20 alkyl, C4-12 cycloalkyl, C2-20 alkenyl, C1-20 alkoxy, C4-12 cycloalkoxy, C2-20 alkenyloxy, C7-20 aralkyl, halogen, —C≡N, C1-5 haloalkyl, —SO2R′, —SO3H, —SO3M (M=alkali metal), —COOR′, —CONHR′, —CONR′R″, —OCOOR′, —OCOR′, —OCONHR′, (meth)acrylamino, (meth)acryloxy, C6-12 aryl (optionally substituted by C1-12 alkyl, C1-12 alkoxy, CN and/or by halogen), or C3-12 heteroaryl (optionally substituted by C1-12 alkyl, C1-12 alkoxy, CN and/or by halogen)
- and wherein
- R′ and R″ represent —H, C1-20 alkyl, —C4-12 cycloalkyl, C6-12 aryl (optionally substituted by C1-12 alkyl, C1-12 alkoxy, CN and/or by halogen) or C3-12 heteroaryl (optionally substituted by C1-12 alkyl, C1-12 alkoxy, CN and/or by halogen),
- X represents a linear or branched linker, wherein between the O atom of group A and each T group there is a chain of at least 4 atoms selected from the group consisting of carbon, oxygen, nitrogen, sulfur, phosphorus and silicon in the chain,
- T represents a urethane group —O—(C═O)—NH— or a urea group —NH—(C═O)—NH—,
- Q represents —(CH2)m—, wherein m is 1,2 or 3,
- P represents a mono-, di- or tri-alkoxysilane group, and
- n represents an integer from 1 to 5,
- wherein the lacquer is a hybrid lacquer obtained by a sol-gel process.
A coating composition comprising a lacquer and an UV-absorbing compound which is soluble in polar media and having the formula (I)
- A-X(-T-Q-P)n (I),
- wherein
- A represents
- wherein
- Y1 and Y2, independently of one another, represent substituents having the formula
- wherein
- r is 0 or 1,
- R1, R2, and R3, independently of one another, represent H, OH, C1-20 alkyl, C4-12 cycloalkyl, C2-20 alkenyl, C1-20 alkoxy, C4-12 cycloalkoxy, C2-20 alkenyloxy, C7-20 aralkyl, halogen, —C≡N, C1-5 haloalkyl, —SO2R′, —SO3H, —SO3M (M=alkali metal), —COOR′, —CONHR′, —CONR′R″, —OCOOR′, —OCOR′, —OCONHR′, (meth)acrylamino, (meth)acryloxy, C6-12 aryl (optionally substituted by C1-12 alkyl, C1-12 alkoxy, CN and/or by halogen), or C3-12 heteroaryl (optionally substituted by C1-12 alkyl, C1-12 alkoxy, CN and/or by halogen)
- and wherein
- R′ and R″ represent —H, C1-20 alkyl, —C4-12 cycloalkyl, C6-12 aryl (optionally substituted by C1-12 alkyl, C1-12 alkoxy, CN and/or by halogen) or C3-12 heteroaryl (optionally substituted by C1-12 alkyl, C1-12 alkoxy, CN and/or by halogen),
- X represents a linear or branched linker, wherein between the O atom of group A and each T group there is a chain of at least 4 atoms selected from the group consisting of carbon, oxygen, nitrogen, sulfur, phosphorus and silicon in the chain,
- T represents a urethane group —O—(C═O)—NH— or a urea group —NH—(C═O)—NH—,
- Q represents —(CH2)m—, wherein m is 1,2 or 3,
- P represents a mono-, di- or tri-alkoxysilane group, and
- n represents an integer from 1 to 5,
- wherein the lacquer is a sol-gel lacquer.
Dependencies are inferred from the claim text.