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US 8,710,120 B2Granted
Cross-linkable compositions
AssigneeWacker Chemie AG
InventorMarko Prasse
Life of this patent
Estimating the term…
Abstract
Crosslinkable compositions contain a calcium carbonate-rich filler coated with a carboxylic acid of the formula R4—(OCR32—C(═O)OH)y. The compositions exhibit low modulus, good adhesion to substrates, and low skin formation time.
Claims10
A crosslinkable composition comprising
- (A) at least one crosslinkable compound selected from the group consisting of compounds (A1) of formula
- A-[(CR12)b—SiRa(OR2)3-a]x (II)
- where
- A is an x-valent polymer radical bonded via nitrogen, phosphorus, oxygen, sulfur, carbon or a carbonyl group,
- R are identical or different and are monovalent, optionally substituted hydrocarbyl radicals,
- R1 are identical or different and are hydrogen or a monovalent, optionally substituted hydrocarbyl radical which may be attached to the carbon atom via nitrogen, phosphorus, oxygen, sulfur or a carbonyl group,
- R2 are identical or different and are hydrogen or a monovalent, optionally substituted hydrocarbyl radical,
- x is an integer from 1 to 10,
- a is 0, 1 or 2 and
- b is an integer from 1 to 10
- with the proviso that at least two OR2 groups per molecule are present, and
- compounds (A2) of the formula
- R5cZdSiO(4-c-d)/2 (III)
- where
- R5 are identical or different and each is an optionally substituted hydrocarbyl radical which may be interrupted by oxygen atoms,
- Z are identical or different and are a hydroxyl radical or hydrolyzable radical,
- c is 0, 1, 2 or 3 and
- d is 0, 1, 2 or 3
- with the proviso that the sum of c+d is less than or equal to 4 and at least two Z radicals are present per molecule;
- and
- (B) a calcium carbonate-containing filler (B0) surface-treated with carboxylic acids (C) of the formula
- R4—(OCR32—C(═O)OH)y (I)
- where
- R3 are identical or different and are hydrogen or a monovalent, optionally substituted hydrocarbyl radical,
- R4 is a y-valent, carbon-bonded, optionally substituted hydrocarbyl radical which may be interrupted by oxygen atoms, and
- y is an integer from 1 to 3.
23 more elements
Dependencies are inferred from the claim text.