Economical, food-safe extraction of bisphenols
AssigneeEmpire Technology Development LLC
InventorKraig Anderson
Life of this patent
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Abstract
Methods for extracting bisphenols from polymer substrates are described. The methods include contacting the polymer substrate with an aqueous composition which includes a phase transfer agent, a base and optionally an oxidant, whereby the bisphenol is extracted into the aqueous composition. Suitable phase transfer agents are delineated. Also described are compositions which can be used in the present methods.
Claims29
A method for extracting a bisphenol from a polymer substrate comprising:
- contacting the polymer substrate with an aqueous composition comprising a phase transfer agent and a base, whereby the bisphenol is extracted in to the aqueous composition;
- wherein:
- the phase transfer agent is a quaternary organic ammonium compound of Formula I:
- R1, R2, R3, and R4 may be the same or different and are independently selected from H, C1-C20 alkyl, C3-C8 cycloalkyl, heterocyclyl, C6-C10 aryl and heteroaryl groups, or R1 and R2 or R1-R3 together with the nitrogen atom to which they are bound are a part of heterocyclic ring system and at least one of R1, R2, R3, and R4 is a C6-C10 aryl or heteroaryl group;
- and
- X- represents an anion comprising halide, hydroxide, sulphonate, phosphate, alkylphosphate, dialkylphosphate, borate, alkylborate, nitrite, nitrate, carbonate, bicarbonate, alkanoate, or O,O-dialkyldithiophosphate.
A method for removing Bisphenol-A from food can linings, the method comprising contacting the can lining with a composition comprising a) cetylpyridinium chloride, b) potassium carbonate or sodium carbonate, and c) sodium hypochlorite.
A method for extracting a bisphenol from a polymer substrate comprising:
- contacting the polymer substrate with an aqueous composition comprising a phase transfer agent and a base, whereby the bisphenol is extracted in to the aqueous composition;
- wherein:
- the phase transfer agent comprises benzethonium chloride, cetylpyridinium chloride, methylbenzthionium chloride, benzalkonium chloride, cetalkonium chloride, cetrimonium chloride, cetrimide, didecyldimethylammonium chloride, or domiphen bromide.
Dependencies are inferred from the claim text.